[Discussion of the Application and Influence Factors of Low-Background Gamma Spectrometry in Distinguishing Sedimentary Rock Types].

The contents of radionuclides uranium, thorium and potassium in the sedimentary rocks mainly depend on the contents of clay in the rocks. And the content of clay is the main basis for distinguishing types of sedimentary rock. Therefore, the value of specific activity or content of uranium, thorium and potassium can be as the quantitative index to distinguish sedimentary rock type. The specific activity or content of radionuclides uranium, thorium and potassium with the method of low-background gamma spectrometry can distinguish the type of rock quickly and accurately. Because of the influence of geometry, mass and moisture content in the sample, the accuracy of distinguishing types of rocks is influenced. This paper makes a theoretical discussion and experimental verification on the influence of mass and moisture content on the results of low-background gamma spectrometry. Results show that there is a linear relationship between (cps) of characteristic peak of all radionuclides and the mass of sample while different energy ranges and lithologies have different linear coefficient and trend fitting degree; The moisture content which is no more than 10%(while collecting samples, the moisture content is no more than 10%) has a little influence on the measurement results( the change values are within the twice standard deviation), so the moisture content which has no significant influence on the accuracy of distinguishing types of sedimentary rock using the method of low-background gamma spectrometry could not be considered. The distinguishing experiment of drilling cuttings samples collected from one oil and gas exploration area in Shanxi Dingbian is done. By the mass correction of the measured data, normalized (cps) ((cps) of per unit mass) of uranium, thorium and potassium channel can only roughly divide the types of sedimentary rocks. Therefore, synthetic distinguishing mode is established with (cps) of combination peak of characteristic peak of uranium, thorium and potassium. The type of rocks is further subdivided, and the distinguishing accuracy is more than 75%.

[Research on the Background Subtraction Method for X-Ray Fluorescence Spectrum with X-Ray Tube Excitation].

X-ray tube is the most commonly used equipment in X-ray fluorescence spectrum analysis as excitation source whose primary spectrum has become a major source of the background of X-ray fluorescence spectrum. Background subtraction should go before further analysis of this spectrum. The accuracy of the estimation of the background directly affect the results of subsequent processing steps. In this paper, the tube excitation component of X fluorescence spectrum is analyzed with an estimation method of background intensity against their background characteristics, and structuring theoretical spectral lines based on the measured spectral lines in order to evaluate the effect of spectral processing algorithms. The method utilizes the measured X-ray fluorescence spectrum which does not contain the characteristic peak of the spectrum, In order to estimate the composition of the original spectrum of the X-ray tube. It uses the spectrum that contains the continuous background for interpolating the entire measured spectrum, thereby avoiding overlapping the spectral characteristic peaks or improperly estimating full width at half maximum. This paper compared SNIP, Fourier transform method and the background subtraction method using the measured spectral lines. Using this method to estimate the background is closer to the theoretical background. The results showe that the method for X-ray fluorescence spectrum by X-ray tube excitation is accurate in this article, this method can be used to deduct continuous background, and good applied effectiveness has been achieved in the background subtraction of the actually measured X-ray fluorescence spectrometry.

[Rapid Determination of Cu and Zn in PM2.5 with Wavelength Dispersive X-Ray Fluorescence Spectrometry].

This paper proposes the analyzing method of adopting wavelength dispersive X-ray fluorescence spectrometry to measure the content of Cu and Zn in PM2.5. PTFE membrane is used to prepare standard samples and atmospheric particulate samples; a research into sample cup's structure，using polypropylene film of 6.7 µm to help to improved sample cup to package atmospheric particulate samples. The improved sample cup is used to measure the content of Cu and Zn in atmospheric particulate, which can obviously reduce background, improve peak/background ratio and decrease detection limit to target element; discussion is made on the measurement condition of Cu and Zn in PM2.5: taking Kα line as analysis line of Cu and Zn, selecting PX10 as analyzer crystal, using 300 µm pitch collimator, adopting scintillation detector for the Kα of Zn, applying the integrating of flow-gas proportional counter and closed-end proportional counter to the Kα of Cu, setting 50 kV, 50 mA as operating voltage and current. The prepared Cu and Zn standard sample is used to set up working curve, the results show that their linear correlations are better, accuracy are higher, relative standard deviations of Cu and Zn are 2.43% and 2.00%(n=8), detection limit are 0.028 and 0.021 µg·cm-2respectively, and analysis of the single sample only need 60 s. To sum up, this method can quickly and accurately analyze the content of Cu and Zn in PM2.5, and provide scientific basis for study the element content characteristics and source apportionment.

[Determination of 22 Elements in Herb Tea by X-Ray Fluorescence Spectrometry].

N, Na, Mg, Al, Si, P, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Ni, Cu, Zn, Br, Rb, Sr, Ba and Pb in herb tea were determined by X-ray fluorescence spectrometry with pressed powder pellets. The measuring conditions of target elements were investigated, including how to select its analytical line. In addition to Ba and Pb using L line, Kalpha line was selected for the rest. When the Compton scattered radiation of Rh Kalpha was measured, The X-ray tube voltage should be appropriately reduced, and the appropriate tube current should be selected. The matrix effect was corrected by empirical coefficient method and using scattered radiation (the Rayleigh scattered radiation of Rh Lalpha, the scattered background of 0.1876 nm wavelength position and the Compton scattered radiation of Rh Kalpha) as internal standard, and the spectral overlapping interference of some elements (N, Na, Ca, Ti, Mn, Sr and Ba) was corrected. For the target elements, the detection limit of this method was low, and its accuracy and precision were high. The results showed that there were abandon of elements in herb tea, of which different kinds had different components, even the same kind of herb tea with different source had some difference in element and content more or less, however, there was a lot of similarity between the features of its components. In a word, this method could achieve multi-element determination of herb tea, and it was simple in operation, low cost, rapid, and accurate.

[Research on the content prediction model for the determination of nickel in soil by portable energy dispersive X-ray fluorescence analyzer].

The present paper discusses the influence of matrix effect on measurement results when portable energy dispersive X-ray fluorescence analyzer is used for the determination of Ni in soil. Based on the scattered X-ray intensity of WL(alpha) emitted from the X-ray tube on the sample, a correction method was proposed, and it combines with the correction of absorption element, which can effectively overcome the matrix effect. The correlation coefficient of the content prediction model based on this method is 0.999 and the residual standard deviation is 2.541. The average relative error is 3.90 when the content prediction model is used to measure the content of Ni in the national standard soil samples, so the results coincide well with standard values, and the precision is high.