1.
J Chem Phys
; 126(3): 034511, 2007 Jan 21.
Artículo
en Inglés
| MEDLINE
| ID: mdl-17249888
RESUMEN
Experimental observation and time relaxation measurement of the hydrated proton Eigen form [H(3)O(+)(H(2)O)(3)] are presented here. Vibrational time-resolved spectroscopy is used with an original method of investigating the proton excess in water. The anharmonicity of the time-resolved spectra is characteristic of the Eigen-type proton geometry. Proton relaxation occurs in less than 200 fs. A calculation of the potential energy confirms the experimental result and the Eigen cation lifetime is in good agreement with previous molecular dynamics simulations.