1.
Org Lett
; 26(9): 1813-1818, 2024 Mar 08.
Artículo
en Inglés
| MEDLINE
| ID: mdl-38386925
RESUMEN
Herein, we present a novel Catellani-type reaction that employed aryl-thianthrenium salts as aryl substrates to trigger the subsequent palladium/norbornene cooperatively catalyzed progress. This strategy can achieve site-selective C-H difunctionalization of aryl compounds without directing groups or a known initiating reagent. A series of functionalized syntheses of bioactive molecules further demonstrated the potential of this strategy.