Directional Growth and Density Modulation of Single-Atom Platinum for Efficient Electrocatalytic Hydrogen Evolution.

Dispersion of single atoms (SAs) in the host is important for optimizing catalytic activity. Herein, we propose a novel strategy to tune oxygen vacancies in CeO2-X directionally anchoring the single atom platinum (PtSA), which is uniformly dispersed on the rGO. The catalyst's performance for the hydrogen evolution reaction (HER) can be enhanced by controlling different densities of CeO2-X in rGO. The PtSA performs best optimally densified and loaded on homogeneous and moderately densified CeO2-X/rGO (PtSA-M-CeO2-X/rGO). It exhibited high activity in HER with an overpotential of 25 mV at 0.5 M H2SO4 and 33 mV at 1 KOH than that of almost reported electrocatalysts. Furthermore, it exhibited stability for 90 hours at -100 mA cm-2 in 1 KOH and -150 mA cm-2 in 0.5 M H2SO4 conditions, respectively. Through comprehensive experiments and theoretical calculations, the suitable dispersion density of PtSA on the defects of CeO2-X with more active sites gives the potential for practical applications. This research paves the way for developing single-atom catalysts with exceptional catalytic activity and stability, holding promise in advanced green energy conversion through defects engineering.

Numerical and experimental investigations on quasi-static component generation of longitudinal wave propagation in isotropic pipes.

In this paper, the quasi-static component (QSC) generation of longitudinal waves propagating in an isotropic pipe is investigated numerically and experimentally. The three-dimensional (3D) finite element (FE) simulations are first carried out to gain physical insights into the characteristics of QSC generation from longitudinal wave travelling in an isotropic pipe with weak material nonlinearity. By applying the axial displacement excitation in the FE model, L(0, 1) mode and L(0, 2) mode are excited simultaneously. Then, the generated QSC pulses are extracted using the phase reversal approach for analysis. It is found that the QSC pulses generated by L(0, 2) mode and L(0, 1) mode are L(0, 1) mode. Meanwhile, the shapes of QSC pulses at different locations are extracted and compared. In this study, a data pre-processing method is proposed to handle numerically calculated and subsequent experimentally measured displacement signals, and a nonlinear acoustic parameter is defined to evaluate the incipient damages. After that, an experiment is conducted to measure the QSCs induced by the propagation of longitudinal waves in an aluminum pipe. The experimental results indicate that the propagation of longitudinal waves in the aluminum pipe can induce the QSCs. Different levels of corrosion are created on the surface of the aluminum pipe and are assessed by the generated QSCs. The results show that the nonlinear acoustic parameter has a monotonically increasing trend with the growing severity of corrosion. The QSCs generated by longitudinal wave can be used to detect and evaluate the early-stage surface corrosion in the aluminum pipe.

Confined Tri-Functional FeOx @MnO2 @SiO2 Flask Micromotors for Long-Lasting Motion and Catalytic Reactions.

H2 O2 -fueled micromotors are state-of-the-art mobile microreactors in environmental remediation. In this work, a magnetic FeOx @MnO2 @SiO2 micromotor with multi-functions is designed and demonstrated its catalytic performance in H2 O2 /peroxymonosulfate (PMS) activation for simultaneously sustained motion and organic degradation. Moreover, this work reveals the correlations between catalytic efficiency and motion behavior/mechanism. The inner magnetic FeOx nanoellipsoids primarily trigger radical species (• OH and O2 •- ) to attack organics via Fenton-like reactions. The coated MnO2 layers on FeOx surface are responsible for decomposing H2 O2 into O2 bubbles to provide a propelling torque in the solution and generating SO4 •- and • OH for organic degradation. The outer SiO2 microcapsules with a hollow head and tail result in an asymmetrical Janus structure for the motion, driven by O2 bubbles ejecting from the inner cavity via the opening tail. Intriguingly, PMS adjusts the local environment to control over-violent O2 formation from H2 O2 decomposition by occupying the Mn sites via inter-sphere interactions and enhances organic removal due to the strengthened contacts and Fenton-like reactions between inner FeOx and peroxides within the microreactor. The findings will advance the design of functional micromotors and the knowledge of micromotor-based remediation with controlled motion and high-efficiency oxidation using multiple peroxides.

Adaptively Weighted k-Tuple Metric Network for Kinship Verification.

Facial image-based kinship verification is a rapidly growing field in computer vision and biometrics. The key to determining whether a pair of facial images has a kin relation is to train a model that can enlarge the margin between the faces that have no kin relation while reducing the distance between faces that have a kin relation. Most existing approaches primarily exploit duplet (i.e., two input samples without cross pair) or triplet (i.e., single negative pair for each positive pair with low-order cross pair) information, omitting discriminative features from multiple negative pairs. These approaches suffer from weak generalizability, resulting in unsatisfactory performance. Inspired by human visual systems that incorporate both low-order and high-order cross-pair information from local and global perspectives, we propose to leverage high-order cross-pair features and develop a novel end-to-end deep learning model called the adaptively weighted k -tuple metric network (AW k -TMN). Our main contributions are three-fold. First, a novel cross-pair metric learning loss based on k -tuplet loss is introduced. It naturally captures both the low-order and high-order discriminative features from multiple negative pairs. Second, an adaptively weighted scheme is formulated to better highlight hard negative examples among multiple negative pairs, leading to enhanced performance. Third, the model utilizes multiple levels of convolutional features and jointly optimizes feature and metric learning to further exploit the low-order and high-order representational power. Extensive experimental results on three popular kinship verification datasets demonstrate the effectiveness of our proposed AW k -TMN approach compared with several state-of-the-art approaches. The source codes and models are released.1.

Carbon nitride-based Z-scheme heterojunctions for solar-driven advanced oxidation processes.

Solar-driven advanced oxidation processes (AOPs) via direct photodegradation or indirect photocatalytic activation of typical oxidants, such as hydrogen peroxide (H2O2), peroxymonosulfate (PMS), and peroxydisulfate (PDS), have been deemed to be an efficient technology for wastewater remediation. Artificial Z-scheme structured materials represent a promising class of photocatalysts due to their spatially separated charge carriers and strong redox abilities. Herein, we summarize the development of metal-free graphitic carbon nitride (g-C3N4, CN)-based direct and indirect Z-scheme photocatalysts for solar-driven AOPs in removing organic pollutants from water. In the work, the classification of AOPs, definition and validation of Z-schemes are summarized firstly. The innovative engineering strategies (e.g., morphology and dimensionality control, element doping, defect engineering, cocatalyst loading, and tandem Z-scheme construction) over CN-based direct Z-scheme structure are then examined. Rational design of indirect CN-based Z-scheme systems using different charge mediators, such as solid conductive materials and soluble ion pairs, is further discussed. Through examining the relationship between the Z-scheme structure and activity (charge transfer and separation, light absorption, and reaction kinetics), we aim to provide more insights into the construction strategies and structure modification on CN-based Z-schemes towards improving their catalytic performances in AOPs. Lastly, limitations, challenges, and perspectives on future development in this emerging field are proposed.

Kinetics and mechanism of synergistic adsorption and persulfate activation by N-doped porous carbon for antibiotics removals in single and binary solutions.

Porous carbon serves as a green material for efficient wastewater purification by adsorption and advanced oxidation processes. However, a clear understanding of the simultaneous removal of multiple pollutants in water is still ambiguous. Herein, the synergistic effect of adsorption and peroxydisulfate (PS) activation on kinetics and mechanism of removing single and binary antibiotic pollutants, sulfamethoxazole (SMX) and ibuprofen (IBP), from water by biomass-derived N-doped porous carbon was investigated. Our findings suggest that adsorption contributed to efficient removals of SMX/IBP. Comparative quenching experiments and electrochemical analysis demonstrated that hydroxyl (•OH) and sulfate (SO4•-) radicals, as well as singlet oxygen (1O2) led to the catalytic degradation of SMX, while only 1O2 reacted for IBP oxidation. Superoxide ion (O2•-) radicals were not related to SMX/IBP degradation. Electron transfer pathway accounted for PS activation but was not involved in direct SMX/IBP oxidation. Only slight differences were found between the degradation kinetics of SMX and IBP in the binary and single SMX or IBP solutions. This arose from the non-selective effect of adsorption and 1O2 attack for SMX/IBP removal, and the weak selective oxidation process of SMX by •OH and SO4•-. This study provides a new viewpoint on the role of adsorption in catalysis and enriches the mechanistic study of multi-component antibiotic degradation.

A practical biphasic contrast media injection protocol strongly enhances the aorta and pulmonary artery simultaneously using a single CT angiography scan.

BACKGROUND: Enhancement profiles of the pulmonary artery (PA) and aorta differ when using computed tomography (CT) angiography. Our aim was to determine the optimal CT protocol for a one-time CT scan that assesses both blood vessels. METHODS: We prospectively enrolled 101 cases of CT angiography in patients with suspected pulmonary embolism or aortic dissection from our center between 2018 and 2020. We also retrospectively collected the data of 40 patients who underwent traditional two-time CT scans between 2015 and 2018. Patients were divided into four groups: test bolus (TB) I, TB II, bolus-tracking (BT) I, and BT II. The enhancement of the PA and aorta, and the radiation doses used in the four groups were collected. Those who underwent two-time scans were classified into the traditional PA or aorta scan groups. Data were compared between the BT and traditional groups. RESULTS: The aortic enhancement was highest in BT II (294.78 ± 64.48 HU) followed BT I (285.18 ± 64.99 HU), TB II (186.58 ± 57.53 HU), and TB I (173.62 ± 69.70 HU). The radiation dose used was lowest in BT I (11.85 ± 5.55 mSv) and BT II (9.07 ± 3.44 mSv) compared with that used in the traditional groups (20.07 ± 7.78 mSv) and accounted for half of the traditional group (45.17-59.02%). The aortic enhancement was also highest in BT II (294.78 ± 64.48 HU) followed by BT I (285.18 ± 64.99 HU) when compared with that in the traditional aorta scan group (234.95 ± 94.18 HU). CONCLUSION: Our CT protocol with a BT technique allows for a lower radiation dose and better image quality of the PA and aorta than those obtained using traditional CT scans. TRIAL REGISTRATION: NCT04832633, retrospectively registered in April 2021 to the clinical trial registry.

Effects of hand placement, handles and support on manual holding tasks.

This study recruited 16 participants to examine the effects of hand placement, handles and support on the muscular activities of the musculus biceps brachii and erector spinae, box tilt angle and total center of pressure (CoP) length beneath the feet in manual holding tasks. Each participant was asked to hold a box in two hand placement conditions (symmetrical hand placement and asymmetrical hand placement) × two handle conditions (handles and no handles) × two support conditions (hands-and-body and hands). The results showed that symmetrical hand placement reduced the overall muscular activities of the musculus biceps brachii and erector spinae, box tilt angle and CoP length. The same results were also found in the handles condition and in the hands-and-body support condition. This study recommends that box designers should provide symmetrical handles, and people should keep the box against their front body while holding.

Enhanced removals of micropollutants in binary organic systems by biomass derived porous carbon/peroxymonosulfate.

Water pollution usually involves multiple pollutants, and their degradation mechanisms are complicated. In this study, we investigated the degradation of single and binary pollutants (phenol and p-hydroxybenzoic acid (HBA)) in water, using biomass-derived N-doped porous carbon (Y-PC) for peroxymonosulfate (PMS) activation and we found better kinetics and efficiencies of degradation in binary pollutants than single pollutant systems. Electron paramagnetic resonance (EPR), quenching experiments, and electrochemical tests indicated that •OH, SO4•-, O2•-, and 1O2 accounted for the catalytic oxidation of phenol/HBA, while the electron-transfer pathway had an additional contribution to phenol degradation. We unveiled that the HBA degradation rate was similar in the binary and single systems due to the non-selective attack of the micropollutants by •OH, SO4•-, O2•- and 1O2. However, phenol degradation rate was significantly accelerated in the binary phenol/HBA system as compared to that in the single phenol solution, due to the exclusive and selective role of electron transfer pathway. In the binary micropollutant system, a fortified electron-transfer pathway over phenol directly expedited its decomposition and contributed indirectly to this process. This study provides new insights into porous carbon-based advanced oxidation processes for the simultaneous removal of multicomponent contaminants in practical applications.

The well-designed hierarchical structure of Musa basjoo for supercapacitors.

Application of biological structure is one of the hottest topics in the field of science and technology. The unimaginable and excellent architectures of living beings supporting their vital activities have attracted the interests of worldwide researchers. An intriguing example is Musa basjoo which belongs to the herb, while appears like a tree. The profound mystery of structure and potential application of Musa basjoo have not been probed. Here we show the finding of the hierarchical structure of Musa basjoo and the outstanding electrochemical performance of the super-capacitors fabricated through the simple carbonization of Musa basjoo followed by KOH activation. Musa basjoo has three layers of structure: nanometer-level, micrometer-level and millimeter-level. The nanometer-level structure constructs the micrometer-level structure, while the micrometer-level structure constructs the millimeter-level structure. Based on this hierarchical structure, Musa basjoo reduces the unnecessary weight and therefore supports its huge body. The super-capacitors derived from Musa basjoo display a high specific capacitance and a good cycling stability. This enlightening work opens a window for the applications of the natural structure and we hope that more and more people could pay attention to the bio-inspired materials.

[Study on acute toxicity test of different processed products of Radix polygalae].

OBJECTIVE: To study the acute toxicity of the water extracts (ERWE) and 60% ethanol extracts (EREE) from different processed products of Radix Polygalae (crude Radix Polygalae, licorice, and honey processed Radix Polygalae), thus providing scientific evidence for toxicity study of Radix Polygalae and its safe clinical application. METHODS: The ERWE and EREE were prepared from different processed products of Radix Polygalae. Their contents of saponins were respectively determined. The poisoning condition and death of the mice administered with ERWE and EREE by gastrogavage were observed within fourteen days. The modified Karber's method was used to calculate LD50 and 95% confidence interval (CI). RESULTS: The EREE of licorice processed Radix Polygalae had the maximum toxicity with highest content of saponins, while the ERWE of honey processed Radix Polygalae had the minimum toxicity with lowest content of saponins. CONCLUSIONS: Different processing methods have effects on the contents of saponins in Radix Polygalae. The experiment showed that the toxicity of Radix Polygalae is in direct proportion to the content of saponins. The higher the saponins contents, the higher the toxicity.

Molecular characterization of Mycobacterium tuberculosis complex (MTBC) isolated from cattle in northeast and northwest China.

We studied throat swabs and corresponding serum samples collected from 1067 protein purified derivative (PPD)-tuberculin skin test (TST) positive cattle from different regions of China. The 1067 throat swabs were inoculated onto modified Löwenstein-Jensen medium for the isolation and culture of Mycobacteria. Acid-fast bacilli were identified using traditional biochemical methods, polymerase chain reaction (PCR) amplification and multiplex PCR. They were distinguished as Mycobacterium tuberculosis complex (MTBC) and non-tuberculous mycobacteria (NTM) strains. An indirect Enzyme-Linked Immunosorbent Assay (ELISA) was applied to detect specific antibodies against bovine TB (bTB). Correlations among the ELISA, bacteriology and TST were analyzed and compared. Spoligotyping and variable number tandem repeats-mycobacterial interspersed repetitive unit (VNTR-MIRU) analysis were used to genotype the MTBC. In total, 111 strains of Mycobacteria were cultured from the 1067 throat swab samples, including 43 stains of MTBC (14 strains of Mycobacterium bovis and 29 of Mycobacterium tuberculosis) and 68 strains of NTM. Thirty-eight MTBC strains and four NTM strains were isolated from 72 throat swab samples that the ELISA determined were antibody positive; five MTBC strains and 64 NTM strains were isolated from 995 throat swab samples that were antibody negative on the ELISA. The positive isolation rates of MTBC and NTM were 38.7% (43/111) and 61.3% (68/111), respectively. The concordance rate of cultured MTBC with a positive result on the indirect ELISA for antibody was 52.8% (38/72), which was much higher than the positive rate for TST (4.0%; 43/1067). Genotyping of the 43 strains of MTBC isolated, using spoligotyping and VNTR-MIRU, showed that the 43 isolates had 26 genotypes; 16 strains had a unique genotype. Two groups of six strains and two strains, respectively, showed the same spoligotyping pattern, and belonged to the Beijing family and Beijing-like family, respectively. Combined application of spoligotyping and VNTR-MIRU typing would improve the molecular epidemiological investigation and monitoring of the etiology of bTB in China.