NiCo-LDH coupled with 2D ZIF-derived Co nitrogen doped carbon nanosheet arrays as a self-supporting electrocatalyst for detection of formaldehyde.

Formaldehyde is susceptible to illegal addition to foodstuffs to extend their shelf life due to its antimicrobial, preservative and bleaching properties. In this study, a self-supporting "nanosheet on nanosheet" arrays electrocatalyst with core-shell heterostructure was prepared in situ by coupling NiCo layer double hydroxide with 2D ZIF derived Co-nitrogen-doped porous carbon on carbon cloth (Co-N/C@NiCo-LDH NSAs/CC). Co-N/C nanosheet arrays act as a scaffold core with good electrical conductivity, providing more NiCo-LDH nucleation sites to avoid NiCo-LDH agglomeration, thus having fast mass/charge transfer performance. While the NiCo-LDH nanosheet arrays shell with high specific surface area provide more active sites for electrochemical reactions. As an electrocatalytic sensing electrode, Co-N/C@NiCo-LDH NSAs/CC has a wide linear range of 1 µM to 13 mM for formaldehyde detection, and the detection limit is 82 nM. Besides, the sensor has been applied to the detection of formaldehyde in food samples with satisfactory results.

A novel hollow CuMn-PBA@NiCo-LDH nanobox for efficient detection of glucose in food.

Designing a rapid and sensitive glucose detection method is of great significance to public health. Herein, hollow CuMn-PBA@NiCo-LDH nanoboxes (CuMn-PBA@NiCo-LDH NBs) were prepared using acid etching, cation exchange, and reflux method. The modified electrode exhibited outstanding electrocatalytic performance for glucose oxidation due to the unique hollow nanostructure and synergistic effects. The CuMn-PBA@NiCo-LDH NBs electrode displayed excellent electrocatalytic oxidation activity for glucose in an alkaline solution. Under optimal conditions, the electrode achieved a wide linear range (0.0005-1 mmol L-1, and 1-7 mmol L-1) and high sensitivity (10,300 µA L/mmol cm-2 and 5310 µA L/mmol cm-2), with a limit of detection (LOD) of 19 nmol L-1. The feasibility of the sensor applied to the detection of glucose was verified in real food samples through spiked recovery experiments. This electrode material offers an alternative method for the non-enzymatic glucose sensors.

Microplasma and quenching-induced Co doped NiMoO4 nanorods with oxygen vacancies for electrochemical determination of glucose in food and serum.

In this paper, Co-doped NiMoO4 nanorods with oxygen vacancies are synthesized on carbon cloth (Co-NiMoO4 NRs/CC) via microplasma and quenching-induced method.Owing to the surface defects and metal ion doping, the electronic structure and surface properties of the catalyst are tuned.Cyclic voltammetry (CV) and amperometry are used to investigate the electrocatalytic behavior of the glucose sensor in an alkaline medium with sensitivities of 7411 and 3125 µA L mmol-1 cm-2 in the linear range 1.0 µmol L-1 to 1.0 mmol L-1 and 1.0 mmol L-1 to 7.0 mmol L-1, respectively. The detection limit is 0.079 µmol L-1 at S/N = 3. Moreover, the as-prepared catalyst electrode is also successfully used in real food and serum samples, with a recovery rate of 97.1%-107.4%.The DFT calculations show that the Co site of the catalyst significantly influenced glucose sensing performance. This idea expands the application of quenching chemistry in electrochemical sensing.

One-step rapid synthesis of Ni0.5Co0.5-CPO-27 nanorod array with oxygen vacancies based on DBD microplasma: As an effective non-enzymatic glucose sensor for beverage and human serum.

The rational design of high-efficiency catalysts for non-enzymatic glucose sensing is extremely important for the timely and effective monitoring of glucose content in beverages and human blood. A 3D bimetallic organic framework (Coordination Polymer of Oslo, CPO) nanorod array with oxygen vacancies was green fabricated on carbon cloth (Ni0.5Co0.5-CPO-27 NRA/CC) using dielectric barrier discharge (DBD) microplasma for the first time. Density functional theory (DFT) calculations demonstrated that the oxygen vacancy of Ni0.5Co0.5-CPO-27 can be effectively induced under DBD microplasma conditions. Based on the 3D nanorod arrays with rich oxygen vacancies and bimetallic synergistic effects, as a non-enzyme glucose sensor, the Ni0.5Co0.5-CPO-27 electrode exhibited a sensitivity of 8499.5 µA L/mmol cm-2 and 3239.2 µA L/mmol cm-2 and a limit of detection (LOD) of 0.16 µmol/L (S/N = 3). It has been successfully applied to the determination of glucose levels in real samples such as cola, green tea and human serum.