Node deployment optimization of underwater wireless sensor networks using intelligent optimization algorithm and robot collaboration.

This study aims to optimize the node deployment of underwater wireless sensor networks (UWSNs) using intelligent optimization algorithms and robot collaboration technology to enhance network performance and coverage. The study employs the chemical reaction optimization (CRO) algorithm, which combines the advantages of genetic algorithms, simulated annealing algorithms, and ant colony algorithms. The CRO algorithm is enhanced through a structure correction function to determine the optimal node deployment scheme to achieve effective and optimal coverage control of the UWSN. Additionally, the flexibility and autonomy of robots are leveraged to improve the efficiency of node deployment and address the unique challenges posed by the underwater environment. Furthermore, the study conducts a comparative analysis of different intelligent optimization algorithms and demonstrates the effectiveness and advantages of the enhanced CRO algorithm in optimizing node deployment for UWSNs. The study findings reveal that the improved algorithm achieves an average coverage rate of 95.66%, significantly outperforming traditional intelligent optimization algorithms. The coverage of UWSNs can be significantly improved by utilizing the enhanced CRO algorithm and robot collaboration technology for node deployment optimization, which offers an effective approach for achieving optimal node deployment. Moreover, the rational deployment of nodes enhances the monitoring capability, resource utilization efficiency, and accuracy of environmental monitoring in underwater networks. The results of this study hold great practical significance for underwater environment monitoring, marine resource exploration, and marine scientific research.

Application of a green coagulant with PACl in efficient purification of turbid water and its mechanism study.

The applications of natural polymeric flocculants due to their green feature has been recently received much more attention. In this work, the combined usages of a cationic starch-based coagulant and polyaluminum chloride (PACl) were extensively evaluated for various addition sequences in the coagulation of both raw (surface water from the Jiuxiang River) and synthetic turbid water (two kaolin suspensions with different initial turbidities). Two typical cationic starch-based coagulants with different structures (St-G and St-E) were tried. In comparison to St-G, St-E and PACl used individually as well as St-G and St-E dosed after PACl, the combination of the starch-based coagulants fed before PACl showed higher turbidity removal efficiency, which featured not only less optimal doses of both inorganic and organic coagulants but also lower residual turbidity. On the basis of a detailed analysis of the particle size and its distribution in solution supernatants before and after coagulation by two starch-based coagulants and PACl, polymeric coagulants preferentially coagulate the small-sized colloids due to their distinct long-chain structures, but PACl preferentially coagulates the medium-sized ones. Thus, the medium-sized particles that were previously formed by the starch-based coagulants would be collectively and effectively removed by the subsequent addition of PACl. The addition sequence of the inorganic and organic coagulants in their combined usage is an important factor for improvement of the turbidity removal efficiency in practice.

Enhanced coagulation of low-turbidity micro-polluted surface water: Properties and optimization.

Micro-polluted surface water with low turbidity and low content of dissolved organic matter (DOM) is usually inefficiently purified. In this work, a combined technique for the enhanced coagulation of this surface water was proposed and investigated using cationic grafted starch (St-G) and polyaluminum chloride (PACl) as co-coagulants, followed by a magnetic ion-exchange resin (MIER). St-G was fed before PACl, and this procedure not only efficiently removes turbidity but also largely reduces the doses of the two coagulants. MIER remarkably removed DOM, and raw water was effectively purified. The entire coagulation process was further optimized through response surface methodology based on a central composite design by using the doses of St-G, PACl, and MIER as input variables. The dose effects of the three chemicals on the coagulation performance for turbidity and DOM removal were examined, and the coagulation mechanisms, including the interactive effect among various chemicals, were discussed in detail. This work provided a new strategy for the efficient treatment of low-turbidity micro-polluted surface water by utilizing organic and inorganic co-coagulants with magnetic ion-exchange resin in practical applications.

Flocculation and antimicrobial properties of a cationized starch.

In this study, a series of cationized starch-based flocculants (starch-3-chloro-2-hydroxypropyl triethyl ammonium chloride, St-CTA) containing various quaternary ammonium salt groups on the starch backbone were prepared using a simple etherification reaction. All of the prepared starch-based flocculants show effective performance for the flocculation of kaolin suspension, two bacterial (Escherichia coli and Staphylococcus aureus) suspensions, and two contaminant mixtures (kaolin and each bacterium) under most pH conditions. St-CTA with a high substitution degree of CTA demonstrates improved contaminant removal efficiency because of the strong cationic nature of the grafted quaternary ammonium salt groups and the charge naturalization flocculation effect. The antibacterial effects of St-CTA were also evaluated, considering that many quaternary ammonium salt compounds elicit bactericidal effects. Three-dimensional excitation-emission matrix spectra and direct cell morphological observation under scanning electron microscopy reveal that the starch-based flocculants exhibit better antibacterial effects on the Gram-negative bacterium E. coli than on the Gram-positive bacterium S. aureus. The thicker cell wall due to the presence of abundant peptidoglycan and teichoic acids of S. aureus than E. coli explains the uneasy breakage of S. aureus cell wall after being attacked by the cationized starch-based flocculants.

Evaluation of structural effects on the flocculation performance of a co-graft starch-based flocculant.

The molecular structure of a material substantially determines its final application performance. In this work, a series of starch-based flocculants with different charge densities and average graft chain lengths were prepared by the co-graft polymerization of acrylamide and [(2-methacryloyloxyethyl) trimethyl ammonium chloride] (St-g-PAM-co-PDMC). The flocculation performance of St-g-PAM-co-PDMC was studied systematically at neutral pH using kaolin suspension and sodium humate (NaHA) aqueous solution as synthetic wastewaters. The effects of the two structural factors on the flocculation efficiency of the starch-based flocculants have been investigated. The experimental results showed that the charge density and average graft chain length contributed distinctly to flocculation performance during the removal of both kaolin particles and NaHA under insufficient and excessive flocculant dose conditions. The flocculation mechanisms of this starch-based flocculant were discussed in detail on the basis of the structure-activity relationship, which are significant to optimize the flocculation conditions and guide the development of novel high-performance flocculants.

Dual functionality of a graft starch flocculant: Flocculation and antibacterial performance.

In this work, a series of quaternary ammonium salt grafted starch flocculant, starch-graft-poly(2-methacryloyloxyethyl) trimethyl ammonium chloride (St-g-PDMC), with different grafting ratios was prepared by a simple method. Various characterization techniques were employed to investigate the structure and charge property of the starch-based flocculants. The efficiencies of St-g-PDMC for flocculation of kaolin and Escherichia coli suspensions as well as their mixtures were systematically examined in laboratory scale. In addition to environmental factors, such as flocculant dose and pH, the effects of grafting ratio were also evaluated. Results indicated that St-g-PDMCs exhibited dual functionality of high flocculation effects and antibacterial properties. Moreover, the flocculation and antibacterial mechanisms were investigated in detail based on apparent flocculation performance, charge properties, floc structures (floc size and its two-dimensional fractal dimension), and cell surface morphology, respectively.

Evaluation of starch-based flocculants for the flocculation of dissolved organic matter from textile dyeing secondary wastewater.

China is a major textile manufacturer in the world; as a result, large quantities of dyeing effluents are generated every year in the country. In this study, the performances of two cationic starch-based flocculants with different chain architectures, i.e., starch-graft-poly[(2-methacryloyloxyethyl) trimethyl ammonium chloride] (STC-g-PDMC) and starch-3-chloro-2-hydroxypropyl trimethyl ammonium chloride (STC-CTA), in flocculating dissolved organic matter (DOM) in dyeing secondary effluents were investigated and compared with that of polyaluminum chloride (PAC). In the exploration of the flocculation mechanisms, humic acid (HA) and bovine serum albumin (BSA) were selected as main representatives of DOM in textile dyeing secondary effluents, which were humic/fulvic acid-like and protein-like extracellular matters according to the studied wastewater's characteristics based on its three-dimensional excitation-emission matrix spectrum. According to experimental results of the flocculation of both the real and synthetic wastewaters, STC-g-PDMC with cationic branches had remarkable advantages over STC-CTA and PAC because of the more efficient charge neutralization and bridging flocculation effects of STC-g-PDMC. Another interesting finding in this study was the reaggregation phenomenon after restabilization at an overdose during the flocculation of BSA effluents by STC-g-PDMC at a very narrow pH range under a nearly neutral condition. This phenomenon might be ascribed to the formation of STC-g-PDMC/BSA complexes induced by some local charge interactions between starch-based flocculant and the amino acid fragments of protein due to charge patch effects.

Evaluation of chain architectures and charge properties of various starch-based flocculants for flocculation of humic acid from water.

Three different starch-based flocculants with various chain architectures and charge properties have been prepared through etherification, graft copolymerization, or their combination. Two of the flocculants (starch-graft-poly[(2-methacryloyloxyethyl) trimethyl ammonium chloride] and starch-3-chloro-2-hydroxypropyl triethyl ammonium chloride, denoted as STC-g-PDMC and STC-CTA respectively) are cationic, and another one (carboxymethyl starch-graft-poly[(2-methacryloyloxyethyl) trimethyl ammonium chloride], denoted as CMS-g-PDMC) is amphoteric. Those three flocculants have shown far different flocculation efficiency and floc properties for the removal of humic acid (HA) from water due to their distinct structural features. The effects of pH, flocculant dose, and initial HA concentration have been studied systematically. Accordingly, STC-g-PDMC and CMS-g-PDMC with strongly cationic branch chains have much better flocculation performance than polyaluminum chloride (PAC) and STC-CTA, the latter of which features linear chain architecture and strongly cationic pieces lying on its chain backbone. It indicates that the architecture of cationic branch chains plays an important role in HA flocculation due to their significantly enhanced bridging effects. Moreover, STC-g-PDMC has higher HA removal efficiency and better floc properties than CMS-g-PDMC, suggesting that charge neutralization effects make notable contributions to HA removal and that the additional anionic pieces on CMS-g-PDMC can weaken its flocculation performance. In addition, STC-g-PDMC used as coagulant aid for PAC has also been tried, which observably reduces the optimal dose of the inorganic coagulant.

Three-dimensional graphene/Pt nanoparticle composites as freestanding anode for enhancing performance of microbial fuel cells.

Microbial fuel cells (MFCs) are able to directly convert about 50 to 90% of energy from oxidation of organic matters in waste to electricity and have great potential application in broad fields such as wastewater treatment. Unfortunately, the power density of the MFCs at present is significantly lower than the theoretical value because of technical limitations including low bacteria loading capacity and difficult electron transfer between the bacteria and the electrode. We reported a three-dimensional (3D) graphene aerogel (GA) decorated with platinum nanoparticles (Pt NPs) as an efficient freestanding anode for MFCs. The 3D GA/Pt-based anode has a continuous 3D macroporous structure that is favorable for microorganism immobilization and efficient electrolyte transport. Moreover, GA scaffold is homogenously decorated with Pt NPs to further enhance extracellular charge transfer between the bacteria and the anode. The MFCs constructed with 3D GA/Pt-based anode generate a remarkable maximum power density of 1460 mW/m(2), 5.3 times higher than that based on carbon cloth (273 mW/m(2)). It deserves to be stressed that 1460 mW/m(2) obtained from the GA/Pt anode shows the superior performance among all the reported MFCs inoculated with Shewanella oneidensis MR-1. Moreover, as a demonstration of the real application, the MFC equipped with the freestanding GA/Pt anode has been successfully applied in driving timer for the first time, which opens the avenue toward the real application of the MFCs.