RESUMEN
Risk assessment of pesticide impacts on remote ecosystems makes use of model-estimated degradation in air. Recent studies suggest these degradation rates to be overestimated, questioning current pesticide regulation. Here, we investigated the concentrations of 76 pesticides in Europe at 29 rural, coastal, mountain, and polar sites during the agricultural application season. Overall, 58 pesticides were observed in the European atmosphere. Low spatial variation of 7 pesticides suggests continental-scale atmospheric dispersal. Based on concentrations in free tropospheric air and at Arctic sites, 22 pesticides were identified to be prone to long-range atmospheric transport, which included 15 substances approved for agricultural use in Europe and 7 banned ones. Comparison between concentrations at remote sites and those found at pesticide source areas suggests long atmospheric lifetimes of atrazine, cyprodinil, spiroxamine, tebuconazole, terbuthylazine, and thiacloprid. In general, our findings suggest that atmospheric transport and persistence of pesticides have been underestimated and that their risk assessment needs to be improved.
RESUMEN
As part of the Dynamics-Aerosol-Chemistry-Cloud Interactions in West Africa (DACCIWA) project, extensive in-situ measurements of the southern West African atmospheric boundary layer (ABL) have been performed at three supersites Kumasi (Ghana), Savè (Benin) and Ile-Ife (Nigeria) during the 2016 monsoon period (June and July). The measurements were designed to provide data for advancing our understanding of the relevant processes governing the formation, persistence and dissolution of nocturnal low-level stratus clouds and their influence on the daytime ABL in southern West Africa. An extensive low-level cloud deck often forms during the night and persists long into the following day strongly influencing the ABL diurnal cycle. Although the clouds are of a high significance for the regional climate, the dearth of observations in this region has hindered process understanding. Here, an overview of the measurements ranging from near-surface observations, cloud characteristics, aerosol and precipitation to the dynamics and thermodynamics in the ABL and above, and data processing is given. So-far achieved scientific findings, based on the dataset analyses, are briefly overviewed.
RESUMEN
In recent years, we developed a small, unmanned aerial system (UAS) called OVLI-TA (Objet Volant Leger Instrumentéâ»Turbulence Atmosphérique) dedicated to atmospheric boundary layer research, in Toulouse (France). The device has a wingspan of 2.60 m and weighed 3.5 kg, including payload. It was essentially developed to investigate turbulence in a way complementary to other existing measurement systems, such as instrumented towers/masts. OVLI-TA's instrumental package includes a 5-hole probe on the nose of the airplane to measure attack and sideslip angles, a Pitot probe to measure static pressure, a fast inertial measurement unit, a GPS receiver, as well as temperature and moisture sensors in specific housings. In addition, the Pixhawk autopilot is used for autonomous flights. OVLI-TA is capable of profiling wind speed, wind direction, temperature, and humidity up to 1 km altitude, in addition to measuring turbulence. After wind tunnel calibrations, flight tests were conducted in March 2016 in Lannemezan (France), where there is a 60-m tower equipped with turbulence sensors. In July 2016, OVLI-TA participated in the international project DACCIWA (Dynamics-Aerosol-Chemistry-Clouds Interactions in West Africa), in Benin. Comparisons of the OVLI-TA observations with both the 60 m tower measurements and the radiosonde profiles showed good agreement for the mean values of wind, temperature, humidity, and turbulence parameters. Moreover, it validated the capacity of the drone to sample wind fluctuations up to a frequency of around 10 Hz, which corresponds to a spatial resolution of the order of 1 m.
