Real space iterative reconstruction for vector tomography (RESIRE-V).

Tomography has had an important impact on the physical, biological, and medical sciences. To date, most tomographic applications have been focused on 3D scalar reconstructions. However, in some crucial applications, vector tomography is required to reconstruct 3D vector fields such as the electric and magnetic fields. Over the years, several vector tomography methods have been developed. Here, we present the mathematical foundation and algorithmic implementation of REal Space Iterative REconstruction for Vector tomography, termed RESIRE-V. RESIRE-V uses multiple tilt series of projections and iterates between the projections and a 3D reconstruction. Each iteration consists of a forward step using the Radon transform and a backward step using its transpose, then updates the object via gradient descent. Incorporating with a 3D support constraint, the algorithm iteratively minimizes an error metric, defined as the difference between the measured and calculated projections. The algorithm can also be used to refine the tilt angles and further improve the 3D reconstruction. To validate RESIRE-V, we first apply it to a simulated data set of the 3D magnetization vector field, consisting of two orthogonal tilt series, each with a missing wedge. Our quantitative analysis shows that the three components of the reconstructed magnetization vector field agree well with the ground-truth counterparts. We then use RESIRE-V to reconstruct the 3D magnetization vector field of a ferromagnetic meta-lattice consisting of three tilt series. Our 3D vector reconstruction reveals the existence of topological magnetic defects with positive and negative charges. We expect that RESIRE-V can be incorporated into different imaging modalities as a general vector tomography method. To make the algorithm accessible to a broad user community, we have made our RESIRE-V MATLAB source codes and the data freely available at https://github.com/minhpham0309/RESIRE-V .

Upcycling of Carbon Fiber/Thermoset Composites into High-Performance Elastomers and Repurposed Carbon Fibers.

Recycling of carbon fiber-reinforced polymer composites (CFRCs) based on thermosetting plastics is difficult. In the present study, high-performance CFRCs are fabricated through complexation of aromatic pinacol-cross-linked polyurethane (PU-AP) thermosets with carbon fiber (CF) cloths. PU-AP thermosets exhibit a breaking strength of 95.5 MPa and toughness of 473.6 MJ m-3 and contain abundant hydrogen-bonding groups, which can have strong adhesion with CFs. Because of the high interfacial adhesion between CF cloths and PU-AP thermosets and high toughness of PU-AP thermosets, CF/PU-AP composites possess a high tensile strength of >870 MPa. Upon heating in N,N-dimethylacetamide (DMAc) at 100 °C, the aromatic pinacols in the CF/PU-AP composites can be cleaved, generating non-destructive CF cloths and linear polymers that can be converted to high-performance elastomers. The elastomers are mechanically robust, healable, reprocessable, and damage-resistant with an extremely high tensile strength of 74.2 MPa and fracture energy of 149.6 kJ m-2. As a result, dissociation of CF/PU-AP composites enables the recovery of reusable CF cloths and high-performance elastomers, thus realizing the upcycling of CF/PU-AP composites.

Construct Robust Epitaxial Growth of (101) Textured Zinc Metal Anode for Long Life and High Capacity in Mild Aqueous Zinc-Ion Batteries.

Aqueous zinc-metal batteries are considered to have the potential for energy storage due to their high safety and low cost. However, the practical applications of zinc batteries are limited by dendrite growth and side reactions. Epitaxial growth is considered an effective method for stabilizing Zn anode, especially for manipulating the (002) plane of deposited zinc. However, (002) texture zinc is difficult to achieve stable cycle at high capacity due to its large lattice distortion and uneven electric field distribution. Here, a novel zinc anode with highly (101) texture (denoted as (101)-Zn) is constructed. Due to unique directional guidance and strong bonding effect, (101)-Zn can achieve dense vertical electroepitaxy in near-neutral electrolytes. In addition, the low grain boundary area inhibits the occurrence of side reactions. The resultant (101)-Zn symmetric cells exhibit excellent stability over 5300 h (4 mA cm-2 for 2 mAh cm-2 ) and 330 h (15 mA cm-2 for 10 mAh cm-2 ). Meanwhile, the cycle life of Zn//MnO2 full cell is meaningfully improved over 1000 cycles.

Acid-Cleavable Aromatic Polymers for the Fabrication of Closed-Loop Recyclable Plastics with High Mechanical Strength and Excellent Chemical Resistance.

Although closed-loop recycling of dynamic covalent bond-based plastics does not require catalysts, their mechanical strength and chemical stability remain a major concern. In this study, closed-loop recyclable poly(aryl imine) (PAI) plastics with high mechanical strength and excellent chemical resistance are fabricated by copolymerizing aromatic amines and aromatic aldehydes through dynamic imine bonds. The resulting PAI plastic with a tensile strength of 58.2 MPa exhibits excellent chemical resistance and mechanical stability in acidic and basic aqueous solutions and various organic solvents. The PAI plastics can be depolymerized in a mixed solvent of tetrahydrofuran (THF)/HCl aqueous solution through the dissociation of imine bonds, and the monomers can be facilely recovered with high purity and isolated yields due to the solubility difference between the aromatic amines and aromatic aldehydes in selective solvents. The efficient closed-loop recycling of the PAI plastic can also be realized through monomer conversion because the hydrolysis of the aromatic aldehydes generates aromatic amines. The recovered monomers can be used to re-fabricate original PAI plastics. This PAI plastic can be selectively recovered from complicated mixed polymer waste streams due to the mild depolymerization conditions of the PAI plastic and its high stability in most organic solvents.

Unlocking the Capacity of Bismuth Oxide by a Redox Mediator Strategy for High-Performance Aqueous Zn-Ion Batteries.

Many cathode materials store zinc ions based on the intercalation reaction mechanism in neutral aqueous Zn-ion batteries, and the structural design of the cathodes has been stuck in the curing mode by extending the ion diffusion channel. Here, we first develop halide ions to unlock the electrochemical activity of conversion-type Bi2O3 in aqueous Zn-ion batteries. Notably, the iodide ion shows the best performance compatibility with the Bi2O3 cathode. The electrochemical reaction mechanism studies show that iodide ions can be regarded as a redox medium to reduce the charge-transfer activation energy and motivate the conversion of Bi2O3 from Bi3+ to Bi0 during the cycle. Unsurprising, the discharge-specific capacity can reach 436.8 mAh g-1 at 0.5 A g-1 and achieve a cyclic lifespan of 6000 cycles at a current density of 3 A g-1. The activation of the Bi2O3 conversion reaction by iodide ions is of great significance for broadening the research range of ZIB cathode materials.

Coherence singularity and evolution of partially coherent Bessel-Gaussian vortex beams.

For a partially coherent Bessel-Gaussian (PCBG) vortex beam, information regarding the topological charge (TC) is hidden in the phase of the cross-spectral density (CSD) function. We theoretically and experimentally confirmed that during free-space propagation, the number of coherence singularities is equal to the magnitude of the TC. In contrast to the Laguerre-Gaussian vortex beam, this quantitative relationship only holds for the case with an off-axis reference point for the PCBG vortex beam. The phase winding direction is determined by the sign of the TC. We developed a scheme for CSD phase measurement of PCBG vortex beams and verified the aforementioned quantitative relationship at different propagation distances and coherence widths. The findings of this study may be useful for optical communications.

Engineering of Chain Rigidity and Hydrogen Bond Cross-Linking toward Ultra-Strong, Healable, Recyclable, and Water-Resistant Elastomers.

High-performance elastomers have gained significant interest because of their wide applications in industry and our daily life. However, it remains a great challenge to fabricate elastomers simultaneously integrating ultra-high mechanical strength, toughness, and excellent healing and recycling capacities. In this study, ultra-strong, healable, and recyclable elastomers are fabricated by dynamically cross-linking copolymers composed of rigid polyimide (PI) segments and soft poly(urea-urethane) (PUU) segments with hydrogen bonds. The elastomers, which are denoted as PIPUU, have a record-high tensile strength of ≈142 MPa and an extremely high toughness of ≈527 MJ m-3 . The structure of the PIPUU elastomer contains hydrogen-bond-cross-linked elastic matrix and homogenously dispersed rigid nanostructures. The rigid PI segments self-assemble to generate phase-separated nanostructures that serve as nanofillers to significantly strengthen the elastomers. Meanwhile, the elastic matrix is composed of soft PUU segments cross-linked with reversible hydrogen bonds, which largely enhance the strength and toughness of the elastomer. The dynamically cross-linked PIPUU elastomers can be healed and recycled to restore their original mechanical strength. Moreover, because of the excellent mechanical performance and the hydrophobic PI segments, the PIPUU elastomers are scratch-, puncture-, and water-resistant.

Three-dimensional topological magnetic monopoles and their interactions in a ferromagnetic meta-lattice.

Topological magnetic monopoles (TMMs), also known as hedgehogs or Bloch points, are three-dimensional (3D) non-local spin textures that are robust to thermal and quantum fluctuations due to the topology protection1-4. Although TMMs have been observed in skyrmion lattices1,5, spinor Bose-Einstein condensates6,7, chiral magnets8, vortex rings2,9 and vortex cores10, it has been difficult to directly measure the 3D magnetization vector field of TMMs and probe their interactions at the nanoscale. Here we report the creation of 138 stable TMMs at the specific sites of a ferromagnetic meta-lattice at room temperature. We further develop soft X-ray vector ptycho-tomography to determine the magnetization vector and emergent magnetic field of the TMMs with a 3D spatial resolution of 10 nm. This spatial resolution is comparable to the magnetic exchange length of transition metals11, enabling us to probe monopole-monopole interactions. We find that the TMM and anti-TMM pairs are separated by 18.3 ± 1.6 nm, while the TMM and TMM, and anti-TMM and anti-TMM pairs are stabilized at comparatively longer distances of 36.1 ± 2.4 nm and 43.1 ± 2.0 nm, respectively. We also observe virtual TMMs created by magnetic voids in the meta-lattice. This work demonstrates that ferromagnetic meta-lattices could be used as a platform to create and investigate the interactions and dynamics of TMMs. Furthermore, we expect that soft X-ray vector ptycho-tomography can be broadly applied to quantitatively image 3D vector fields in magnetic and anisotropic materials at the nanoscale.

Superhydrophobic MXene Coating with Biomimetic Structure for Self-Healing Photothermal Deicing and Photoelectric Detector.

Two-dimensional transition metal carbides (Ti3C2Tx MXene) have emerged as new candidates for applications in multifunctional devices owing to their outstanding performance. However, these electronic devices are easily disturbed by water, breakage, oxidation during use, and limited energy resources. To solve these problems, herein, inspired by nature, a novel superhydrophobic, healable photothermal deicing and photodetector (SHPP) with a "papillary structure" is successfully fabricated for the first time, by a simple layer-by-layer assembly spraying process with 0D/1D/2D nanomaterials. As a result, the superhydrophobic modified 2D MXene coating (FM coating) on the SHPP sensor exhibits outstanding self-cleaning, long-term durability (>20 days), as well as excellent photothermal deicing performances under near-infrared light. Meanwhile, the unique semiembedded nano-ZnO/1D silver nanowire supports the sensor with desirable photoelectric performance with UV light and a fast response time (∼1 s), and good cycle stability. Moreover, benefiting from the transparent self-healing substrate, the photothermal deicing and photodetector properties can be restored at room temperature. The bioinspired structures and function mechanisms offer SHPP sensors great potential for the utilization of clean light energy, sensing, self-cleaning, anti-icing, and so forth.

Statistical properties of a partially coherent vector beam with controllable spatial coherence, vortex phase, and polarization.

We report on a partially coherent radially polarized power-exponent-phase vortex (PC-RP-PEPV) beam with various distributions of intensity, controllable coherence width, vortex phase, and polarization. The statistical properties of the PC-RP-PEPV beam depend on topological charge, power order, polarization states, and coherence width, which differ from those of conventional radially polarized beams. Here, the initial radial polarization state will transform to complex ellipse polarization state during propagation. By modulating the topological charge of the PC-RP-PEPV beam, the intensity structure of the beam can be adjusted from circular to polygonal. Finally, PC-RP-PEPV beams were experimentally generated, and were consistent with numerical simulation results. This work has applications in optical manipulation, optical measurements, and optical information processing.

Facile Preparation of Dual Functional Wearable Devices Based on Hindered Urea Bond-Integrated Reprocessable Polyurea and AgNWs.

With the advancement of material science and electronic technology, wearable devices have been integrated into daily lives, no longer just a stirring idea in science fiction. In the future, robust multifunctionalized wearable devices with low cost and long-term service life are urgently required. However, preparing multifunctional wearable devices robust enough to resist harsh conditions using a commercially available raw material through a simple process still remains challenging. In this work, reprocessable polyurea (HUBTPU) with a hard segment of hindered urea bonds (HUBs) and a soft segment of polyether is synthesized via a facile one-pot method. The robust dual functional wearable devices were obtained by simply spray-coating silver nanowires (AgNWs) on HUBTPU elastomer substrates. Due to the dynamic combination and decomposition of the HUBs and hydrogen bonds at 130 °C, the robust elastomer demonstrates favorable adhesion to various substrates. Especially, the partially embedded AgNW structure is also achieved by using ethanol as a spray solvent. The adhesion of HUBTPU substrates and embedded structure leads to stronger interfacial adhesion and stability compared to non-adhesive substrates. The as-obtained HUBTPU electrodes are able to be heated to 115 °C by applying a low voltage and sensing the strain deformation caused by human movement, which means that the electrodes are endowed with both electrical heating capability and strain sensing functionality. Therefore, this strategy reveals a potential way to prepare multifunctional wearable devices using other conductive particles and adhesive functional polymer substrates.

Microscopic phase reconstruction of cervical exfoliated cell under partially coherent illumination.

Basic coherent diffraction imaging methods strongly rely on having a highly coherent illumination in order to reconstruct the phase accurately. However, regardless of considering the turbulent transport medium, the instability of the system or the generation mechanism of the light source, partially coherent illumination is more common in real case. In this paper, we proposed an efficient microscopic phase imaging method to study normal and abnormal cervical exfoliated cells. By applying three phase modulations in a single point of the sample's transmitted field, the phase can be retrieved with correspoding three intensities under partially coherent illumination. Compared with intensity map, we can efficiently and clearly judge the proportion of high density shrinking abnormal cells from the phase distributions, which provides a confident analysis and evaluation basis for early medical diagnosis of cervical cancer. This study also has potential applications in noninvasive optical imaging of dynamic biological tissues.

Young's double-slit experiment with a partially coherent vortex beam.

We perform a Young's double-slit experiment with a partially coherent vortex beam (PCVB) and explore its cross-spectral density (CSD) at the focal plane after passing through a double-slit. Our results reveal that the phase of the CSD distribution with respect to an on-axis reference point can simultaneously quantitatively characterize the sign and magnitude of the topological charge (TC) carried by such a beam. In particular, the magnitude of the TC is half of the number of coherence singularities and the sign of the TC is determined by the phase winding of the coherence singularities (i.e., counterclockwise- and clockwise increases correspond to positive and negative, respectively). Based on this property, we present and demonstrate experimentally a simple technique to measure the sign and magnitude of the TC of a PCVB through its CSD distribution after a double-slit. Our method allows for easy measurement of the TC by being conceptually simpler than other methods.

Heparin Immobilized on Multiwalled Carbon Nanotubes for Catalytic Conversion of Fructose in Water with High Yield and Selectivity.

Being a member of the glycosaminoglycan family of carbohydrates, native heparin is a highly sulfated polysaccharide. Herein, heparin was grafted onto polydopamine (PDA)- and poly(ethylene imine) (PEI)-coated multiwalled carbon nanotubes (MWCNTs) (heparin-PEI@PDA@MWCNT). The immobilized heparin consists of a sulfated repeating disaccharide unit, conferring a unique microenvironment when catalyzing fructose dehydration into 5-hydroxymethylfurfural (HMF). The hydrogen bonding interactions naturally occur between the disaccharide unit of heparin and the monosaccharide fructose, and the adjacent sulfonic acid groups catalyze the fructose dehydration. The reactions were performed in water, and heparin-PEI@PDA@MWCNT achieved an HMF yield of 46.2% and an HMF selectivity of 82.2%. For the dehydration of fructose in water, heparin-PEI@PDA@MWCNT exhibits advantages over published heterogeneous catalysts on the basis of HMF yield and HMF selectivity. Three aspects contribute to the environmentally benign processing: (1) the catalyst heparin is a natural sulfated polysaccharide; (2) the catalysis is carried out in water and not in organic solvents; and (3) fructose can be produced from a biomass resource.

Simultaneous measurement of the radial and azimuthal mode indices of a higher-order partially coherent vortex beam based on phase detection.

We explore the phase distribution of the cross-spectral density (CSD) function with an off-axis reference point of a focused higher-order partially coherent vortex (PCV) beam in the focal plane. Our results reveal that the numbers of ring dislocations and screw dislocations in the CSD function equal to the magnitudes of the azimuthal mode index and radial mode index of the incident beam, respectively. In addition, the sign of the azimuthal mode index determines the direction of the phase change of the screw dislocation. This phenomenon can be used to measure the magnitude and sign of the mode indices of a higher-order PCV beam simultaneously. Our results will be useful for quantum information processing, optical storage, and communications.

Non-iterative method for phase retrieval and coherence characterization by focus variation using a fixed star-shaped mask.

A novel non-iterative phase retrieval method is proposed and demonstrated with a proof-of-principle experiment. The method uses a fixed specially designed mask and through-focus intensity measurements. It is demonstrated that this method is robust to spatial partial coherence in the illumination, making it suitable for coherent diffractive imaging using spatially partially coherent light, as well as for coherence characterization.

Spatial coherence measurement and partially coherent diffractive imaging using self-referencing holography.

The complete characterization of spatial coherence is extremely difficult because the mutual coherence function (MCF) is a complex-valued function of four independent Cartesian coordinates. This difficulty limits the ability to control and to optimize the spatial coherence in a broad range of key applications. Here we propose an efficient and robust scheme for measuring the complete MCF of an arbitrary partially coherent beam using self-referencing holography, which does not require any prior knowledge or making any assumptions about the MCF. We further apply our method to lensless diffractive imaging, and experimentally demonstrate the reconstruction of a phase object under spatially partially coherent illumination. This application is particularly useful for imaging at short wavelengths, where the illumination sources lack spatial coherence and no high-quality imaging optics are available.

Measuring topological charge of partially coherent elegant Laguerre-Gaussian beam.

The partially coherent elegant Laguerre-Gaussian (ELG) beam is of importance and exhibits extraordinary characteristics in many fields, such as optical communications and optical trapping. Here, we show a method to measure the topological charge of a partially coherent ELG beam. We find that the number of ring dislocations in the far-field complex degree of coherence is equal to the topological charge |l| of a partially coherent ELG beam, and which is confirmed experimentally. Our results will be useful for applications using partially coherent ELG beams.

Periodic Mesoporous Organosilica with a Basic Urea-Derived Framework for Enhanced Carbon Dioxide Capture and Conversion Under Mild Conditions.

A periodic mesoporous organosilica with a basic urea-derived framework (PMO-UDF) was prepared and characterized thoroughly. The PMO-UDF showed an enhanced CO2 capture capacity at low pressure (≤1 atm) and an exceptional catalytic activity in CO2 coupling reactions with various epoxides to yield the corresponding cyclic carbonates under mild conditions because of the presence of a high surface area, basic pyridine units, and multiple hydrogen-bond donors. The highly stable catalyst could be reused at least six successive times without a significant decrease of the catalytic efficiency or structural deterioration, thus the PMO-UDF composite is considered as a promising material for CO2 capture and conversion.