Improved bauxite residue dealkalization by combination of aerated washing and electrodialysis.

Bauxite residue, a major by-product of the alumina-producing Bayer process, is a serious environmental pollutant due to its high alkalinity. Here, we reported an operation system designed in our laboratory that included washing and electrodialysis dealkalization systems with aeration pipes. Washing with aeration releases a substantial amount of free alkali and attached alkali into water and increases the dealkalization efficiency. The washing liquid was treated with five steps of batch-mode electrodialysis. The average removal of total dissolved solids (TDS) after the aeration and non-aeration electrodialysis processes were 61.30% and 39.61%, respectively. The average removal of OH- under aeration conditions was 76.62%, a value that was greater than the value produced under non-aeration conditions (68.48%). This efficiency was also higher than that of some other reports (64.90-68.50%). Aeration decreased the energy consumption to a greater extent than the non-aeration condition. NaOH was recovered in terms of the concentration chamber, and the NaAl(OH)4 present in the dilution chamber was separated for the electrodialysis treatment. Membrane scaling was generated to a lesser amount under aeration conditions than that of non-aeration conditions, which would improve the dealkalization efficiency. The high repeatability of the experiments was indicated by the intraclass correlation coefficient (P < 0.05).

Study on dealkalization and settling performance of red mud.

At present, the dealkalization and comprehensive utilization of red mud is a worldwide problem. Studies on the settling performance and phase transformation of red mud by HCl, CaO, and H2O leaching are limited. In this study, the characteristics of red mud were systematically analyzed. The average sizes of graded and initial red mud were 4.11 and 9.20 µm, respectively. X-ray diffraction (XRD), X-ray fluorescence spectra (XRF), and thermogravimetry-differential scanning calorimetry (TG-DSC) results indicated the different mineralogical phases, composition, and thermal behavior. The addition of HCl could neutralize the alkalization in the red mud slurry, and CaO could replace the Na and K. Notably, the pH of the red mud slurry had no obvious change with the increase in water washing times in a certain pH. Interestingly, soluble Al and Fe were not detected in the HCl-red mud and CaO-red mud. In addition, the settling ratio was used to express the settling performance of the red mud slurry. Their interaction mechanisms were proposed, which may include phase transformation and the changing of the size and surface area. The research provided a better understanding of the phase transformation and settling performance in the treatment of red mud by HCl, CaO, and H2O leaching.