The combined effect of acetone and ZnO with diesel-biodiesel blends on the performance, combustion and emission characteristics of diesel engine.

In this experimental study, the performance, combustion and emission analysis of the combined effect of acetone and Zinc Oxide (ZnO) dispersed diesel-biodiesel (B20) blends were done in four-stroke, single-cylinder and water-cooled diesel engine. ZnO was synthesized by the solvothermal method using cow urine as a solvent and reducing agent. The synthesized ZnO was characterized by X-ray diffraction (XRD) and Scanning Electron Microscope (SEM). The biodiesel was produced from waste cooking oil through a trans-esterification process. The synthesized ZnO was dispersed in 10, 20 and 30 ppm with diesel-biodiesel blend along with 10% of acetone to form B20A10Zn10, B20A10Zn20 and B20A10Zn30 test fuels. The experimental results show that adding acetone and ZnO with diesel-biodiesel blend tends to promising physiochemical properties of the test fuels and produced better results in performance and emission. The test fuel, B20A10Zn30, gave a better outcome than all other fuels and recorded a 0.4% increase in Brake Thermal Efficiency (BTE), while there was an 8% increase in Brake Specific Fuel Consumption (BSFC). Compared to diesel, the emissions, such as Carbon Monoxide (CO), Unburned Hydrocarbon (UHC), Oxides of Nitrogen (NOx), and smoke, were 7.97%, 20%, 1.8% and 1.49% lower than the conventional diesel.

Synthesis and characterization of SnO2/rGO nanocomposite for an efficient photocatalytic degradation of pharmaceutical pollutant: Kinetics, mechanism and recyclability.

The SnO2 and SnO2/rGO nanostructures were successfully synthesized using the facile hydrothermal synthesis technique. The prepared nanostructures were well studied using different techniques such as XRD, XPS, UV-DRS, FT-IR, EDX, SEM and HR-TEM analysis. The crystalline nature of SnO2 and SnO2/rGO was confirmed by the XRD technique. The formation of highly pure SnO2 and SnO2/rGO nanostructures was confirmed by EDX analysis. The morphological results show the good agglomeration of several spherical nanoparticles. The optical properties were studied through the UV-DRS technique and the bandgap energies of SnO2 and SnO2/rGO are estimated to be 3.12 eV and 2.71 eV, respectively. The photocatalytic degradation percentage in presence of SnO2 and SnO2/rGO against RhB was found to be 96% and 98%, respectively. The degradation of TTC molecules was estimated as 90% and 88% with SnO2/rGO and SnO2, respectively. The degradation of both RhB and TTC molecules was well suited with the pseudo-first-order kinetics. The results of successive experiments clearly show the enhancement in the photocatalytic properties in the SnO2/rGO nanostructures.

White LED active α-Fe2O3/rGO photocatalytic nanocomposite for an effective degradation of tetracycline and ibuprofen molecules.

The formation of phase pure magnetically separable α-Fe2O3 and α-Fe2O3/rGO nanostructures were achieved through a simple hydrothermal technique. The properties of synthesized materials were investigated through different analytical techniques. The formation of phase pure FO and FO/rGO nanostructures were confirmed by XRD analysis with crystallite size of about ∼42 nm and ∼65 nm, respectively. The morphological analysis reveals the formation of sphere-like nanoparticles with high agglomeration. The UV-DRS analysis clearly shows the enhanced visible-light activity of FO/rGO nanoparticles. The BET analysis revealed the mesoporous property of FO/rGO nanocomposite. The enhancement in the photoinduced charge transfer process is observed after including rGO nanoparticles with FO. The photocatalytic efficiency of nanomaterials was analyzed using tetracycline and ibuprofen as model organic pollutants under white LED irradiation. The enhanced photocatalytic degradation ability of FO/rGO nanocomposite is studied against both tetracycline and ibuprofen molecules.

Effect of acetone as an oxygenated additive with used sunflower oil biodiesel on performance, combustion and emission in diesel engine.

ABSTRACTA major problem that is confronting mankind is the rapid depletion of fossil resources creating an energy demand along with their environmental impact. Therefore, finding an alternate energy source is the primary goal to attain sustainable development. Biodiesel is a promising alternate energy source for compression ignition engines. But it has some drawbacks like lower thermal efficiency, higher emission of smoke, NOx, CO and HC. Adding fuel additives with biodiesel-diesel blends is a fruitful method to overcome these problems. In this work, acetone is used as an oxygenated fuel additive in the volumetric proportion of 5%, 10%, and 15% with biodiesel-diesel blend and named as B20A5, B20A10 and B20A15. The performance, combustion, and emission characteristics of single-cylinder, four-stroke, water-cooled vertical diesel engine has been evaluated. The experimental results revealed that B20A15 has resulted in a nominal increase in brake specific fuel consumption by 8%, brake thermal efficiency of 1%, and reduction in CO by 18.4%, smoke opacity by 4.46%, HC by 1.42%, and NOx by 4.36% when compared to diesel at full load condition.

The construction of a dual direct Z-scheme NiAl LDH/g-C3N4/Ag3PO4 nanocomposite for enhanced photocatalytic oxygen and hydrogen evolution.

Dual direct Z-scheme photocatalysts for overall water decomposition have demonstrated strong redox abilities and the efficient separation of photogenerated electron-hole pairs. Overall water splitting utilizing NiAl-LDH-based binary and ternary nanocomposites has been extensively investigated. The synthesized binary and ternary nanocomposites were characterized via XRD, FTIR, SEM, HRTEM, XPS, UV-DRS, and photoelectrochemical measurements. The surface wettability properties of the prepared nanocomposites were measured via contact angle measurements. The application of the NiAl-LDH/g-C3N4/Ag3PO4 ternary nanocomposite was investigated for photocatalytic overall water splitting under light irradiation. In this work, we found that in the presence of Ag3PO4, the evolution of H2 and O2 is high over LCN30, and 2.8- fold (O2) and 1.4-fold (H2) activity increases can be obtained compared with the use of LCN30 alone. It is proposed that Ag3PO4 is involved in the O2 evolution reaction during water oxidation and g-C3N4 is involved in overall water splitting. Our work not only reports overall water splitting using NiAl-LDH-based nanocomposites but it also provides experimental evidence for understanding the possible reaction process and the mechanism of photocatalytic water splitting. Photoelectrochemical measurements confirmed the better H2 and O2 evolution abilities of NiAl-LDH/g-C3N4/Ag3PO4 in comparison with NiAl LDH, g-C3N4, Ag3PO4, and LCN30. The observed improvement in the gas evolution properties of NiAl LDH in the presence of Ag3PO4 is due to the formation of a dual direct Z-scheme, which allows for the easier and faster separation of charge carriers. More importantly, the LCNAP5 heterostructure shows high levels of H2 and O2 evolution, which are significantly enhanced compared with LCN30 and pure NiAl LDH.