Separation of anthropogenic radionuclides from aqueous environment using raw and modified biosorbents.

In this study, two types of biosorbents were used to remove 137Cs and plutonium isotopes from aqueous solutions - moss (Ptilium crista - castrensis) and oak sawdust (Quercus robur), both in the form of natural and modified state. Sorbent modification significantly increases the sorbent surface area (for moss sorbents - from 4.0 to 47.2 m2/g, and for sawdust sorbents - from 1.1 to 26.3 m2/g), pore volume (from 10-3 to 10-2), concentration and amount of basic cations and anions, as well as active functional groups on the sorbent surface. The main functional groups on the surface of natural sorbents modified with iron hydroxide interacting with analytes are carboxyl and hydroxyl groups. For carbonized sawdust and its subsequent activation with concentrated HCl, in addition to carboxyl and hydroxyl groups, acetyl groups also become active. Carbonated sawdust treated with HCl showed the highest average removal efficiency and sorption capacity for radiocesium and plutonium isotopes in laboratory column experiments - for 137Cs ∼78.6% and ∼196.6 Bq/g and for 239+240Pu ∼83% and ∼41.5 Bq/g, respectively. The moss and moss modified with iron hydroxide also showed good properties of adsorbing plutonium isotopes in field (in-situ) experiments. The best results on the sorption of 137Cs in field experiments were shown by carbonated sawdust activated with HCl, and for isotopes of plutonium - the raw moss and moss modified with iron hydroxide. The results of the study showed that sorbents can be used not only for purification of water from plutonium isotopes but allow the operational sampling and more accurate measurement of radiocesium and plutonium isotopes in the fresh water reservoirs by the dynamic flow method.

137Cs and plutonium isotopes accumulation/retention in bottom sediments and soil in Lithuania: A case study of the activity concentration of anthropogenic radionuclides and their provenance before the start of operation of the Belarusian Nuclear Power Plant (NPP).

Knowledge of the background activity concentrations of anthropogenic radionuclides before the start of operations of the new nuclear facilities in Belarus is of great value worldwide. Inland water bodies in Lithuania (specifically the Neris River, the Nemunas River and the Curonian Lagoon) are near the site of the Belarusian NPP under construction and, for this reason, sediments and flooded soils from these sensitive areas were analysed for radiocesium and plutonium isotopes (macrophytes were analysed only for 137Cs) in 2011-2012. The 137Cs and 239+240Pu activity concentrations in bottom sediments from the Nemunas River, sampled in 1995-1996 and re-calculated to the year 2016, were compared with those of 2011-2012. The obtained activity of 137Cs in bottom sediments of the Nemunas River and Curonian Lagoon varied from 1 Bq/kg to 47.0 Bq/kg. The activity of 137Cs in the tested soils ranged from 5.3 B g/kg to 32.9 Bq/kg. The 239+240Pu activity in bottom sediments of the studied sampling sites varied between 0.016 and 0.34 Bq/kg and in flooded soils from 0.064 to 0.55 Bq/kg. The 238Pu activity values were very low or lower than the detection limit. The activity of 137Cs in macrophytes varied from values lower than the detection limit to 6 Bq/kg. A strong positive linear correlation for bottom sediments was calculated between: 239+240Pu and total organic carbon (TOC), r = 0.86, p-value 0.01; 239+240Pu and silt, r = 0.80, p-value 0.029; 137Cs and silt, r = 0.78, p-value 0.04; and 137Cs and TOC, r = 0.85, p-value 0.015. The similar peculiarities of 137Cs and 239+240Pu accumulation in bottom sediments and flooded soil allow us to assume that 137Cs can be used as a tracer for 239+240Pu in the initial stage of searching for radionuclide accumulation zones. A remaining impact of the Chernobyl fallout in average comprised: in the Lower Nemunas River and Curonian Lagoon sediments - 51%, in the Middle Nemunas River -90% and in the floodplains of the Nemunas River - 59%, while the provenance of plutonium in studied bottom sediments and flooded soil was the global fallout.

Study of the formation of the primary 137Cs vertical profile in the organic matter-rich sediments.

A laboratory study of the formation of the primary vertical profile of the 137Cs activity concentration in the anaerobic organic matter-rich sediments was carried out. The incubation was performed using sediment baths method (initial thickness of the water layer over the sediments ∼40 cm, initial radiocesium activity concentration in water ∼14.53 Bq·L-1). An exponential profile (R2∼0.999) with the half-height width of ∼0.65 cm was formed after ∼32 days of the incubation. A further course of the experiment (sediments were sampled after 64, 130 and 293 days of the incubation) revealed deviations in the form of the radiocesium activity concentration profile related to the appearance of the additional Gauss factor with the increasing half-height width of ∼1.2, ∼1.3 and ∼3 cm, respectively. In spite of the evident growth of the half-height width, the radiocesium migration rate decreased from 0.02 cm·day-1 for the first 32 days of incubation down to 0.009 cm·day-1 at the end of the incubation experiment. Such a time-dependent decrease in the radiocesium migration is possibly related to the beginning of the second radiocesium migration phase depending on the retardation factor. Besides diffusion, the formation of vertical profiles of radiocesium activity concentrations in sediments was additionally induced by effects of buoyancy of the upper sediment layer due to the seepage of the above lying water into sediments.

Radionuclides in the ground-level atmosphere in Vilnius, Lithuania, in March 2011, detected by gamma-ray spectrometry.

This study presents the ground-level air monitoring results obtained in Vilnius, the capital of Lithuania, on 14 March-14 April 2011 after the recent earthquake and subsequent Tsunami having a crucial impact on Japanese nuclear reactors at the Fukushima Daiichi Nuclear Power Plant (NPP) on 11 March 2011. To collect representative diurnal aerosol samples a powerful sampling system ensuring the air filtration rate of 5500 m(3) h(-1) was used. The following artificial gamma-ray emitting radionuclides have been determined: (129m)Te, (132)Te (in equilibrium with its daughter (132)I), (131)I, (134)Cs, (136)Cs and (137)Cs. Activity concentration of the globally distributed fission product (137)Cs has increased from a background value of 1.6 µBq m(-3) to the value of 0.9 mBq m(-3) at the beginning of April. The activity ratio (134)Cs/(137)Cs was found to be close to 1, with a slightly higher activity of (134)Cs. The maximum aerosol-associated (131)I activity concentration of 3.45 mBq m(-3) was by four orders of magnitude lower than that measured at the same location in April-May 1986 as a consequence of the Chernobyl NPP accident. The estimated gaseous fraction of iodine-131 constituted about 70% of the total (131)I activity.

Uncertainties in individual doses in a case-control study of thyroid cancer after the Chernobyl accident.

Individual radiation doses to the thyroid were reconstructed for 2239 subjects of a case-control study of thyroid cancer among young people that was carried out in regions of Belarus and Russia contaminated by radioactive fallout from the Chernobyl accident. Although the process of dose reconstruction provides a point estimate of each subject's dose, it is obvious that there is uncertainty associated with these dose calculations. The following main sources of uncertainty in the estimated individual doses were identified: (1) shared and unshared errors associated with parameters of the dosimetry model; and (2) unshared errors that are associated with the variability, reliability and ability of information from the personal interviews. Besides setting up proper distributions for the parameters of the dosimetry model, inter-individual correlations were also defined to take into account shared errors. By the application of Monte Carlo simulations, a set of approximately log-normally distributed thyroid doses was obtained for each subject; the geometric standard deviations of the distributions are found to vary among individuals from 1.7 to 3.7.

Environmental releases of radioactivity and the incidence of thyroid disease at the Ignalina Nuclear Power Plant.

The Ignalina Nuclear Power Plant consists of two Russian-made RBMK-1500 reactors. The plant uses Lake Druksiai as a natural reservoir for cooling water. Within the framework of the revised radiation dose limitation system, site-specific routine release conversion factors and maximum annual effective doses for the dominant radionuclides and pathways were evaluated for both atmospheric and aquatic releases. Using calculated release conversion factors, the locations of the highest predicted activity concentrations were determined for air and for the dilution zone of heated effluent water during the period 1984-1998. Committed effective doses for critical group members were less than 0.001 mSv for Ignalina Nuclear Power Plant airborne releases and less than 0.05 mSv for aquatic releases. These dose estimates are lower than the 1 mSv dose limit for the adjacent population. In the case of Ignalina Nuclear Power Plant, taking into account the uncertainties, a recommendation for the administrative dose constraint is 0.25 mSv y(-1). This dose level may scarcely affect human health. Interestingly, during screening for thyroid disorders, endocrinologists and pediatric-endocrinologists determined a dominance of abnormal thyroids (up to 60%) among school children in the vicinity of Ignalina NPP. The data on neonatal screening for congenital hypothyroidism and transient hyperthyrotropinemia, however, suggested a possibility that the majority of abnormal thyroid cases were related to stable iodine deficiency. Thus, the influence of Ignalina Nuclear Power Plant on thyroid disorders is highly conjectural and unlikely to be associated with the observed levels of childhood thyroid disease.