Transport and dispersion of PFOA and PFOS in the Black Sea.

A 3-D transport and dispersion model was applied to study the recent past and future dynamics of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) concentrations in the Black Sea for the 2016-2030 period. The modelled surface concentrations show a distinct seasonal behaviour, shaped by winter to spring convective mixing. A significant increasing long-term trend in PFOS concentrations is established, with concentrations in water layers 200 m below the surface increasing at 4-8% per year. Driving mechanisms for PFOA and PFOS transport and accumulation in the subsurface and deeper layers are the cooling of the surface water in winter and the transport of water masses from the North Western Shelf (NWS) of the Black Sea. A simulated 50% phase-out of PFOA and PFOS from 2020 to 2030 shows a 21% reduction in PFOA, while PFOS continues to increase.

Tracing water-soluble, persistent substances in the Black Sea.

We apply a tracer model linked with a 3D circulation model to simulate transport and fate of water-soluble persistent substances in the Black Sea that do not bioaccumulate to a considerable extent. The model uses specified degradation time and identical concentrations in the rivers to build a correlation between average concentration in the basin and half-life (DT50). The average concentration in certain sub-regions of the Black Sea can be estimated using an exponential dependence of DT50, if DT50 and concentration in rivers are known. Averaging is performed on the simulations from 2000 to 2019 with real atmospheric forcing and river runoff. A well-defined seasonal cycle is evident for the average shelf concentration, while the average concentration in the deep region does not show a pronounced seasonal cycle or inter-annual variations. With the help of the existing observational data, we estimate DT50 and concentration in the rivers for carbamazepine, sulfamethoxazole and terbuthylazine. Atrazine and simazine are believed to have accumulated in the basin for a long time due to their widespread use in the past and the slow rate of degradation in the marine environment.

Pathways and mixing of the north western river waters in the Black Sea.

Given the increasing role of river-borne anthropogenically-derived substances on the water quality of impacted marine ecosystems, it is important to study the pathways of the river waters in the Black Sea. We perform tracer simulations for the river-borne substance, aiming to track its transport and accumulation in the basin and to identify possible long term trends. Our results suggest a decrease in Danube plume transport southward along the coastline and increasing transport to the north and north-eastern parts of the North Western Shelf (NWS) and then to the southwest. Over the 1960-2017 period, the Black Sea circulation showed an amplification and consolidation of the Rim Current, most likely in response to climatic changes. Recent changes in the circulation patterns seem to be a key factor for the modification of the river plume pathways. The concentration of the river-borne substance reaches an annual maximum in September, when pulses with larger tracer concentrations can be found in the inner basin. The accumulation of river-borne substance on the north and south shelf has increased in recent decades.

Black Sea thermohaline properties: Long-term trends and variations.

The current knowledge about spatial and temporal dynamics of the Black Sea's thermohaline structure is incomplete because of missing data and sparse distribution of existing measurements in space and time. This study presents 56 year continuous simulations of the Black Sea's hydrodynamics using the 3D General Estuarine Transport Model (GETM), without incorporating any relaxation toward climatological or observational data fields. This property of the model allows us to estimate independent temporal trends, in addition to resolving the spatial structure. The simulations suggest that the intermediate layer temperature is characterized by a weak positive trend (warming), whereas the surface temperature does not show a clear linear trend. Different salinity trends have been established at the surface (negative), upper (weaker negative) and main halocline (positive). Three distinct dynamic periods are identified (1960-1970, 1970-1995, 1995-2015), which exhibit pronounced changes in the Black Sea's thermohaline properties and basin circulation. Strengthening of the main cyclonic circulation, accompanied by intensification of the mesoscale anticyclonic eddy formation is found. Both events strongly affect the sea surface salinity but contribute in opposing directions. Specifically, strong composite large-scale circulation leads to an increase in sea surface salinity, while enhanced formation of mesoscale anticyclones decreases it. Salinity evolution with time is thus the result of the competition of these two opposing yet interdependent processes.