The impact of high-intensity arm crank exercise on reaction time in wheelchair fencers: gender differences and mechanical predictors.

To achieve high performance, wheelchair fencing (WF) athletes are required to exhibit good physiological and timing indicators. The main aims of this study were to assess the relationship between the results of the repeated sprint ability (RSA) test and reaction time (RT) in WF, and to evaluate changes in RT after repeated high-intensity sprints in the group of an international-level WF athletes. This experimental study involved 18 athletes (aged 34.6 ± 7.70) from the Paralympic WF team. To establish the impact of fatigue on psychomotor capacity, the participants undergo a series of tests. At the beginning of the study, first reaction time (RT1) was measured. Afterwards, the RSA test was performed using the arm crank ergometer to evaluate the participants' repeated sprint ability. Immediately after RSA, the second reaction time (RT2) was measured. Statistical analysis revealed moderate correlations between the RT2 and total work, decrease of work (DW), highest peak power, mean peak power, and highest peak power/kg, but these correlations were not statistically significant (p > 0.05). All fencers achieved a significantly shorter average RT2 (p < 0.005) after the RSA test (0.383 ± 0.035 s) than before the test (0.391 ± 0.038 s). Additionally, RT2 was significantly shorter than RT1 in the women's group (p < 0.001). Moreover, males had significantly greater values of repeated sprint ability parameters: highest work, total work, decrease of work and highest peak power (p < 0.05) than females. To conclude, repeated high-intensity arm crank exercise has a positive impact on simple postexercise cognitive tasks in WF fencers, especially in women, and leads to a decrease in RT. The RSA parameters can be predictors of changes in RT in men and women wheelchair fencers.

Surface Depassivation via B-O Dative Bonds Affects the Friction Performance of B-Doped Carbon Coatings.

Boron doping of diamond-like carbon coatings has multiple effects on their tribological properties. While boron typically reduces wear in cutting applications, some B-doped coatings show poor tribological performance compared with undoped films. This is the case of the tribological tests presented in this work in which an alumina ball is placed in frictional contact with different undoped and B-doped amorphous carbon coatings in humid air. With B-doped coatings, a higher friction coefficient at a steady state with respect to their undoped counterparts was observed. Estimates of the average contact shear stress based on experimental friction coefficients, surface topographies, and Persson's contact theory suggest that the increased friction is compatible with the formation of a sparse network of interfacial ether bonds leading to a mild cold-welding friction regime, as documented in the literature. Tight binding and density functional theory simulations were performed to investigate the chemical effect of B-doping on the interfacial properties of the carbon coatings. The results reveal that OH groups that normally passivate carbon surfaces in humid environments can be activated by boron and form B-O dative bonds across the tribological interfaces, leading to a mild cold-welding friction regime. Simulations performed on different tribological pairs suggest that this mechanism could be valid for B-doped carbon surfaces in contact with a variety of materials. In general, this study highlights the impact that subtle modifications in surface and interface chemistry caused by the presence of impurities can have on macroscopic properties, such as friction and wear.

Advantages of Using Triboscopic Imaging: Case Studies on Carbon Coatings in Non-Lubricated Friction Conditions.

Triboscopy focuses on the analysis of the temporal evolution of a tribological system, combining local and time-resolved information, most commonly the evolution of friction. In this work, this technique is applied on measurements, which were carried out with a custom-built ultra-high vacuum tribometer in ball-on-disc configuration. Based on these experiments, an extended classification to distinguish different triboscopic features is suggested, depending on the persistence in both track position and time: Uniform, Global, Local, and Sporadic. Further, a filter technique for quantifying triboscopic data regarding this classification is introduced. The new and improved triboscopic techniques are applied to various dry friction measurements of hydrogen-free carbon coatings under varying humidity and pressure. The resulting specific triboscopic features are correlated to wear phenomena, such as counter body coating abrasion, inhomogeneities in the wear track, non-uniform track wear, stick-slip and debris in the contact area, demonstrating the increased analysis and monitoring capabilities when compared to conventional friction curves and wear track images.

Low-Friction of ta-C Coatings Paired with Brass and Other Materials under Vacuum and Atmospheric Conditions.

Vacuum environments provide challenging conditions for tribological systems. MoS2 is one of the materials commonly known to provide low friction for both ambient and vacuum conditions. However, it also exhibits poor wear resistance and low ability to withstand higher contact pressures. In search of wear-resistant alternatives, superhard hydrogen-free tetrahedral amorphous carbon coatings (ta-C) are explored in this study. Although known to have excellent friction and wear properties in ambient atmospheres, their vacuum performance is limited when self-paired and with steel. In this study, the influence of the paired material on the friction behavior of ta-C is studied using counterbodies made from brass, bronze, copper, silicon carbide, and aluminum oxide, as well as from steel and ta-C coatings as reference materials. Brass was found to be the most promising counterbody material and was further tested in direct comparison to steel, as well as in long-term performance experiments. It was shown that the brass/ta-C friction pair exhibits low friction (µ < 0.1) and high wear in the short term, irrespective of ambient pressure, whereas in the long term, the friction coefficient increases due to a change in the wear mechanism. Al2O3 was identified as another promising sliding partner against ta-C, with a higher friction coefficient than that of brass (µ = 0.3), but considerably lower wear. All other pairings exhibited high friction, high wear, or both.

Effect of Energy and Temperature on Tetrahedral Amorphous Carbon Coatings Deposited by Filtered Laser-Arc.

In this study, both the plasma process of filtered laser-arc evaporation and the resulting properties of tetrahedral amorphous carbon coatings are investigated. The energy distribution of the plasma species and the arc spot dynamics during the arc evaporation are described. Different ta-C coatings are synthesized by varying the bias pulse time and temperature during deposition. An increase in hardness was observed with the increased overlapping of the bias and arc pulse times. External heating resulted in a significant loss of hardness. A strong discrepancy between the in-plane properties and the properties in the film normal direction was detected specifically for a medium temperature of 120 °C during deposition. Investigations using electron microscopy revealed that this strong anisotropy can be explained by the formation of nanocrystalline graphite areas and their orientation toward the film's normal direction. This novel coating type differs from standard amorphous a-C and ta-C coatings and offers new possibilities for superior mechanical behavior due to its combination of a high hardness and low in-plane Young's Modulus.

Mechano-chemical decomposition of organic friction modifiers with multiple reactive centres induces superlubricity of ta-C.

Superlubricity of tetrahedral amorphous carbon (ta-C) coatings under boundary lubrication with organic friction modifiers is important for industrial applications, but the underlying mechanisms remain elusive. Here, combined experiments and simulations unveil a universal tribochemical mechanism leading to superlubricity of ta-C/ta-C tribopairs. Pin-on-disc sliding experiments show that ultra- and superlow friction with negligible wear can be achieved by lubrication with unsaturated fatty acids or glycerol, but not with saturated fatty acids and hydrocarbons. Atomistic simulations reveal that, due to the simultaneous presence of two reactive centers (carboxylic group and C=C double bond), unsaturated fatty acids can concurrently chemisorb on both ta-C surfaces and bridge the tribogap. Sliding-induced mechanical strain triggers a cascade of molecular fragmentation reactions releasing passivating hydroxyl, keto, epoxy, hydrogen and olefinic groups. Similarly, glycerol's three hydroxyl groups react simultaneously with both ta-C surfaces, causing the molecule's complete mechano-chemical fragmentation and formation of aromatic passivation layers with superlow friction.