1.
Steroids
; 117: 112-119, 2017 01.
Artículo
en Inglés
| MEDLINE
| ID: mdl-27693094
RESUMEN
Reaction of nitrosochlorides of natural monoterpene hydrocarbons (+)-3-carene and (-)-α-pinene with L-amino acids and their methyl esters results in stereoselective formation of terpene-amino acids hybrids, which belong to the series of α-substituted amino oximes. The reaction with an excess of racemic DL-amino acids and their derivatives induces partial resolution of the amino acid components and formation of the diastereomeric mixtures of the terpene-amino acids hybrids, with diastereomeric excess varying from 0 to 100%.