The Evaluation of a Long-Term Experiment on the Relationships between Weather, Nitrogen Fertilization, Preceding Crop, and Winter Wheat Grain Yield on Cambisol.

In this paper, a sequence (1979-2022) of a long-term trial established in Lukavec in 1956 (Czech Republic) focusing on the effect of weather, various nitrogen (N) fertilization methods (control, PK, N1PK, N2PK, and N3PK) and preceding crops (cereals, legumes, and oil plants) on winter wheat grain yield is presented. The weather significantly changed at the site of the long-term trial. While the trend in the mean temperature significantly increased, precipitation did not change significantly over the long term. Four relationships between weather and grain yield were evaluated to be significant: (a) the mean temperature in February (r = -0.4) and the precipitation in (b) February (r = -0.4), (c) March (r = -0.4), and (d) May (r = 0.5). The yield trends for all the fertilizer treatments increased, including the unfertilized control. The N3PK treatment provided the highest mean grain yields, while the unfertilized control had the lowest yields. Comparing the preceding crops, the highest yields were harvested when the wheat followed the legumes. On the other hand, the cereals were evaluated as the least suitable preceding crop in terms of grain yield. According to the linear-plateau model, the optimal nitrogen (N) dose for modern wheat varieties, following legumes and under the trial's soil climate conditions, was 131 kg ha-1 N, corresponding to a mean grain yield of 8.2 t ha-1.

Development and the Effect of Weather and Mineral Fertilization on Grain Yield and Stability of Winter Wheat following Alfalfa-Analysis of Long-Term Field Trial.

Within the framework of a long-term experiment, established in 1955, we evaluated the development and effects of weather and mineral fertilization (Control, NPK1, NPK2, NPK3, NPK4) on the yield and stability of winter wheat following alfalfa. In total, 19 seasons were analysed. The weather changed considerably at the experimental site. Significant increases in minimal, mean, and maximal temperatures were dated to the period 1987-1988, while precipitation remained the same to this day (insignificantly increasing trend by 0.5 mm per annum). Rising temperatures in November, May, and July positively affected wheat grain yield, especially in treatments with higher N doses. No relationship between yield and precipitation was recorded. Highest inter-annual yield variability was recorded in Control and NPK4 treatments. Although minerally fertilized treatments provided slightly higher yields, the difference between Control and NPK treatments was insignificant. According to the linear-plateau response model, the recommended dose of 44 kg ha-1 N corresponds with yield of 7.4 t ha-1, while Control provides an average yield of 6.8 t ha-1. The application of higher doses did not lead to significant grain yield increase. Alfalfa as a preceding crop reduces the need of N fertilization and contributes to sustainable conventional agriculture, however, its share in crop rotations is decreasing both in the Czech Republic and in Europe.

The Effects of Weather and Fertilization on Grain Yield and Stability of Winter Wheat Growing on Orthic Luvisol-Analysis of Long-Term Field Experiment.

Based on a long-term experiment in Prague, established in 1954, we analyzed the effect of weather and seven fertilization treatments (mineral and manure treatments) on winter wheat grain yield (GY) and stability. In total, 23 seasons were analyzed, where a wheat crop followed a summer crop of potatoes. A regression analysis showed that, since the experiment started, there has been a significant increase in the annual daily maximum, average, and minimum temperature of 0.5 °C, and an increase in annual rainfall of 0.3 mm. Grain yield was positively associated with April precipitation, mean daily temperature in October, and daily maximum temperature in February. Yields were most stable between years with two fertilizer treatments that supplied a mean of 47 kg N ha-1yr-1, 54 kg P ha-1yr-1, and 108 kg K ha-1yr-1. The rate of N at which grain yield was optimized was determined according to the linear-plateau (LP) and quadratic response models as 44 kg N ha-1yr-1 for the long-strawed varieties and 87 kg N ha-1yr-1for short-strawed varieties. A gradual increase in yields was observed in all treatments, including the unfertilized control, which was attributed to improved varieties rather than to a changing climate.

Preliminary Findings on Cadmium Bioaccumulation and Photosynthesis in Rice (Oryza sativa L.) and Maize (Zea mays L.) Using Biochar Made from C3- and C4-Originated Straw.

Understanding the structural differences between feedstocks is critical for biochar effectiveness in plant growth. To examine the efficiency of biochars with unique physiological structures in a cadmium (Cd)-polluted soil, rice and maize as C3 and C4 plants, as well as biochar generated from their residues, defined as BC3 and BC4, were utilized. The experiment involved a control and a Cd-polluted soil (20 mg kg-1) without biochar application, and applications of each type of biochar (20 t ha-1) on Cd-polluted or unpolluted soil. In rice and maize fields, BC3 application led to the highest value of cation exchange capacity (CEC), with increases of 162% and 115%, respectively, over the control, while CEC increased by 110% and 71% with BC4 in the rice and maize field, respectively. As compared to the control, BC3 and BC4 dramatically enhanced the photosynthetic rate (Pn) of rice by 116% and 80%, respectively, and maize by 67% and 31%. BC3 and BC4 significantly decreased the Cd transfer coefficient in rice by 54% and 30% and in maize by 45% and 21%. Overall, BC3 is preferred over BC4 for establishing rice and maize in Cd-polluted soil, as it has a lower C/N ratio, a considerably higher surface area, and more notable alkaline features such as a higher CEC and nutrient storage.

The Effect of Soil-Climate Conditions, Farmyard Manure and Mineral Fertilizers on Potato Yield and Soil Chemical Parameters.

If available to farmers, potatoes represent a crop classically fertilized with farmyard manure in the Czech Republic. At the same time, potatoes are a crop sensitive to soil-climate conditions. We evaluated the effect of cattle manure (FYM), manure and mineral nitrogen (FYM + N1, FYM + N2), manure and mineral fertilizers (FYM + N1PK, FYM + N2PK, FYM + N3PK) application and the effect of three soil-climatic conditions (Caslav-maize production area with degraded Chernozem, Ivanovice-maize production area with Chernozem, Lukavec-potatoes production area with Cambisol) over four years (2016-2019) on potatoes yield and soil chemical properties. Of all the factors, yields were most affected by location. Lukavec provided the highest average yields (37.2 t ha-1), followed by Ivanovice (23.5 t ha-1) and Caslav (15.5 t ha-1). The second most important factor was the climatic conditions of the year. Fertilization was the third most important parameter. FYM significantly increased yields compared to Control, but applied alone cannot cover the needs of potatoes. Similarly, the application of FYM and N increases yields, but for the highest yields, it is best to apply FYM + NPK (80 kg ha-1 N). Co-application of FYM and mineral N fertilizers mitigates the negative impact of mineral N on soil pH.

Effect of selected organic materials on soil humic acids chemical properties.

Environmental friendly agricultural management has an urgent need for finding a sustainable strategy for the usage of different by-products from bioenergy production. These are either used as soil amendments or fertilizers. This study is aimed at evaluating if and how soil organic matter changes after the application of biochar, compost, and digestate. A pot experiment was conducted with Haplic Cambisol (low range arable soil) in Phytotron CLF PlantMaster (Wertingen, Germany). The chemical composition of isolated humic acids (HA) was determined by an inductively coupled plasma-mass spectrometer (ICP-MS). FT-IR spectroscopy and CHNS analysis were used for detailed chemical and optical characterization. Soil magnetic properties - radical concentration, g-parameters of radicals, and iron ions were evaluated by EPR spectroscopy. The results showed that amending arable soil with biochar, digestate and compost results in chemical and structural changes of humic substances. The radicals originated in biochar and digestate are built-in to the structure of the humic acid, which was confirmed by EPR g-parameter values. Despite a relatively high concentration of paramagnetic metal ions Fe and Mn the effect of semiquinone radical quenching was not observed. That suggests a conclusion that metal ions of studied amendments are binding in HA structure and did not disturb natural radical processes in the soil. It was also concluded that the effect of applied material depends mainly on its chemical properties and the soil type.

The influence of tree species composition on the storage and mobility of semivolatile organic compounds in forest soils.

Soil contamination with PCBs and PAHs in adjacent forest plots, characterized by a distinct composition in tree species (spruce only, mixed and beech only), was analyzed to investigate the influence of ecosystem type on contaminant mobility in soil under very similar climate and exposure conditions. Physical-chemical properties and contaminant concentrations in litter (L), organic (F, H) and mineral (A, B) soil horizons were analyzed. Contaminant distribution in the soil core varied both in relation to forest type and contaminant group/properties. Contaminant mobility in soil was assessed by examining the ratios of total organic carbon (TOC)-standardized concentrations across soil horizons (Enrichment factors, EFTOC) and the relationship between EFTOC and the octanol-water equilibrium partitioning coefficient (KOW). Contaminant distribution appeared to be highly unsteady, with pedogenic/biogeochemical drivers controlling contaminant mobility in organic layers and leaching controlling accumulation in mineral layers. Lighter PCBs displayed higher mobility in all forest types primarily controlled by leaching and, to a minor extent, diffusion. Pedogenic processes controlling the formation of soil horizons were found to be crucial drivers of PAHs and heavier PCBs distribution. All contaminants appeared to be more mobile in the soil of the broadleaved plot, followed by mixed canopy and spruce forest. Increasing proportion of deciduous broadleaf species in the forest can thus lead to faster degradation or the faster leaching of PAHs and PCBs. The composition of humic substances was found to be a better descriptor of contaminant concentration than TOC.