Quantification of parabens in marine fish samples by a rapid, simple, effective sample preparation method.

Parabens (p-hydroxybenzoic acid esters) commonly used preservatives (in cosmetics, pharmaceuticals, and foods) can pose potential effects on environmental health. In this study, seven parabens were quantified in marine fish samples using an ultra-high performance liquid chromatography triple quadrupole mass spectrometer (UHPLC-MS/MS) system. Parabens in the fish samples were extracted and purified by a rapid, simple, and effective procedure comprising sample homogenization with solvent, solid-phase extraction clean-up, and solvent evaporation. Results demonstrated that the recoveries of seven compounds (with relative standard deviation < 15%) were 88-103% in matrix-spike samples and 86-105% in surrogate standards. The method detection limits and method quantification limits of seven parabens were 0.015-0.030 and 0.045-0.090 ng/g-ww (wet weight), respectively. The optimized method was applied to measure the concentration of parabens in the 37 marine fish samples collected from Vietnam coastal waters. The concentration ranges of seven parabens found in round scad and greater lizardfish samples were 6.82-25.3 ng/g ww and 6.21-17.2 ng/g-ww, respectively. Among parabens, methylparaben accounted for the highest contribution in both fish species (43.2 and 44.9%, respectively). Based on the measured concentrations of parabens in marine fish samples, the estimated daily intake was calculated for children and adults with the corresponding values of 0.0477 µg/kg/day and 0.0119 µg/kg/day, respectively. However, the presence of parabens in Vietnamese marine fish may not pose a significant risk to human health.

Widespread distribution of phthalic acid esters in indoor and ambient air samples collected from Hanoi, Vietnam.

In the present study, distribution characteristics of ten typical phthalic acid esters (PAEs) were investigated in 90 air samples collected from the urban areas in Hanoi, Vietnam from May to August 2022. The total concentrations of PAEs in indoor and ambient air samples were in the range of 320-4770 ng/m3 and 35.9-133 ng/m3, respectively. Total concentrations of PAEs in indoor air were about one order of magnitude higher than those in ambient air. Among PAEs studied, di-(2-ethyl)hexyl phthalate (DEHP) was measured at the highest levels in all air samples, followed by di-n-octyl phthalate (DnOP) and di-n-butyl phthalate (DnBP). The PAEs concentrations in air samples collected from laboratories at nighttime were significantly higher than those during daytime (p < 0.05). Meanwhile, the distributions of PAEs in various micro-environments in the same house are no statistically significant difference. The median exposure doses of PAEs through inhalation for adults and children were 248 and 725 ng/kg-bw/d, respectively. These exposure levels were still lower than the respective reference doses (RfD) proposed by the US EPA for selected compounds such as diethyl phthalate (DEP), DnBP, and DEHP.

Assessment of cyclic volatile methyl siloxanes (CVMSs) in indoor dust from different micro-environments in northern and central Vietnam.

Comprehensive studies on emerging contaminants like volatile methyl siloxanes in settled dust from different micro-environments are still limited. In this study, concentrations and distribution of cyclic volatile methyl siloxanes (CVMSs) including D3, D4, D5, and D6 were examined in indoor dust samples collected from various micro-environments in northern and central Vietnam. Concentrations of total CVMSs in the dust samples ranged from 86.0 to 5890 (median 755) ng/g and decreased in the order: waste processing workshops (median 1560; range 329-5890) > common houses (650; 115-1680) > university classrooms (480; 86.0-1540) > vehicle repair shops (295; 126-1950) ng/g. This observation suggests that informal waste processing activities are sources of CVMSs. Among the studied CVMSs, D5 was the most predominant compound (41 ± 14%), followed by D6 (26 ± 13%), D4 (23 ± 12%), and D3 (11 ± 11%). Moderate positive correlations between D3/D4, D4/D5, and D5/D6 were found. Median daily intake doses of D3, D4, D5, and D6 through dust ingestion were 0.016, 0.051, 0.11, and 0.054 ng/kg/d, respectively, which were comparable to water consumption and markedly lower than the air inhalation pathway.

Distribution characteristics and ecological risks of heavy metals in bottom ash, fly ash, and particulate matter released from municipal solid waste incinerators in northern Vietnam.

Residue concentrations of heavy metals, including As, Cd, Cr, Cu, Ni, Pb, and Zn, were determined in bottom ash, fly ash, and particulate matter (PM10) samples collected from five municipal incinerators in northern Vietnam to assess their occurrence, distribution characteristics, and potential risks. Concentrations and profiles of heavy metals are presented, showing the dominance of Zn in all types of samples. Highly volatile elements (Cd, Pb, and Zn) were found at elevated proportions in PM10 but not fly ash. The large difference in the heavy metal profiles could be explained by the variation of input raw materials, the absence of an appropriate cycle for the material feeding process, and post-combustion technology applied. Mass balance of heavy metals in the bottom ash, fly ash, and PM10 varied significantly between the investigated incinerators, largely due to the difference in incineration technology and air pollution control system. Emission factors and annual emissions were also estimated, indicating the highest value and amount in bottom ash, followed by PM10 and fly ash. Our results are among the first studies reporting contents and emissions of toxic elements in incinerated solid wastes in Vietnam.

Chemical Fractionations of Lead and Zinc in the Contaminated Soil Amended with the Blended Biochar/Apatite.

Heavy metal contamination in agricultural land is an alarming issue in Vietnam. It is necessary to develop suitable remediation methods for environmental and farming purposes. The present study investigated the effectiveness of using peanut shell-derived biochar to remediate the two heavy metals Zn and Pb in laboratory soil assays following Tessier's sequential extraction procedure. The concentration of heavy metals was analyzed using Inductively coupled plasma mass spectrometry (ICP-MS). This study also compared the effectiveness of the blend of biochar and apatite applied and the mere biochar amendment on the chemical fractions of Pb and Zn in the contaminated agricultural soil. Results have shown that the investigated soil was extremely polluted by Pb (3047.8 mg kg−1) and Zn (2034.3 mg kg−1). In addition, the pH, organic carbon, and electrical conductivity values of amended soil samples increased with the increase in the amendment's ratios. The distribution of heavy metals in soil samples was in the descending order of carbonate fraction (F2) > residue fraction (F5) > exchangeable fraction (F1) > Fe/Mn oxide fraction (F3) > organic fraction (F4) for Pb and F5 ≈ F2 > F1 > F3 > F4 for Zn. The peanut shell-derived biochar produced at 400 °C and 600 °C amended at a 10% ratio (PB4:10 and PB6:10) could significantly reduce the exchangeable fraction Zn from 424.82 mg kg−1 to 277.69 mg kg−1 and 302.89 mg kg−1, respectively, and Pb from 495.77 mg kg−1 to 234.55 mg kg−1 and 275.15 mg kg−1, respectively, and immobilize them in soil. Amending the biochar and apatite combination increased the soil pH, then produced a highly negative charge on the soil surface and facilitated Pb and Zn adsorption. This study shows that the amendment of biochar and biochar blended with apatite could stabilize Pb and Zn fractions, indicating the potential of these amendments to remediate Pb and Zn in contaminated soil.

Distribution and ecological risk assessment of phthalic acid esters in surface sediments of three rivers in Northern Vietnam.

Pollution status and distribution characteristics of ten typical phthalic acid esters (PAEs) were investigated in 36 sediment samples collected from three rivers in Northern Vietnam from June to October 2020. The total concentrations of PAEs in sediment samples collected from the To Lich River (n = 9), the Nhue River (n = 12), and the Day River (n = 15) were in ranges of 11,000-125,000 ng/g-dwt (mean/median: 50,000/42,200 ng/g-dwt), 2140-89,900 ng/g-dwt (mean/median: 29,300/20,700 ng/g-dwt), and 1140-43,100 ng/g-dwt (mean/median: 13,800/10,400 ng/g-dwt), respectively. Among ten PAEs studied, di-(2-ethylhexyl) phthalate (DEHP) was found at the highest levels in all samples meanwhile dimethyl phthalate (DMP), diethyl phthalate (DEP), and dipropyl phthalate (DPP) were detected at low frequency and concentration. Significant correlations have existed between the median-chain (C4-C7) PAE pairs in sediment samples. Due to the high accumulation in the sediments, the median-chain PAEs had a higher ecological risk than the short-chain (C1-C3) PAEs. These contaminants may present a longstanding influence on organisms and ecosystems.

Assessment of distributional characteristics and ecological risks of cyclic volatile methylsiloxanes in sediments from urban rivers in northern Vietnam.

In this report, four cVMSs including hexamethylcyclotrisiloxane (D3), octamethylcyclotetrasiloxane (D4), decamethylcyclopentasiloxane (D5), and dodecamethylcyclohexasiloxane (D6) were determined in 85 sediment samples collected from three rivers in northern Vietnam during the period from May to November 2020. Total mean concentrations of cVMSs ranged from 75.4 to 15,000 ng/g-dw. The highest levels of cVMS were found in sediment samples collected from the To Lich River (range, 260-15,000 ng/g-dw; median, 2840 ng/g-dw), followed by the Nhue River (range, 188-6800 ng/g-dw; median, 1370 ng/g-dw), and the Day River (range, 75.4-4600 ng/g-dw; median, 666 ng/g-dw). Among cVMSs, decamethylcyclopentasiloxane (D5) was found at the highest levels in all samples and ranged from 9.00 to 11,000 ng/g-dw. Significant correlations exist between the concentrations of D4/D6 and D5/D6 pairs in river sediment samples. Although the calculated ecological risk was not high, the presence of cVMSs in the sediment raises concerns about the impact on aquatic life because of their long-term accumulation capacity.

Phthalic acid esters (PAEs) in workplace and house dust from Vietnam: concentrations, profiles, emission sources, and exposure risk.

The occurrence of nine phthalic acid esters (PAEs) were determined in indoor dust samples collected from vehicle repair shops, waste processing workshops, and homes in Vietnam. Concentrations of total PAEs ranged from 585 to 153,000 (median 33,400 ng/g), which fall in the lower end of global range. The PAE levels in workplace dust (median 49,100; range 9210-153,000 ng/g) were significantly higher than those in house dust (median 23,700; range 585-83,700 ng/g), indicating waste processing activities as potential PAE sources. The most predominant compound was di-(2-ethyl)hexyl phthalate (DEHP), accounting for 62 ± 18% of total PAEs. Other major compounds were benzyl butyl phthalate (BzBP) (10 ± 12%), di-n-butyl phthalate (DnBP) (9.7 ± 7.7%), di-n-octyl phthalate (DnOP) (7.9 ± 8.1%), and diisobutyl phthalate (DiBP) (6.9 ± 5.0%). Proportions of BzBP and DnBP in some workplace dust samples were markedly greater than in common house dust, suggesting specific emission sources. Daily intake doses of selected PAEs (e.g., DnBP, DiBP, BzBP, and DEHP) through dust ingestion were much lower than reference doses, implying acceptable levels of risk.

Assessment of some water quality parameters in the Red River downstream, Vietnam by combining field monitoring and remote sensing method.

The Red River is the largest river in northern Vietnam, and it serves as the main water source for production and human activities in the Red River Delta region. Cities and provinces located in the Red River Delta, for example, Hanoi, Nam Dinh, and Ha Nam, have experienced rapid economic growth with various large urban, industrial zones, and agricultural areas. As a result of urbanization and industrialization, surface water in this region has been contaminated by multiple anthropogenic sources. In this study, in addition to water quality assessment using WQI, we used the reflectance values of visible and near-infrared bands and in situ data to build a regression model for several water quality parameters. Among ten parameters examined, two parameters, including total suspended solids (TSS) and turbidity, were used to construct regression correlation models using the Sentinel-2 multispectral images. Our results can contribute useful information for comprehensive monitoring, evaluation, and management scheme of water quality in the Red River Delta. The application of this method can overcome the limitation of actual observation results that only reflect local contamination status and require a lot of sampling and laboratory efforts.

Profiles of phthalic acid esters (PAEs) in bottled water, tap water, lake water, and wastewater samples collected from Hanoi, Vietnam.

Contamination levels and distribution patterns of ten typical phthalic acid esters (PAEs) were investigated in various types of water samples collected from Hanoi metropolitan area in Vietnam. Concentrations of 10 PAEs in bottled water, tap water, lake water, and wastewater samples were measured in the ranges of 1640-15,700 ng/L (mean/median: 6400/5820 ng/L), 2100-18,000 ng/L (mean/median: 11,200/9270 ng/L), 19,600-127,000 ng/L (mean/median: 51,800/49,300 ng/L), and 20,700-405,000 ng/L (mean/median: 121,000/115,000 ng/L), respectively. Among PAEs, di-(2-ethylhexyl) phthalate (DEHP) accounted for a major proportion of total concentrations (45%) in wastewater, followed by diisobutyl phthalate (DiBP, 10.3%), and dibutyl phthalate (DBP, 9.53%). Concentrations of PAEs in wastewater decreased significantly with distance from the wastewater treatment plants (WWTPs). Concentrations of PAEs in surface water samples did not vary greatly between locations. PAEs were found in bottled water in the following order: DBP (22.4%), DiBP (22.3%), benzylbutyl phthalate (BzBP, 20.1%), and DEHP (15.5%). The estimated mean exposure doses of 10 PAEs through consumption of drinking water for adults and children in Vietnam were 254 and 256 ng/kg-bw/day, respectively. Capsule: Highest concentrations of PAEs were measured in wastewater, followed by lake water, tap water, and bottled water.

Field evaluation of diffusive gradients in thin-film passive samplers for wastewater-based epidemiology.

There is a need for a simple water sampling technique to enable routine monitoring of community drug consumption through wastewater-based epidemiology (WBE). This study investigates the potential use of diffusive gradients in thin films to sample organic compounds (o-DGT) for WBE. Three types of resin gels (HLB, XAD 18, and XDA-1) within o-DGT samplers each were deployed in triplicate at the inlets of two sewage treatment plants of Southern Asian cities. The target compounds included 15 illicit drugs and 18 antibiotics. A comprehensive evaluation was undertaken regarding each resin's ability to accumulate the target compounds and accuracy by comparing active samples. The organic compounds accumulated on each resin gel were characterised at the molecular level using Fourier transform ion-cyclotron-resonance mass spectrometry (FT-ICR MS). The results showed that the HLB resin performed better than the XAD 18 and XDA-1 resins. Based on calculations using the HLB-DGT data, methamphetamine and heroin were the two most popular illicit drugs consumed among the studied populations, and were followed by ketamine and codeine, which agreed well with the authoritative reports and reference data. The total drug consumption in Hanoi was one order of magnitude higher than that in Guangzhou, thus implying a probably more serious drug situation in the former. Overall, the findings of this study demonstrate that o-DGT passive samplers are a promising tool for WBE studies, particularly at WWTPs or in urban streams where an automatic sampler for taking composite water samples is absent.

Unintentionally produced polychlorinated biphenyls in pigments: An updated review on their formation, emission sources, contamination status, and toxic effects.

The formation, emission, environmental occurrence, and potential adverse effects of unintentionally produced polychlorinated biphenyls (PCBs) in pigments are reviewed, providing a comprehensive and up-to-date picture on these pollutants. PCBs are typically formed during manufacturing of organic pigments that involve chlorinated intermediates and reaction solvents, rather than those of inorganic pigments. Concentrations and profiles of PCBs vary greatly among pigment types and producers, with total PCB levels ranging from lower than detection limits to several hundred ppm; major components can be low-chlorinated (e.g., CB-11) or high-chlorinated congeners (e.g., CB-209). Pigment-derived PCBs can be released into the environment through different steps including pigment production, application, and disposal. They can contaminate atmospheric, terrestrial, and aquatic ecosystems, and then affect organisms living there. This situation garners scientific and public attention to nonlegacy emissions of PCBs and suggests the need for appropriate monitoring, management, and abatement strategies regarding these pollutants.

Air pollution caused by phthalates and cyclic siloxanes in Hanoi, Vietnam: Levels, distribution characteristics, and implications for inhalation exposure.

Contamination status and distribution characteristics of ten phthalic acid esters (PAEs) and three cyclic volatile methyl siloxanes (CSs) were determined in the air (gas and particle) samples collected from indoor and outdoor spaces of several chemistry laboratories, offices, and homes from urban area of Hanoi, the capital city of Vietnam. Air concentrations of Σ10PAEs (median 688; range 142-2390 ng m-3) and Σ3CSs (171; not detected-1100 ng m-3) in the indoor air samples were significantly higher than those measured in the outdoor ones (Σ10PAEs: 161; 34.1-515 ng m-3 and Σ3CSs: 43.2; not detected-258 ng m-3), partly suggesting the predominance of indoor emission sources of these substances. There were significant positive correlations in total air concentrations of phthalates and siloxanes between the indoor and outdoor air samples. The most predominant phthalates were diethyl-, di-n-butyl-, diisobutyl-, and di(2-ethylhexyl) phthalate. For siloxanes, D5 and D6 were more abundant than D4 in most samples. Except for di(2-ethylhexyl)- and di-n-octyl phthalate in some locations, almost all the compounds were likely associated with gas phase than particle phase. Daily intake doses of airborne phthalates and siloxanes, and non-cancer and cancer risks of selected phthalates were estimated for different exposure groups such as adults, children, and university subjects (e.g., laboratory staff and students), indicating relatively low levels of risk.

Parabens in personal care products and indoor dust from Hanoi, Vietnam: Temporal trends, emission sources, and non-dietary exposure through dust ingestion.

The occurrence of seven typical parabens was investigated in several types of personal care products (PCPs) sold at supermarkets and in indoor dust samples collected from houses, laboratories, and medical stores in Hanoi, Vietnam. Parabens were frequently detected in PCPs regardless of the paraben indication in their ingredient labels. However, concentrations of parabens in labeled products (median 3280; range 1370-5610 µg/g) were much higher than those found in non-labeled products (69.4; not detected - 356 µg/g). Parabens were also measured in indoor dust samples of this study at elevated concentrations, ranging from not detected to 1650 (median 286 ng/g). Levels of parabens in the indoor dust samples collected in 2019 decreased in the order: house > medical store > laboratory dust, however, the difference was not statistically significant. Interestingly, levels of parabens in Vietnamese house dust exhibited an increasing trend over time, for example, mean/median concentrations of parabens in house dust samples collected in 2014, 2017, and 2019 were 245/205, 310/264, and 505/379 ng/g, respectively. Methylparaben was found at the highest frequency and concentrations in both PCPs and indoor dust samples. Mean exposure doses of total parabens through dust ingestion were estimated to be 2.02, 1.61, 0.968, 0.504, and 0.192 ng/kg-bw/d for infants, toddlers, children, teenagers, and adults, respectively. Further studies on the distribution, emission behavior, potential sources, and negative impacts of parabens in different environmental media in Vietnam are needed.

Antibiotics in surface water of East and Southeast Asian countries: A focused review on contamination status, pollution sources, potential risks, and future perspectives.

This review provides focused insights into the contamination status, sources, and ecological risks associated with multiple classes of antibiotics in surface water from the East and Southeast Asia based on publications over the period 2007 to 2020. Antibiotics are ubiquitous in surface water of these countries with concentrations ranging from <1 ng/L to hundreds µg/L and median values from 10 to 100 ng/L. Wider ranges and higher maximum concentrations of certain antibiotics were found in surface water of the East Asian countries like China and South Korea than in the Southeast Asian nations. Environmental behavior and fate of antibiotics in surface water is discussed. The reviewed occurrence of antibiotics in their sources suggests that effluent from wastewater treatment plants, wastewater from aquaculture and livestock production activities, and untreated urban sewage are principal sources of antibiotics in surface water. Ecological risks associated with antibiotic residues were estimated for aquatic organisms and the prevalence of antibiotic resistance genes and antibiotic-resistant bacteria were reviewed. Such findings underline the need for synergistic efforts from scientists, engineers, policy makers, government managers, entrepreneurs, and communities to manage and reduce the burden of antibiotics and antibiotic resistance in water bodies of East and Southeast Asian countries.

Polychlorinated biphenyls in settled dusts from an end-of-life vehicle processing area and normal house dusts in northern Vietnam: Occurrence, potential sources, and risk assessment.

Concentrations and congener-specific profiles of total 209 polychlorinated biphenyls (PCBs) were investigated in settled dust samples collected from end-of-life vehicle (ELV) processing, urban, and rural areas in northern Vietnam. Concentrations of total 209 PCBs, seven indicator congeners, and twelve dioxin-like PCBs decreased in the order: ELV working > ELV living ≈ urban > rural dusts. Penta- and hexa-CBs dominated the homolog patterns in all the samples with higher proportions in the ELV dusts compared to the urban and rural house dusts. The abundance and pattern of PCBs in the ELV dusts suggest on-going emissions of these compounds related to processing of vehicular oils and lubricants containing PCBs, whereas the presence of PCBs in the urban and rural house dusts indicate long-time releases. However, levels of some PCBs identified as by-products of pigment manufacturing (e.g., PCB-11 and PCB-209) were higher in the urban house dusts than those from other locations, resulting from human activities utilizing paints and pigments. Daily intake doses (ID), non-carcinogenic hazard quotient (HQ), and lifetime cancer risk (CR) of PCBs through dust ingestion were estimated for ELV workers and residents in the studied areas. The workers and children in the ELV sites were estimated to be at higher risk of PCB exposure, however almost all of the HQ < 1 and CR < 10-4 indicate no serious risk related to dust-bound PCBs.

Contamination status and temporal trends of persistent toxic substances in sediment cores from coastal areas of central Vietnam.

Residue concentrations of organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs) were measured in sediment core samples from two estuary areas of central Vietnam to elucidate recent status and temporal trends of pollution based on the depth profiles. Concentrations of PCBs, PBDEs, and endosulfan compounds were generally higher than those of the remaining OCPs. Peak concentrations of OCPs were found in the sediment layers corresponding to the late 1950s to the early 1980s, implying the intensive application of these insecticides in Vietnam during such periods. Although the highest PCB concentrations were measured in sediment layers dated in the 1970s, increasing PCB residues observed in the shallower layers may be related to the strong industrialization and urbanization in Vietnam. BDE-209 exhibited increasing concentrations and proportions to total PBDEs towards shallower depths, suggesting substantial use and on-going releases of deca-BDE products in recent years.

Characterization of triclosan and triclocarban in indoor dust from home micro-environments in Vietnam and relevance of non-dietary exposure.

Contamination status, spatial variability, and exposure risk of triclosan (TCS) and triclocarban (TCC) in indoor dusts from different micro-environments were evaluated for the first time in Vietnam as well as in Southeast Asian region. TCS and TCC were measured in 89 dust samples collected from bedrooms, living rooms, and kitchens of private houses in four northern cities including Hanoi, Bac Ninh, Hung Yen, and Nam Dinh, by means of liquid chromatography-tandem mass spectrometry. Concentrations of TCS and TCC ranged from <5 to 1090 (median 33.2) and from <3 to 531 (median 19.3) ng g-1, respectively. Concentrations of TCS and TCC in the kitchen and bedroom dusts were markedly higher than levels found in the living room samples, probably due to their applications in kitchen utensils, household cleaning reagents, and personal care products. A strong positive correlation between TCS and TCC concentrations was detected in the whole dataset (R2 = 0.810, p < 0.001). For samples in which both TCS and TCC were quantified, TCS/TCC ratios ranged from 0.3 to 12 with a median value of 1.8, and did not show big differences between micro-environments. Human exposures to TCS and TCC through dust ingestion were estimated for various age groups with 95% CI daily intake doses ranging from (0.032-0.070) to (0.340-0.740) and from (0.017-0.033) to (0.175-0.345) ng kg-bw-1 d-1 for adults and infants respectively. Although our derived values were much lower than reference doses, more comprehensive risk assessment considering multiple exposure pathways of TCS and TCC is needed.

Polyurethane foam-based passive air sampling for simultaneous determination of POP- and PAH-related compounds: A case study in informal waste processing and urban areas, northern Vietnam.

Polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), hexabromobiphenyl (BB-153), novel brominated flame retardants (NBFRs), and unsubstituted/methylated polycyclic aromatic hydrocarbons (PAHs/Me-PAHs) were simultaneously monitored in the air samples collected from Vietnamese urban and vehicular waste processing areas by using polyurethane foam-based passive air sampling (PUF-PAS) method. Concentrations (pg m-3) of organic pollutants decreased in the order: PAHs (median 29,000; range 5100-100,000) > Me-PAHs (6000; 1000-33,000) > PCBs (480; 170-1100) > PBDEs (11; 5.3-86) > NBFRs (0.20; n. d. - 51) > BB-153 (n.d.). The difference in total PCB and PBDE concentrations between the urban and waste processing air samples was not statistically significant. Meanwhile, levels of PAHs, Me-PAHs, benzo [a]pyrene equivalents (BaP-EQs), and toxic equivalents of dioxin-like PCBs (WHO-TEQs) were much higher in the waste processing sites. This is the first report on the abundance of mono- and di-CBs (notably CB-11) in the air from a developing country, suggesting their roles as emerging and ubiquitous air pollutants. Our results have indicated potential sources of specific organic pollutants such as dioxin-like PCBs, PAHs, and Me-PAHs from improper treatment of end-of-life vehicles and other vehicle related materials (e.g., waste oils and rubber tires), as well as current emission of PCBs and PBDEs in the urban area in Vietnam. Further atmospheric monitoring studies should be conducted in this developing country that cover both legacy and emerging contaminants with a focus on areas affected by rapid urbanization and informal waste processing activities.

Road dust contamination by polycyclic aromatic hydrocarbons and their methylated derivatives in northern Vietnam: Concentrations, profiles, emission sources, and risk assessment.

Concentrations of unsubstituted and methylated polycyclic aromatic hydrocarbons (PAHs and Me-PAHs) were examined in road dusts from some representative areas with different land-use types in northern Vietnam, providing updated information about the occurrence, sources, and risks of these pollutants in Southeast Asian region. The Vietnamese road dusts were contaminated with low to moderate levels of PAHs and Me-PAHs as compared to those from other countries in the world. Concentrations of PAHs and Me-PAHs (Σ34PAHs) decreased in the order: urban (median 1800; range 1100-5500) ≈ industrial (1300; 550-10,000) > suburban (450; 310-1300) ≈ rural road dust (330; 210-2300 ng g-1), suggesting an urban-rural declining trend and effects of urbanization-industrialization processes in PAH emission extent in Vietnam. The profiles and diagnostic ratios of PAHs and Me-PAHs in our samples revealed that these compounds were mainly derived from pyrogenic sources rather than petrogenic sources. Traffic emissions (e.g., vehicle exhaust, tire debris, and possible leaks of fuels, oils, and lubricants) were estimated as principal sources of PAHs and Me-PAHs, especially in the urban and industrial areas. Other pyrogenic sources (e.g., coal, wood, and biomass combustion) were also existed in the industrial, suburban, and rural areas, reflecting PAH origins from thermal industrial processes, open burning of agricultural by-products, and domestic energy utilization. Persons working outdoors and children in the urban and industrial areas were estimated to receive higher intake doses of PAHs and Me-PAHs, which were one to two orders of magnitude higher than those estimated for other groups. Except for potential cancer risk estimated for the occupational groups in the industrial area under the worst exposure scenarios, the non-cancer and cancer risk levels were generally acceptable; however, more comprehensive risk assessment considering other exposure pathways (e.g., inhalation and diet) is needed.