Biofouling control of a forward osmosis membrane during single-pass pre-concentration of wastewater.

Pre-concentration of wastewater using a forward osmosis (FO) membrane prior to processing by an anaerobic digester can enhance biogas production. However, biofouling caused by microbes in wastewater remains a challenge. The study aimed to evaluate the efficacy of chloramination in mitigating the biofouling of an FO membrane during a single-pass concentration of primary wastewater effluent. Pre-disinfection at a chloramine dose of 22-121 mg/L successfully alleviated membrane fouling. Bacterial cell counts in the feed and concentrate showed that most of the bacterial cells in the wastewater were trapped on the membrane surface or spacer. The FO membrane surfaces in non-chloraminated/chloraminated systems were fully-covered by intact/damaged bacterial cells, respectively, indicating that chloramination effectively mitigated biofouling. However, due to high permeate-recovery and low cross-flow velocity in a single-pass concentration process, organic fouling on the membrane surface (and possibly on the interior wall of the membrane-pores) appeared to cause a gradual reduction in permeate-flux. This study demonstrated successful biofouling control using chloramination during a single-pass and high-recovery pre-concentration of primary wastewater effluent.

Green synthesis of silver nanoparticles using cellulose extracted from an aquatic weed; water hyacinth.

As part of the desire to save the environment through "green" chemistry practices, we herein report an environmentally benign synthesis of silver nanoparticles (Ag-NPs) using cellulose extracted from an environmentally problematic aquatic weed, water hyacinth (WH), as both reducing and capping agent in an aqueous medium. By varying the pH of the solution and reaction time, the temporal evolutions of the optical and morphological properties of the as-synthesised Ag-NPs were investigated. The as-synthesised cellulose capped silver nanoparticles (C-Ag-NPs) were characterised using Fourier transform infrared spectroscopy (FTIR), ultraviolet-visible spectroscopy (UV-vis), transmission electron microscopy (TEM) and high resolution transmission electron microscopy (HRTEM). The maximum surface plasmon resonance (SPR) peak decreased as the pH increased indicating that an increase in the pH of the solution favoured the formation of smaller particles. In addition, instantaneous change in the colour of the solution from colourless to brown within 5 min at pH 11 showed that the rate of reduction is faster at this pH compared to those at lower pH. The TEM micrographs showed that the materials are small, highly monodispersed and spherical in shape. The average particle mean diameters were calculated to be 5.69±5.89 nm, 4.53±1.36 nm and 2.68±0.69 nm nm at pH 4, 8 and 11 respectively. The HRTEM confirmed the crystallinity of the material while the FTIR spectra confirmed the capping of the as-synthesised Ag-NPs by the cellulose. It has been shown therefore that based on this synthetic method, this aquatic plant can be used to the advantage of mankind.