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1.
ACS Appl Mater Interfaces ; 14(2): 3334-3343, 2022 Jan 19.
Artículo en Inglés | MEDLINE | ID: mdl-34981919

RESUMEN

Icephobic coatings have been extensively studied for decades to overcome the potential damage associated with ice formation in various devices that are operated under harsh weather conditions. Superhydrophobic surface coatings have been applied for icephobic coating applications owing to their low surface energy. In this study, an icephobic coating of a self-formed superhydrophobic surface using polydimethylsiloxane (PDMS) and SiO2 powder was investigated. The effect of superhydrophobicity on icephobicity was determined by varying the experimental parameters. Polyvinylidene fluoride (PVDF) was added to the PDMS solution to improve the mechanical properties of the icephobic layer. The PDMS-PVDF solution also showed a self-formation behavior into a superhydrophobic surface. In addition, the icephobicity and mechanical properties of the PDMS-PVDF mixture coating improved because of the multilevel nanostructure formed by physical and chemical interactions between the mixture and SiO2 powder. We believe that the proposed approach will be a suitable candidate for various practical applications of icephobicity and a model system to understand the correlation between superhydrophobicity and icephobicity.

2.
Langmuir ; 37(17): 5356-5363, 2021 May 04.
Artículo en Inglés | MEDLINE | ID: mdl-33890793

RESUMEN

The superhydrophobic surface has been used in ultradry surface applications, such as the maritime industry, windshields, non-sticky surfaces, anti-icing surfaces, self-cleaning surfaces, and so forth. However, one of the main hurdles for the production of superhydrophobic surfaces is high-cost fabrication methods. Here, we report a handy process of self-synthesis fabrication of superhydrophobic surfaces with daily supplies. Driven by the physics of biscuit dunking, we introduce a method to self-synthesize superhydrophobic surfaces from daily supplies by coating a substrate with a liquid (liquids of paraffin from candles or polydimethylsiloxane) and subsequently sprinkling powders (food-desiccant silica, alumina, sugar, salt, or flour). A mechanistic study revealed that the capillary force, governed by surface energy difference, liquid viscosity, and powder pore size, draws the liquid solution into the porous channels within the powders. The entire surface of powders, in turn, is covered with the low-surface-energy liquid to maintain the porosity, creating a 3D porous nanostructure, resulting in a water contact angle over 160°. This work provides a scientific understanding that technological developments are closely related to the science that can be seen in our daily lives. Also, we believe that further intensive studies extended from this work could enable to home-fabricate a superhydrophobic surface, such as a bathtub and sink in bathrooms and a cooking area and sink in kitchens.

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