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Solar energy is an environmentally friendly and inexhaustible natural resource. It can be converted into thermal energy by using concentrated solar power (CSP) methods. One of the key components of CSP is a solar absorber, which absorbs concentrated solar radiation and converts it into heat. Recently, there have been many studies on enhancing the solar-to-thermal conversion efficiency of solar absorbers. In this work, a pulsed fiber laser was used to modify the surface of AISI 304 stainless steel as a solar absorbing material. By varying the energy density, surface roughness and oxide films can be formed, which affect the solar absorptance and thermal emittance of the substrate. The surface characteristics and corresponding optical properties were investigated. The surface roughness was measured to be in the range of 9-158 nm. Due to heat generated during engraving, metal surface oxidation occurs on the AISI 304 substrate, resulting in different values of solar absorptance and thermal emittance. Compared with the unmodified surface, the modified AISI 304 surfaces resulted in solar absorptance ranging from 58.57% to 91.78%, and the thermal emittance ranged from 10.56% to 32.90%. Consequently, the solar-to-thermal conversion efficiency was improved from 50.09% to 81.69%, and the technique can be used for solar absorbing applications.
RESUMEN
Ice accumulation on brass surfaces can lead to heat transfer inefficiency, equipment degradation, and potential accidents. To address this issue, superhydrophobic surface technology is utilized. This work aims to develop superhydrophobic nanostructured brass surfaces using the combination of nanolaser ablation and the deposition of silica nanoparticles to achieve the anti-icing property. Four distinct types of brass surfaces namely, the bare surface (BS), the lasered surface (LS), the coated surface (CS), and the coated-lasered surface (CLS) were prepared. The anti-icing performances of the fabricated samples including the effects of the surface structure, the droplet size, and the surface temperature were investigated and evaluated. The results showed that the delayed icing time increased with the increases in the apparent contact angle, the droplet size, and the surface temperature. When the apparent contact angle increased, the contact area between the droplet and the cooling substrate reduced, leading to the longer delayed icing time. With the deposition of silica nanoparticles and nanolaser treatment, CLS achieved the greatest apparent contact angle of 164.5°, resulting in the longest delayed icing time under all experimental conditions. The longest delayed icing time on CLS recorded in this study was 2584 s, which was 575%, 356%, and 27% greater than those on BS, LS, and CS, respectively. The study also revealed that the surface structure played a more crucial role in achieving the anti-icing property when compared to the surface temperature or the droplet size. The shortest delayed icing time on CLS at the lowest surface temperature and at the smallest droplet size was longer than those on BS and LS at all conditions. The results were also discussed in relation to a heat transfer model. The findings of this research can serve as an avenue for advancing knowledge on heat transfer enhancement and energy efficiency.
RESUMEN
This research studies the physical, superhydrophobic, and optical properties of functionalized silica-coated copper phthalocyanine (CuPc) pigments. The silica coating was confirmed by the size increase and the atomic ratio of silicon and copper of the coated pigments. Under optimal conditions, the green and blue shades of the pigments were enhanced as indicated by the increase in solar reflectance at 450-540 nm for the CuPc green and 380-520 nm for the CuPc blue. The total near-infrared (NIR) reflectance of the CuPc green and blue also increases by 10.6 and 11.5% compared to the uncoated pigments, respectively. The functionalized silica layer also adds a superhydrophobic property to the pigments. The contact angles of the functionalized pigments with water and oil are 154.4 and 54.3° for the CuPc green pigment and 142.9 and 78.1° for the CuPc blue pigment, respectively. The improved optical and hydrophobic properties make the pigment suitable for outdoor applications as an advanced protection layer to slow down material degradations from heat and humidity.
RESUMEN
Cermet-based solar absorbers containing nickel (Ni) in a nanochain (NC) structure embedded in an aluminum oxide (Al2O3) film demonstrated a high absorptance of more than 90% of the solar spectrum. In this work, Ni NCs were successfully prepared by a simple chemical reduction method without the assistance of a template or magnetic field. The formation of Ni nanoparticles (NPs) in different configurations was controlled by adjusting the NaOH:NiCl2 molar ratio. Not only was NaOH used to adjust the solution pH but it also induced the reduction reaction to be faster and so resulted in a larger number of Ni nuclei. Together with the intrinsic magnetic property of Ni, Ni NPs tended to orient in a chain-like manner to form Ni NCs that remained stable throughout the reaction. Increasing the NaOH:NiCl2 molar ratio up to 8 led to a uniform morphology of Ni NCs. However, at higher molar ratios (above 8), the NCs were likely to collapse at the end of the reaction, forming near-globular particles. With its unique structure, metallic Ni NCs were employed by incorporating them into a ceramic layer of Al2O3, which can be used as efficient cermet materials. Compared to a conventional cermet with embedded spherical Ni NPs, a 16.4% increase in solar absorptance was observed with the Ni NCs due to their enhanced absorption and scattering in the solar spectrum. Moreover, increasing the Ni NC content in the Al2O3 layer gradually enhanced the solar absorptance to 0.91 and so was a good solar absorber.
RESUMEN
A polydimethylsiloxane film patterned by a self-assembled array has been demonstrated as a strain sensor. A monolayer of 580 nm polystyrene spheres prepared by convective deposition was the template to transfer a periodic pattern to a polydimethylsiloxane (PDMS) film. Optical diffraction through the stretched PDMS film, enabled strain sensing perpendicular and parallel to the stretching direction, with sensitivities of 1.7â nm/% strain and 4.0â nm/% strain, respectively. The PDMS film was used as a vibration sensor at 50â Hz.
RESUMEN
The majority of high-performance perovskite and polymer solar cells consist of a TiO2 electron transport layer (ETL) processed at a high temperature (>450 °C). Here, we demonstrate that low-temperature (80 °C) ETL thin film of TiOx:Zn1-xCdxS can be used as an effective ETL and its band energy can be tuned by varying the TiOx:Zn1-xCdxS ratio. At the optimal ratio of 50:50 (vol%), the MAPbIxCl1-x perovskite and PCBTBT:PC70BM polymer solar cells achieved 9.79% and 4.95%, respectively. Morphological and optoelectronic analyses showed that tailoring band edges and homogeneous distribution of the local surface charges could improve the solar cells efficiency by more than 2%. We proposed a plausible mechanism to rationalize the variation in morphology and band energy of the ETL.
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This research concerns the development of Surlyn film reinforced with micro-/nanofibrillated celluloses (MFC) for use as an encapsulant in organic photovoltaic (OPV) cells. The aim of this work was to investigate the effects of fibre types and the mixing methods on the structure-properties of the composite films. Three types of cellulose micro/nanofibrils were prepared: the as-received MFC, the dispersed MFC and the esterified MFC. The fibres were mixed with Surlyn via an extrusion process, using two different mixing methods. It was found that the extent of fibre disintegration and tensile modulus of the composite films prepared by the master-batching process was superior to that of the composite system prepared by the direct mixing method. Using the esterified MFC as a reinforcement, compatibility between polymer and the fibre increased, accompanied with the improvement of the percentage elongation of the Surlyn composite film. The percentage of light transmittance of the Surlyn/MFC films was above 88, regardless of the fibre types and fibre concentrations. The water vapour transmission rate of the Surlyn/esterified MFC film was 65% lower than that of the neat Surlyn film. This contributed to the longer lifetime of the OPV encapsulated with the Surlyn/esterified MFC film.
RESUMEN
Particle-particle and particle-substrate interactions play a crucial role in capillary driven convective self-assembly for continuous deposition of particles. This systematic study demonstrates the nontrivial effects of varying surface charge and ionic strength of monosized silica microspheres in water on the quality of the deposited monolayer. Increase in particle surface charge results a broader range of parameters that result in monolayer deposition which can be explained considering the particle-substrate electrostatic repulsion in solution. Resulting changes in the coating morphology and microstructure at different solution conditions were observed using confocal microscopy enabling correlation of order to disorder transitions with relative particle stability. These results, in part, may explain similar results seen by Muangnapoh et al., 2013 in vibration-assisted convective deposition.
RESUMEN
Convective deposition is widely used to deposit a highly ordered and uniform layer of monosized particles from solution by drawing the particles into an advancing thin film that uses capillary forces to define their local orientation. This process is often plagued by the formation of streaks, the regions where particles accumulate due to a local flux inhomogeneity. Flow occurs in the direction orthogonal to the deposition direction and parallel to the substrate near the streaks due to enhanced evaporation where particles have accumulated. This study investigates the formation of streaks nucleated from seeds or defects having prescribed dimensions and spacing across the substrate. The formation and spacing of both seeded and spontaneous streaks are characterized and were observed to be roughly dictated by the suspending fluid capillary length. Thus, spontaneously forming streaks can be suppressed by reducing the spacing to less than twice the critical length. Likewise, the conditions for maximum density or minimal spacing of streaks are also shown.
RESUMEN
The realization of structural diversity in colloidal crystals obtained by self-assembly techniques remains constrained by thermodynamic considerations and current limits on our ability to alter structure over large scales using imposed fields and confinement. In this work, a convective-based procedure to fabricate multi-layer colloidal crystal films with extensive square-like symmetry is enabled by periodic substrate motion imposed during the continuous assembly. The formation of film-spanning domains of (100) fcc symmetry as a result of added vibration is robust across a range of micron-scale monosized spherical colloidal suspensions (e.g., polystyrene, silica) as well as substrate surface chemistries (e.g., hydrophobic, hydrophilic). The generation of extensive single crystalline (100) fcc domains as large as 15 mm(2) and covering nearly 40% of the colloidal crystalline film is possible by simply tuning coating conditions and multi-layer film thickness. Preferential orientation of the square-packed domains with respect to the direction of deposition is attributed to domain generation based upon a shear-related mechanism. Visualization during assembly gives clues toward the mechanism of this flow-driven self-assembly method.
