Surfactant-driven Amphoteric Doping of Carbon Nanotubes.

Aqueous surfactant dispersion is the most typical starting step to functionalize materials consisting of carbon nanotubes, but the effects of surfactants on the electronic properties are still unclear. Here we report how the functional groups of surfactants affect the electronic properties of carbon nanotube films. Using spectroscopic and thermoelectric characterization, we demonstrate that anionic and non-ionic surfactants contribute to the formation of p-type and n-type carbon nanotubes, respectively. Additionally, p-type doping with oxygen adsorption is found to compete with surfactants' doping. These findings are useful for designing the srarting carbon nanotube materials exhibiting desirable electronic properties.

Solvent basicity promotes the hydride-mediated electron transfer doping of carbon nanotubes.

This study investigates the hydride-mediated electron transfer doping of single-walled carbon nanotubes using absorption spectroscopy and thermoelectric measurements. Specific solvent basicity is found to be important for the efficient n-type doping of carbon nanotubes. This progress is an essential requirement for the future development of electronic and energy devices.

Air-tolerant Fabrication and Enhanced Thermoelectric Performance of n-Type Single-walled Carbon Nanotubes Encapsulating 1,1'-Bis(diphenylphosphino)ferrocene.

The thermally-triggered n-type doping of single-walled carbon nanotubes is demonstrated using 1,1'-bis(diphenylphosphino)ferrocene, a novel n-type dopant. Through a simple thermal vacuum process, the phosphine compounds are moderately encapsulated inside single-walled carbon nanotubes. The encapsulation into SWNTs is carefully characterized using Raman/X-ray spectroscopy and transmission electron microscopy. This easy-to-handle doping with air-stable precursors for n-type SWNTs enables the large-scale fabrication of thermoelectric materials showing an excellent power factor exceeding approximately 240 µW mK(-2) .