1.
J Org Chem
; 80(14): 7317-20, 2015 Jul 17.
Artículo
en Inglés
| MEDLINE
| ID: mdl-26086525
RESUMEN
A Pd-catalyzed oxidative silylation of simple olefins with hexamethyldisilane to give allylsilanes has been achieved using molecular oxygen as the sole oxidant. The reaction provides a useful protocol to access synthetically useful allylsilanes from easily accessible simple olefins and hexamethyldisilane without using any oxidants other than O2.