Sources of hydrocarbons and their risk assessment in seawater and sediment samples collected from the Nile Delta coast of the Mediterranean Sea.

The aim of this work is to examine the levels, distribution, bases, and hazards of n-alkanes (n-C9 to n-C20) and PAHs in the seawater and sediments around oil production locations in the whole delta region. The variations in the levels of PAHs and n-alkanes in seawater and sediment of the Nile delta coast of the Mediterranean were investigated using GC-MS/MS. The Σn-alkanes residues ranged between 12.05 and 93.51 mg/L (mean: 50.45 ± 17.49 mg/L) and 4.70 to 84.03 µg/g (mean: 31.02 ± 27.995 µg/g) in seawater and sediments, respectively. Total PAHs concentrations ranged between 4.485 and 16.337 µg/L (average: 9.47 ± 3.69 µg/L) and 1.32 to 28.38 ng/g (average 8.61 ± 7.57 ng/g) in seawater and sediment samples, respectively. The CPI (carbon preference index) values fluctuated between 0.62 and 1.72 (seawater) and from 0.234 to 2.175 (sediment), proposing the variation sources of n-alkane in the studied area. PAHs concentrations were lower than the Effective Range Low (ERL) and Effective Range Median (ERM) levels. The Toxic Equivalent Quotient (TEQ) values oscillated between 0.002 and 6.84 ng/L and from 3.72 to 13.48 ng/g for the seawater and sediment samples, respectively. The Ant/(Ant + Phe) ratio in sediment and seawater samples indicated a pyrolytic source while the BaA/(BaA + Chry) ratio indicates petrogenic sources in most of the studied stations.

Quantum and experimental investigation of the application of Crassostrea gasar (mangrove oyster) shell-based CaO nanoparticles as adsorbent and photocatalyst for the removal of procaine penicillin from aqueous solution.

The present study was designed to synthesize and characterize calcium oxide nanoparticles (using mangrove oyster shell as a precursor) and apply the synthesized nanoparticles as a photocatalyst to degrade procaine penicillin in an aqueous solution. The photocatalyst exhibited an average band gap of 4.42 eV, showed a maximum wavelength of absorbance in the UV region (i.e., 280 nm), and is a microporous nanoparticle with a particle diameter of 50 nm. The photocatalyzed degradation of the drug was conducted under natural sunlight, and the influence of parameters such as the period of contact, catalyst load, pH, initial drug concentration, and ionic strength was investigated concerning the degradation profile. The results obtained from response surface analysis indicated that an optimum degradation efficiency of about 93% can be obtained at a concentration, pH, and catalyst dosage of 0.125 M, 2, and 0.20 g respectively, at 0.902 desirabilities. The Langmuir-Hinshelwood, modified Freundlich, parabolic diffusion, pseudo-first-/second-order, and zero-, first-, and second-order kinetic parameters were tested to ascertain the best model that best described the experimental data. Consequently, the Langmuir-Hinshelwood, modified Freundlich, and pseudo-second-order models were accepted based on the minimum error and higher R2 values. Based on the Langmuir-Hinshelwood rate constants for adsorption and photodegradation as well as the evaluated valence bond potential, the degradation of the drug first proceeded through the mechanism of adsorption and followed by the oxidation of the drug by superoxide (generated from the interaction of electrons that generated by through the absorption of UV radiation). The quantum chemical calculation gave evidence that pointed towards the establishment of strong agreement with experimental data and also showed that the carboxyl functional group in the drug is the target site for adsorption and subsequent degradation.

Novel hydrophilic straw biochar for the adsorption of neonicotinoids: kinetics, thermodynamics, influencing factors, and reuse performance.

Nitenpyram (NIT) is the most water-soluble neonicotinoid (NEO). It has been shown to pose a serious threat to human health and the environment but was always ignored due to its limited market share. There were few experts who studied NIT's transport behavior on biochar. In this study, two types of biochar were co-activated separately using zinc chloride combined with phosphoric acid and potassium hydroxide combined with acetic acid, marked as ZBC and KBC. Characterizations suggested that hydrophilic ZBC and KBC had more surface functional groups than unmodified biochar (BC), and specific surface areas of ZBC (456.406 m2·g-1) and KBC (750.588 m2·g-1) were significantly higher than of BC (67.181 m2·g-1). The pore structures of KBC and ZBC were hierarchical porous structures with different pore sizes and typical microporous structure, respectively. The adsorption performance of either NIT or IMI on KBC was better than that on ZBC. Only 0.4 g·L-1 of KBC can absorb 89.62% of NIT in just 5 min. The equilibrium adsorption amounts of NIT on ZBC and KBC were 17.995 mg·g-1 and 82.910 mg·g-1. Elovich and Langmuir models were used to evaluate the whole adsorption process, which was attributed to the chemisorption mechanism. In addition, removal rates of NIT were negatively correlated to NIT's initial concentration and positively correlated to the dose of biochar. pH had almost no effect on adsorption, but the presence of salt ions can inhibit the removal of NIT. Long-term stabilities of biochars were also acceptable. These findings will promote the development in the preparation of biochar fields and provide a positive reference value for NEO removal.

Composite nanofiber formation using a mixture of cellulose acetate and activated carbon for oil spill treatment.

Oil and organic pollutants are significant disasters affecting the aquatic ecosystem and human health. A novel nanofiber composite from cellulose acetate/activated carbon (CA/AC) was successfully fabricated by the electrospinning technique. CA/AC nanofiber composites were prepared from 10% (w/v) polymer solutions dissolving in DMA/acetone ratio 1:3 (v/v) with adding three different percentages of AC (3.7, 5.5, and 6.7%) to the total weight of CA. The prepared CA/AC nanofiber composite morphology reveals randomly oriented bead-free fibers with submicron fiber diameter. CA/AC nanofiber composites were further characterized by TGA, DSC, and surface area analysis. Water uptake was investigated for fabricated fibers at different pH. Oil adsorption was conducted in both static (oil only) and dynamic (oil/water) systems to estimate the adsorption capacity of prepared composites to treat heavy and light machine oils. The results showed increased oil adsorption capacity incorporating activated carbon into CA nanofiber mats. The maximum sorption capacity reached 8.3 and 5.5 g/g for heavy and light machine oils obtained by CA/AC5.5 (AC, 5.5%). A higher oil uptake was reported for the CA/AC composite nanofibers and showed a constant sorption capacity after the second recycles in the reusability test. Of isotherm models, the most applicable model was the Freundlich isotherm model. The result of kinetic models proved the fit of the pseudo-second-order kinetic model to the adsorption system.

Potential of pomegranate husk carbon for Cr(VI) removal from wastewater: kinetic and isotherm studies.

Pomegranate husk was converted into activated carbon and tested for its ability to remove hexavalent chromium from wastewater. The new activated carbon was obtained from pomegranate husk by dehydration process using concentrated sulfuric acid. The important parameters for the adsorption process such as pH, metal concentration and sorbent weight were investigated. Batch equilibrium experiments exhibited that a maximum chromium uptake was obtained at pH 1.0. The maximum adsorption capacity for pomegranate husk activated carbon was 35.2mgg(-1) as calculated by Langmuir model. The ability of activated carbon to remove chromium from synthetic sea water, natural sea water and wastewater was investigated as well. Different isotherm models were used to analyze the experimental data and the models parameters were evaluated. This study showed that the removal of toxic chromium by activated carbon developed from pomegranate husk is a promising technique.

Removal of direct blue-86 from aqueous solution by new activated carbon developed from orange peel.

The use of low-cost, easy obtained, high efficiency and eco-friendly adsorbents has been investigated as an ideal alternative to the current expensive methods of removing dyes from wastewater. This study investigates the potential use of activated carbon prepared from orange peel for the removal of direct blue-86 (DB-86) (Direct Fast Turquoise Blue GL) dye from simulated wastewater. The effects of different system variables, adsorbent dosage, initial dye concentration, pH and contact time were studied. The results showed that as the amount of the adsorbent increased, the percentage of dye removal increased accordingly. Optimum pH value for dye adsorption was determined as approximately 2.0. Maximum dye was sequestered within 30min after the beginning for every experiment. The adsorption of direct blue-86 followed a pseudo-second-order rate equation and fit well Langmuir, Tempkin and Dubinin-Radushkevich (D-R) equations better than Freundlich and Redlich-Peterson equations. The maximum removal of direct blue-86 was obtained at pH 2 as 92% for adsorbent dose of 6gL(-1) and 100mgL(-1) initial dye concentration at room temperature. The maximum adsorption capacity obtained from Langmuir equation was 33.78mgg(-1). Furthermore, adsorption kinetics of DB-86 was studied and the rate of adsorption was found to conform to pseudo-second-order kinetics with a good correlation (R2>0.99) with intraparticle diffusion as one of the rate determining steps. Activated carbon developed from orange peel can be attractive options for dye removal from diluted industrial effluents since test reaction made on simulated dyeing wastewater show better removal percentage of DB-86.