RESUMEN
In recent years, artificial amorphous photonic structure (APS) materials with high color saturation and angle independence have been competitively reported. However, there is a lack of research into their functionalization and application in practical environments. Here, with practical applications in mind, we prepared APS pigments based on CB@SiO2@TiO2 core-bishell nanospheres and demonstrated high color saturation, enhanced color stability, and excellent photocatalytic activity. SiO2 effectively protected the carbon black particles from ablation during the calcination process. Paints composed of ethanol, ethyl cellulose (EC), and pigments could be spray-coated on any substrate to prepare a structurally colored coating without limitation. The coatings show good mechanical stability and photothermal stability. The color of the structurally colored pigments can be easily changed by adjusting the sizes of the CB@SiO2@TiO2 nanospheres. The photocatalytic activity of the pigments on formaldehyde (HCHO) and methylene blue (MB) solution and reaction kinetics of their degradation were studied by experiment. The results showed that the photocatalytic activity of the pigments increased with the increase of the TiO2 loading, and the degradation rate of HCHO reached 96.7% for 3 h and that of MB reached 97.9% for 60 min when the TiO2 shell thickness was 40 nm. The structurally colored pigments based on CB@SiO2@TiO2 nanospheres effectively solve the environmental problems caused by the application of pigments and have a promising future in the fields of color decoration, display, and painting.
RESUMEN
Superhydrophobic coatings have attracted a lot of attention due to their excellent self-cleaning and anti-fouling capabilities. However, the preparation processes for several superhydrophobic coatings are intricate and expensive, which restricts their usefulness. In this work, we present a straightforward technique for creating durable superhydrophobic coatings that can be applied to a variety of substrates. The addition of C9 petroleum resin to a styrene-butadiene-styrene (SBS) solution lengthens the SBS backbone and undergoes a cross-linking reaction to form a dense spatial cross-linked structure, improving the storage stability, viscosity, and aging resistance of the SBS. The combined solution functions as a more stable and effective adhesive. Using a two-step spraying technique, the hydrophobic silica (SiO2) nanoparticles solution was applied to the surface to create durable nano-superhydrophobic coatings. Additionally, the coatings have excellent mechanical, chemical, and self-cleaning stability. Furthermore, the coatings have wide application prospects in the fields of water-oil separation and corrosion prevention.
RESUMEN
We report luminous polylactic acid (PLA) composite prepared via a solvent casting method using different amounts of phosphor strontium aluminate (SrAl2O4: Eu2+ and Dy3+) (SAO). The reason for doing this is that the changes of fluorescence and mechanical properties in the composites with different SAO contents can be directly evaluated. The SAO particles should have a variety of excellent characteristics in the PLA matrix, among which dispersibility and compatibility are particularly important; so, they can be modified by 3-aminopropyltriethoxysilane (APS) to achieve the target characteristics. The results showed that the fluorescence and mechanical properties were affected by SAO addition. The mechanical properties significantly improved with 5 wt% SAO; further, addition had no impact. And the emission band of fluorescence and phosphorescence is just at the peak of 524 nm. The composites with 15 wt% SAO have the best fluorescence properties. The fluorescence decreased with further doping. Fluorescence decay curves with various amounts of SAO particles show a similar tendency as pure SAO particles; the speed of decrease in afterglow intensity was higher for the first 30 min. In addition, the detailed morphological scanning and study by scanning electron microscope (SEM) showed that the particles had good adhesion to the matrix. In conclusion, the concentration of SAO into the PLA matrix impacts the fluorescence and mechanical properties of a SAO/PLA composite material.
