1.
Dalton Trans
; 48(46): 17252-17257, 2019 Nov 26.
Artículo
en Inglés
| MEDLINE
| ID: mdl-31660555
RESUMEN
The interaction of manganese(ii) phthalocyanine with 7,7,8,8-tetracyanoquinodimethane and its perfluoro derivative proceeds with the oxidation of Mn and the reduction of the acceptor molecules to give the first mixed single crystals of manganese(iii) phthalocyanine with TCNQ/F4-TCNQ radical anions. The crystals have unusual structures with C-Hπ interactions between the ions and their orthogonal arrangement, as well as remarkable redox properties. The charge transfer was proved by spectroscopic and magnetic studies.