Development of a trace quantitative method to investigate caffeine distribution in the Yellow and Bohai Seas, China, and assessment of its potential neurotoxic effect on fish larvae.

Caffeine is an emerging contaminant in aquatic environments. The study utilized a validated method to investigate the presence and distribution of caffeine in the surface water of the Yellow and Bohai Seas, urban rivers, and the Yantai estuary area. The analytical method conforms to EPA guidelines and exhibits a limit of quantification that is 200 times lower than that of prior investigations. The study revealed that the highest concentration of 1436.4 ng/L was found in convergence of ocean currents in the Yellow and Bohai Seas. The presence of larger populations and the process of urban industrialization have been observed to result in elevated levels of caffeine in offshore regions, confirming that caffeine can serve as a potential indicator of anthropogenic contamination. Fish larvae exhibited hypoactivity in response to caffeine exposure at environmentally relevant concentrations. The study revealed that caffeine pollution can have adverse effects on marine and offshore ecosystems. This emphasizes the importance of decreasing neurotoxic pollution in the aquatic environment.

Influence of hydrodynamic conditions on the fate of halogenated flame retardants along salinity gradients in a highly polluted micro-tidal estuary.

Halogenated flame retardants (HFRs) have properties similar to those of hydrophobic organic pollutants (HOPs). However, the understanding of their environmental fate in tidal estuaries remains limited. This study aims to bridge knowledge gaps regarding the land-sea transport of HFRs through riverine discharge into coastal waters. HFR levels were significantly influenced by tidal movement, and decabromodiphenyl ethane (DBDPE) was the predominant compound with a median concentration of 3340 pg L-1 in the Xiaoqing River estuary (XRE), whereas BDE209 had a median concentration of 1370 pg L-1. The Mihe River tributary plays a key role in transporting pollution to the downstream estuary of the XRE in summer, and the increasing suspended particulate matter (SPM) by resuspension in winter significantly affects HFR levels. These concentrations were inversely proportional to diurnal tidal oscillations. Tidal asymmetry caused an increase in SPM during an ebb tide, which increased HFR levels in a micro-tidal estuary such as the Xiaoqing River. The location of the point source and flow velocity influences the HFR concentrations during tidal fluctuations. Tidal asymmetry increases the likelihood of some HFRs being adsorbed by particles exported to the adjacent coast, and some settled down in areas with low hydrodynamic conditions, hindering their flow to the ocean.