Impact of volatile solids destruction on the shear and solid-liquid separation behaviour of anaerobic digested sludge.

Systematic and comprehensive characterisation of shear and solid-liquid separation properties of sludge across a wide range of solids concentration and volatile solids destruction (VSD) is critical for design and optimization of the anaerobic digestion process. In addition, there is a need for studies at the psychrophilic temperature range as many unheated anaerobic digestion processes are operated under ambient conditions with minimal self-heating. In this study, two digesters were operated at different combinations of operating temperature (15-25 °C) and hydraulic retention time (16-32 d) to ensure a wide range of VSD in the range of 0.42-0.7 was obtained. For shear rheology, the viscosity increased 1.3 to 3.3 times with the increase of VSD from 43 % to 70 %, while other parameters (temperature, VS fraction) having a negligible impact. Analysis of a hypothetical digester indicated that there is an optimum VSD range 65-80 % where increase in viscosity due to the higher VSD is balanced by the decrease in solids concentration. For solid-liquid separation, a thickener model and a filtration model were used. No significant impact of VSD on the solids flux, underflow solids concentrations or specific solids throughput was observed in the thickener and filtration model. However, there was an increase in average cake solids concentration from 21 % to 31 % with increase of VSD from 55 % to 76 %, indicating better dewatering behaviour.

Effect of long-term operations on the performance of hollow fiber membrane contactor (HFMC) in recovering dissolved methane from anaerobic effluent.

Various studies provide information about the high potential of using hollow fiber membrane contactors (HFMCs) for the recovery of dissolved methane from anaerobically treated wastewater effluent and the effects of different operating conditions on their performance. However, majority of those studies evaluated HFMCs at bench scale under favorable conditions, i.e. clean water as feed under short-term operations. This study evaluated the performance of porous HFMC and dense HFMC (in terms of dissolved methane removal efficiency and methane desorption flux) subjected to anaerobic feed during long-term operation of one month. The study will provide better understanding of the performance of HFMCs with conditions expected at large-scale wastewater treatment systems. From the results, the decrease in the performance of HFMCs and the increase in the mass transfer resistance per week under varying feed flux were determined. These relationships were utilized in a numerical model to incorporate the effect of long-term operation to evaluate the performance of upscaled HFMCs. The fit of the model with the experimental data with one month of operation was evaluated and the relative errors were 11.9 % and 15.3 % for porous HFMC and dense HFMC, respectively. Moreover, results showed that dense HFMC will provide better performance than porous HFMC if it were to be operated longer than two weeks before cleaning. The net energy for porous HFMC and dense HFMC were optimized to be 0.07 and 0.02 kWh·d-1, respectively. Although these results are specific to the operations and conditions used for the HFMCs in this study, the methodology established for incorporating the effect of long-term operation will be highly relevant in evaluating the performance of HFMCs in large-scale wastewater treatment applications. This will contribute to the improved recovery of dissolved methane to reduce the greenhouse gas emissions in the atmosphere and to provide additional source of clean and sustainable energy.

A focused review on membrane contactors for the recovery of dissolved methane from anaerobic membrane bioreactor (AnMBR) effluents.

The need for a more sustainable wastewater treatment is more relevant now due to climate change. Production and reuse of methane from anaerobic treatment is one pathway. However, this is defeated by the presence of dissolved methane in the effluent and would be released to the environment, adding to the greenhouse gas emissions. This review paper provided summary and analysis of studies involved in the production of dissolved methane from AnMBR, focusing with actual methane measurement (gas and dissolved) from AnMBR with different types of wastewater. Then more focused discussion and analysis on the use of membrane-based technology or membrane contactors in the recovery of dissolved methane from AnMBR effluent are included, with its development and energy analysis. The dissolved methane removal and recovery rate of membrane contactors can be as high as 96% and 0.05 mol methane/m2/h, respectively, with very low additional energy requirement of 0.01 kWh/m3 for the recovery. Future perspectives presented focus on the long-term evaluation and modelling of membrane contactors and on the membrane modifications to improve the selectivity of membranes to methane and to limit their fouling and wetting, thus making the technology more economical for resource recovery.

Structural and Morphological Analysis of Cellulose Pulp Produced from the Fractionation of Eucalyptus obliqua Sawdust Using γ-Valerolactone.

Organic solvents offer promising methods for the fractionation of Eucalyptus obliqua lignocellulosic biomass. This study investigated the impact of γ-valerolactone (GVL) fractionation on the morphology of cellulose and its internal structure using scanning electron microscopy (SEM), nuclear magnetic resonance (NMR) and Fourier-transform infrared (FT-IR) spectroscopy. The solubilized lignin precipitated on the macrofibril surface as lignin spheres. GVL fractionation significantly increased the crystallinity of the recovered pulps from 0.29 for the sawdust to an average of 0.53 and a maximum of 0.66. The main states of cellulose that were susceptible to hydrolysis during the fractionation were amorphous and surface cellulose, both of which were reduced significantly, while paracrystalline and pure crystalline fractions in the pulp increased. It was concluded that GVL fractionation can produce a crystalline cellulose pulp of high quality suitable for further processing.

A selective fractionation method of lignocellulosic materials using electro-assisted organosolv pretreatment.

Lignocellulosic materials (LCMs) extracted from waste-wood products are promising sources of renewable chemicals and fuels. Organosolv pretreatment is commonly used for the fractionation of LCMs; however, these methods require high reaction temperatures, which remain problematic. In this study, room temperature ionic liquids (RTILs) and electrochemical conversion were used for LCMs fractionation. This paper presents a modified organosolv pretreatment, termed electro-assisted organosolv pretreatment (EAOP), which utilises gamma-valerolactone and 1-Butyl-3-methylimidazolium acetate as binary solution, in the presence of electrical energy. Importantly, EAOP can selectively fractionate lignin or cellulose at temperatures lower than 80 °C. Cellulose dissolution occurred at 2.4 V whereas lignin dissolution occurred at 4.2 V. A capacitance parameter was established and validated to describe the operating condition and selectively of EAOP. Operations conducted with capacitance less than 2317 F have the potential for cellulose solubilisation, whereas at capacitance exceeding 2317, lignin solubilisation was observed. This study showed that EAOP can overcome organosolv pretreatment shortfalls.

Effect of pre-treatment on sequential anaerobic co-digestion of chicken litter with agricultural and food wastes under semi-solid conditions and comparison with wet anaerobic digestion.

Sequential co-digestion batch assays were conducted using feedstocks of chicken litter (CL), food waste (FW) and wheat straw (WS) mixed to a C/N ratio of 26.5 and 15% TS. Untreated mixture produced biogas of 321.6 ±â€¯13.4 mLN/g VSadded which improved up to 50% when either CL or WS pre-treated substrates were fed. However, when both pre-treated CL and WS were fed, 80% and 88% increase in total biogas were found with associated VS removal of 49% and 55%, respectively, for alkali and sequential acid pre-treatment. Also, reactors received pre-treated substrates showed reduction in ammonia and digestate cellulose fraction with an increase in water soluble contents. Biogas production using sequential AD at 15% was almost 38% less than BMP biogas at 4%, however this was negated with the pre-treatment indicating that co-digestion at high TS of 15% is achievable. Further testing is required to confirm these results under semi-continuous conditions.

Process intensification of anaerobic digestion: Influence on mixing and process performance.

The adoption of process intensification to anaerobic digestion can present significant complications for digester mixing and process performance. This work investigated how increasing the solids concentration of the digester sludge influenced the process at various mixing energy inputs. Based on the results, adequate mixing is defined qualitatively as the input of sufficient energy to mobilize the reactor contents without producing significant regions of inhibitory shear force. However, the quantitative definition is dependent on the solids concentration of the sludge. But, the existing design criterion of specific mixing power input based on fluid volume (W/m3) does not represent it well. Therefore, a new design criterion of specific mixing power input based on total solids in the sludge (W/kgTS) is proposed to achieve maximum biogas production using optimum power input. The relationship has its limitations, but it represents a significant step forward in the design and operation of improved digester mixing systems.

Semi-continuous anaerobic co-digestion of chicken litter with agricultural and food wastes: A case study on the effect of carbon/nitrogen ratio, substrates mixing ratio and organic loading.

In this study, four agro-industrial substrates, chicken litter (CL), food waste (FW), wheat straw (WS) and hay grass (HG) were assessed as feedstock for anaerobic digestion (AD) under semi-continuous conditions at organic loading rates (OLRs) of 2.0-3.0 g TS/L.d and hydraulic retention time (HRT) of 20 days. Six different substrate mixtures were prepared such that the C/N ratio of each was 20 or more. Using principal component analysis 68.1% of data variability was explained. Biogas production from CL, as a single substrate, was 181.3 ±â€¯9.8mLN biogas/g VSadded at OLR of 2.0gTS/L.d. The optimum substrates mixture was CL:FW:WS 60:20:20, where 73.0%, 167.2% and 116.9% increase in total biogas production at OLR of 2.0, 2.5, 3.0gTS/L.d, respectively, compared to that from CL, was obtained. Digestate sequential fractionation revealed carbohydrate degradation is an important factor that can explain the variation in performance and production of biogas for feedstocks of balanced C/N ratio.

Fractionation of spent liquor from organosolv-pretreatment using lignin-incompatible extraction.

Spent liquor, or liquor in short, is the liquid stream resulting from organosolv pretreatment of lignocellulosic materials. The recovery of GVL, lignin and monosaccharide from the liquor is critical for producing value-added products and reducing operating costs. This work presents a new method, referred to as lignin-incompatible extraction, developed for the simultaneous recovery of GVL, lignin and monosaccharides from liquor. This method involves neutralisation of the liquor with calcium carbonate followed by extraction with toluene. Through the lignin-incompatible extraction, 87.6% of GVL was separated from liquor, 89.4% of lignin was precipitated during extraction, and 93.9% of xylose remained in the aqueous fraction. The lignin-incompatible extraction results correlated with the non-dispersion force parameters of the extracting solvent. The precipitated lignin indicated a lower hydrogen bonding ability and recycled GVL proved to have the same effectiveness in organosolv pretreatment in the first two cycles of operation.

Quantitative investigation of hydraulic mixing energy input during batch mode anaerobic digestion and its impact on performance.

The relationship between mixing energy input and biogas production was investigated by anaerobically digesting sewage sludge in lab scale, hydraulically mixed, batch mode digesters at six different specific energy inputs. The goal was to identify how mixing energy influenced digestion performance at quantitative levels to help explain the varying results in other published works. The results showed that digester homogeneity was largely uninfluenced by energy input, whereas cumulative biogas production and solids destruction were. With similar solids distributions between conditions, the observed differences were attributed to shear forces disrupting substrate-microbe flocs rather than the formation of temperature and/or concentration gradients. Disruption of the substrate-microbe flocs produced less favourable conditions for hydrolytic bacteria, resulting in less production of biomass and more biogas. Overall, this hypothesis explains the current body of research including the inhibitory conditions reported at extreme mixing power inputs. However, further work is required to definitively prove it.

Life cycle assessment to compare the environmental impact of seven contemporary food waste management systems.

Municipal food waste (FW) represents 35-45% of household residual waste in Australia, with the nation generating 1.6Tg annually. It is estimated that 91% of this FW ends up in landfill. This study used life cycle assessment to determine and compare the environmental impact of seven contemporary FW management systems for two real-life jurisdictions; incorporating the complete waste service and expanding the system to include inert and garden waste. Although, no system exhibited a best ranking across all impact categories, FW digestion based systems were all revealed to have a lower global warming potential than composting and landfilling systems. Mechanical biological treatment, anaerobic co-digestion, and home composting all demonstrated the lowest environmental impacts for two or more of the environmental impact categories assessed. The assessment included market and technological specific variables and uncertainties providing a framework for robust decision making at a municipality level.

Application of Victorian brown coal for removal of ammonium and organics from wastewater.

Brown coal is a relatively abundant and low-cost material, which has been used as an effective ion-exchanger to remove ammonium from wastewater. In this study, the influences of pH, ammonium concentration and brown coal dose were investigated for removal of ammonium content from synthetic wastewater. Raw brown coal (RBC) treated with base solution has superior ammonium removal efficiency compared to RBC, which was due to chemical alterations and thus greater attachment of ammonium molecules to base-washed brown coal (BWBC), confirmed by Fourier transform infra-red spectroscopy. Scanning electron microscopy-electron diffraction scattering has identified the augmented sodium content in BWBC, which was subsequently replaced with nitrogen upon wastewater treatment. Crystallographic analysis showed a higher crystallinity formed in BWBC compared to RBC, which was likely due to formation of sodium salt crystals during NaOH treatment. Fitting batch experimental results to adsorption kinetic models suggested that the removal of ammonium was mainly governed by the reaction process rather than the physical diffusion mechanism. Both kinetic and isotherm studies confirmed higher adsorption capacity for BWBC compared to RBC. RBC in column mode was also experimented with to show organics removal from a secondary effluent. A comparatively lower removal of organics was obtained due to inability of charge neutralization as both brown coal and organics are positively charged.

Anaerobic digestion/co-digestion kinetic potentials of different agro-industrial wastes: A comparative batch study for C/N optimisation.

Anaerobic digestion (AD) of different agro-industrial wastes and their co-digestion potential has been exhaustively studied in this research. It explores variation of feedstock characteristics such as biodegradability and methane potential during AD and anaerobic co-digestion (ACoD) of chicken litter (CL) with yoghurt whey (YW), organic fraction of municipal solid waste (OFMSW), hay grass (HG) and wheat straw (WS) under mesophilic conditions. Comparative performance was made at different loading concentrations (2%, 3% and 4% VS) with 1:2g/g VS of substrate to inoculum and carrying C/N ratio. Among different kinetic models, the AD of single substrates showed better fit to the modified Gompertz model (R2: 0.93-0.997) indicating variation in lag phase and methane production rate depend on the substrate characteristics. During ACoD, the methane yield improved by 9-85% through the addition of two, three or four substrates due to the synergistic effect asa result of increased biodegradability and optimum conditions (such asC/N ratio). A surface (optimisation) model indicated that maximum methane production can be achieved by blending chicken litter (30-35%) and a (65-70%) mixture of yoghurt whey, hay and wheat straw with aC/N ratio of (26-27.5).

Bioethanol potential of Eucalyptus obliqua sawdust using gamma-valerolactone fractionation.

Optimisation of conditions for gamma-valerolactone (GVL) pretreatment of Australian eucalyptus sawdust for high cellulose biomass and bioethanol production was demonstrated. Pretreatment parameters investigated included GVL concentrations of 35-50% w/w, temperatures of 120-180 °C and reaction durations of 0.5-2.0 h. Optimum conditions were determined using the response surface method (RSM) and central composite face-centred design. Cellulose content increased from 39.9% to a maximum of 89.3% w/w using treatments with 50% GVL at 156 °C for 0.5 h. Temperature had the most significant effect (RSM p < .05) on cellulose content of residual biomass and reducing operational duration of < 0.5 h may be viable according to RSM. PSSF fermentations of optimised pretreated eucalyptus sawdust produced up to 94% theoretical ethanol yield, which corresponded to approximately 181 kg of ethanol per dry ton of eucalyptus sawdust. The compositions of both the residual biomass and pretreatment liquors show that GVL pretreatment is a promising solvent for lignocellulosic biorefining.

Life cycle inventory and mass-balance of municipal food waste management systems: Decision support methods beyond the waste hierarchy.

When assessing the environmental and human health impact of a municipal food waste (FW) management system waste managers typically rely on the principles of the waste hierarchy; using metrics such as the mass or rate of waste that is 'prepared for recycling,' 'recovered for energy,' or 'sent to landfill.' These metrics measure the collection and sorting efficiency of a waste system but are incapable of determining the efficiency of a system to turn waste into a valuable resource. In this study a life cycle approach was employed using a system boundary that includes the entire waste service provision from collection to safe end-use or disposal. A life cycle inventory of seven waste management systems was calculated, including the first service wide inventory of FW management through kitchen in-sink disposal (food waste disposer). Results describe the mass, energy and water balance of each system along with key emissions profile. It was demonstrated that the energy balance can differ significantly from its' energy generation, exemplified by mechanical biological treatment, which was the best system for generating energy from waste but only 5th best for net-energy generation. Furthermore, the energy balance of kitchen in-sink disposal was shown to be reduced because 31% of volatile solids were lost in pre-treatment. The study also confirmed that higher FW landfill diversion rates were critical for reducing many harmful emissions to air and water. Although, mass-balance analysis showed that the alternative end-use of the FW material may still contain high impact pollutants.

Anaerobic co-digestion of municipal food waste and sewage sludge: A comparative life cycle assessment in the context of a waste service provision.

This study used life cycle assessment to evaluate the environmental impact of anaerobic co-digestion (AcoD) and compared it against the current waste management system in two case study areas. Results indicated AcoD to have less environmental impact for all categories modelled excluding human toxicity, despite the need to collect and pre-treat food waste separately. Uncertainty modelling confirmed that AcoD has a 100% likelihood of a smaller global warming potential, and for acidification, eutrophication and fossil fuel depletion AcoD carried a greater than 85% confidence of inducing a lesser impact than the current waste service.

Anaerobic Codigestion of Municipal Wastewater Treatment Plant Sludge with Food Waste: A Case Study.

The aim of this study was to assess the effects of the codigestion of food manufacturing and processing wastes (FW) with sewage sludge (SS), that is, municipal wastewater treatment plant primary sludge and waste activated sludge. Bench scale mesophilic anaerobic reactors were fed intermittently with varying ratio of SS and FW and operated at a hydraulic retention time of 20 days and organic loading of 2.0 kg TS/m3·d. The specific biogas production (SBP) increased by 25% to 50% with the addition of 1%-5% FW to SS which is significantly higher than the SBP from SS of 284 ± 9.7 mLN/g VS added. Although the TS, VS, and tCOD removal slightly increased, the biogas yield and methane content improved significantly and no inhibitory effects were observed as indicated by the stable pH throughout the experiment. Metal screening of the digestate suggested the biosolids meet the guidelines for use as a soil conditioner. Batch biochemical methane potential tests at different ratios of SS : FW were used to determine the optimum ratio using surface model analysis. The results showed that up to 47-48% FW can be codigested with SS. Overall these results confirm that codigestion has great potential in improving the methane yield of SS.

Energy and time modelling of kerbside waste collection: Changes incurred when adding source separated food waste.

The collection of source separated kerbside municipal FW (SSFW) is being incentivised in Australia, however such a collection is likely to increase the fuel and time a collection truck fleet requires. Therefore, waste managers need to determine whether the incentives outweigh the cost. With literature scarcely describing the magnitude of increase, and local parameters playing a crucial role in accurately modelling kerbside collection; this paper develops a new general mathematical model that predicts the energy and time requirements of a collection regime whilst incorporating the unique variables of different jurisdictions. The model, Municipal solid waste collect (MSW-Collect), is validated and shown to be more accurate at predicting fuel consumption and trucks required than other common collection models. When predicting changes incurred for five different SSFW collection scenarios, results show that SSFW scenarios require an increase in fuel ranging from 1.38% to 57.59%. There is also a need for additional trucks across most SSFW scenarios tested. All SSFW scenarios are ranked and analysed in regards to fuel consumption; sensitivity analysis is conducted to test key assumptions.

The use of laboratory scale reactors to predict sensitivity to changes in operating conditions for full-scale anaerobic digestion treating municipal sewage sludge.

Anaerobic digestion of sewage sludge is highly complex and prone to inhibition, which can cause major issues for digester operators. The result is that there have been numerous investigations into changes in operational conditions, however to date all have focused on the qualitative sensitivities, neglecting the quantitative. This study therefore aimed to determine the quantitative sensitivities by using factorial design of experiments and small semi continuous reactors. Analysis showed total and volatile solids removals are chiefly influenced by retention time, with 79% and 59% of the observed results being attributed to retention time respectively, whereas biogas was mainly influenced by loading rate, 38%, and temperature, 22%. Notably the regression model fitted to the experimental data predicted full-scale performance with a high level of precision, indicating that small reactors are subject to the same sensitivity of full-scale digesters and thus can be used to predict changes loading, retention time, and temperature.

Dynamics of biofilm formation during anaerobic digestion of organic waste.

Biofilm-based reactors are effectively used for wastewater treatment but are not common in biogas production. This study investigated biofilm dynamics on biofilm carriers incubated in batch biogas reactors at high and low organic loading rates for sludge from meat industry dissolved air flotation units. Biofilm formation and dynamics were studied using various microscopic techniques. Resulting micrographs were analysed for total cell numbers, thickness of biofilms, biofilm-covered surface area, and the area covered by extracellular polymeric substances (EPS). Cell numbers within biofilms (10(11) cells ml(-1)) were up to one order of magnitude higher compared to the numbers of cells in the fluid reactor content. Further, biofilm formation and structure mainly correlated with the numbers of microorganisms present in the fluid reactor content and the organic loading. At high organic loading (45 kg VS m(-3)), the thickness of the continuous biofilm layer ranged from 5 to 160 µm with an average of 51 µm and a median of 26 µm. Conversely, at lower organic loading (15 kg VS m(-3)), only microcolonies were detectable. Those microcolonies increased in their frequency of occurrence during ongoing fermentation. Independently from the organic loading rate, biofilms were embedded completely in EPS within seven days. The maturation and maintenance of biofilms changed during the batch fermentation due to decreasing substrate availability. Concomitant, detachment of microorganisms within biofilms was observed simultaneously with the decrease of biogas formation. This study demonstrates that biofilms of high cell densities can enhance digestion of organic waste and have positive effects on biogas production.