RESUMEN
In this study, batch flotation tests were conducted to investigate the flotation of oxidized copper ore from the supergene zone of the Bounhas deposit. Utilizing the Response Surface Methodology (RSM) anchored on the Box-Behnken Design (BBD), the effects of parameters such as collector dosage, sulfidizing agent, copper oxide and iron oxide grades, and particle size on copper recovery were explored. ANOVA and response surface plots elucidated the complex behavior of copper flotation. Mineralogical analyses of the initial feed and postflotation tails were performed on an industrial scale using advanced Zeiss microscopy. The quadratic model with an R 2 of 94.49% accurately captured the impact of the process parameters on copper recovery. Among the key findings, the sulfidizing agent exhibited the most substantial quadratic effect, while the copper oxide grade had the most substantial linear impact on recovery. A pivotal observation was the link between copper losses in tailings and specific iron oxide-copper associations. Optimization identified conditions leading to a maximum copper recovery rate of 71.49%. When validated industrially, the model demonstrated robust applicability for analogous mineral processing contexts. The study's mineralogical insights enhance our understanding of the supergene zone mineralization and offer a solid foundation for subsequent in-depth mineral processing studies.
RESUMEN
Herein, bio-based alginates (Alg) containing metallic beads (Ce and Cu) were synthesized via an alginate cross-linking method, and their properties were studied using experimental techniques combined with theoretical simulations. Materials were characterized through Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and scanning electron microscope (SEM) images, to determine the cross-linking structural features, thermal stability, and surface morphology of alginates. Besides, density functional theory (DFT) methods were employed to calculate global reactivity parameters such as HOMO-LUMO gap energies (ΔEH-L), electronegativity (χ), hardness (η), and electrophilic and nucleophilic indicators, using both gas and aqueous media for the study of the complexation process. Among other features, characterization of the thermal properties showed that Alg@Ce and Alg@Cu alginate beads behave differently as a function of the temperature. This behavior was also predicted by the conformation energy differences between Alg@Ce and Alg@Cu, which were found out theoretically and explained with the combined study of the vibrational modes between the carboxylate group with either Ce or Cu. Overall, the reactivity of the Alg@Ce alginate bead was higher than that of the Alg@Cu counterpart, results could be used as a cornerstone to employed the materials here studied in a wide range of applications.
Asunto(s)
Alginatos/química , Materiales Biocompatibles/química , Cerio/química , Fenómenos Químicos , Cobre/química , Modelos Teóricos , Algoritmos , Materiales Biocompatibles/síntesis química , Técnicas de Química Sintética , Tecnología Química Verde , Modelos Moleculares , Análisis EspectralRESUMEN
Five novel pyrazolylnucleosides have been evaluated theoretically for their corrosion inhibition efficiency on the Cu(111) surface in acidic media. DFT calculations were carried out to exhibit the intrinsic properties such as lowest unoccupied (ELUMO) and highest occupied (EHOMO) molecular orbital energies, as well as energy gap (∆E), chemical hardness (η), chemical softness (σ), electronegativity (χ), electrophilicity (ω) and nucleophilicity (ε). The theoretical FT-IR spectra were recorded to indicate the presence of the specific bonds in the studied molecules. The surface interactions between the inhibitor molecules and the metal surface were investigated using molecular dynamics simulations and Monte Carlo (MC) simulations. As a result, we have found that the inhibitor pyrazolylnucleosides 5a-e have strong interactions with Cu(111) surface, and therefore have excellent predictive inhibition power against copper corrosion.
RESUMEN
The inhibition efficiency of benzoic acid (C1), para-hydroxybenzoic acid (C2), and 3,4-dihydroxybenzoic acid (C3) towards enhancing the corrosion resistance of austenitic AISI 316 stainless steel (SS) has been evaluated in 0.5 M HCl using weight loss (WL), open circuit potential (OCP), potentiodynamic polarization method, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM) analysis. The results obtained from the different experimental techniques were consistent and showed that the inhibition efficiency of these inhibitors increased with the increase in concentration in this order C3 > C2 > C1. In addition, the results of the weight loss measurements showed that these inhibitors followed the Villamil isotherm. Quantum chemical calculations and Monte Carlo simulations have also been used for further insight into the adsorption mechanism of the inhibitor molecules on Fe (110). The quantum chemical parameters have been calculated by density functional theory (DFT) at the B3LYP level of theory with 6-31G+(2d,p) and 6-31G++(2d,p) basis sets in gas and aqueous phase. Parameters such as the lowest unoccupied (E LUMO) and highest occupied (E HOMO) molecular orbital energies, energy gap (ΔE), chemical hardness (η), softness (σ), electronegativity (χ), electrophilicity (ω), and nucleophilicity (ε) were calculated and showed the anti-corrosive properties of C1, C2 and C3. Moreover, theoretical vibrational spectra were calculated to exhibit the functional hydroxyl groups (OH) in the studied compounds. In agreement with the experimental data, the theoretical results showed that the order of inhibition efficiency was C3 > C2 > C1.
RESUMEN
The influence of chitosan on the copper corrosion in sulfide polluted synthetic seawater (SSW) containing 20â¯ppm of sulfide has been investigated for the first time. Potentiodynamic polarization measurements, electrochemical impedance spectroscopy at the open circuit potential and weight loss measurements were employed to assess the corrosion inhibition ability of chitosan. The impedance studies revealed that in the presence of chitosan at various concentrations, the charge transfer resistance increases. At a concentration of 800â¯ppm, chitosan exhibited a corrosion inhibition efficiency of 89% following physical adsorption. The influence of temperature and immersion time was studied in sulfide-contaminated synthetic seawater and significant inhibition was observed even after 90â¯days. SEM-EDS studies confirm the absence of the deterioration products on copper surface.