Daily scale air quality index forecasting using bidirectional recurrent neural networks: Case study of Delhi, India.

This research was established to accurately forecast daily scale air quality index (AQI) which is an essential environmental index for decision-making. Researchers have projected different types of models and methodologies for AQI forecasting, such as statistical techniques, machine learning (ML), and most recently deep learning (DL) models. The modelling development was adopted for Delhi city, India which is a major city with air pollution issues simialir to entire urban cities of India especially during winter seasons. This research was predicted AQI using different versions of DL models including Long-Short Term Memory (LSTM), Bidirectional LSTM (Bi-LSTM) and Bidirectional Recurrent Neural Networks (Bi-RNN) in addition to Kernel Ridge Regression (KRR). Results indicated that Bi-RNN model consistently outperformed the other models in both training and testing phases, while the KRR model consistently displayed the weakest performance. The outstanding performance of the models development displayed the requirement of adequate data to train the models. The outcomes of the models showed that LSTM, BI-LSTM, KRR had lower performance compared with Bi-RNN models. Statistically, Bi-RNN model attained maximum cofficient of determination (R2 = 0.954) and minimum root mean square error (RMSE = 25.755). The proposed model in this research revealed the robust predictable to provide a valuable base for decision-making in the expansion of combined air pollution anticipation and control policies targeted at addressing composite air pollution problems in the Delhi city.

Assessing metal(loid)s-Induced long-term spatiotemporal health risks in Coastal Regions, Bay of Bengal: A chemometric study.

Despite sporadic and irregular studies on heavy metal(loid)s health risks in water, fish, and soil in the coastal areas of the Bay of Bengal, no chemometric approaches have been applied to assess the human health risks comprehensively. This review aims to employ chemometric analysis to evaluate the long-term spatiotemporal health risks of metal(loid)s e.g., Fe, Mn, Zn, Cd, As, Cr, Pb, Cu, and Ni in coastal water, fish, and soils from 2003 to 2023. Across coastal parts, studies on metal(loid)s were distributed with 40% in the southeast, 28% in the south-central, and 32% in the southwest regions. The southeastern area exhibited the highest contamination levels, primarily due to elevated Zn content (156.8 to 147.2 mg/L for Mn in water, 15.3 to 13.2 mg/kg for Cu in fish, and 50.6 to 46.4 mg/kg for Ni in soil), except for a few sites in the south-central region. Health risks associated with the ingestion of Fe, As, and Cd (water), Ni, Cr, and Pb (fish), and Cd, Cr, and Pb (soil) were identified, with non-carcinogenic risks existing exclusively through this route. Moreover, As, Cr, and Ni pose cancer risks for adults and children via ingestion in the southeastern region. Overall non-carcinogenic risks emphasized a significantly higher risk for children compared to adults, with six, two-, and six-times higher health risks through ingestion of water, fish, and soils along the southeastern coast. The study offers innovative sustainable management strategies and remediation policies aimed at reducing metal(loid)s contamination in various environmental media along coastal Bangladesh.

Source identification and potential health risks from elevated groundwater nitrate contamination in Sundarbans coastal aquifers, India.

In recent years groundwater contamination through nitrate contamination has increased rapidly in the managementof water research. In our study, fourteen nitrate conditioning factors were used, and multi-collinearity analysis is done. Among all variables, pH is crucial and ranked one, with a value of 0.77, which controls the nitrate concentration in the coastal aquifer in South 24 Parganas. The second important factor is Cl-, the value of which is 0.71. Other factors like-As, F-, EC and Mg2+ ranked third, fourth and fifth position, and their value are 0.69, 0.69, 0.67 and 0.55, respectively. Due to contaminated water, people of this district are suffering from several diseases like kidney damage (around 60%), liver (about 40%), low pressure due to salinity, fever, and headache. The applied method is for other regions to determine the nitrate concentration predictions and for the justifiable alterationof some management strategies.

Climate change and geo-environmental factors influencing desertification: a critical review.

The problem of desertification (DSF) is one of the most severe environmental disasters which influence the overall condition of the environment. In Rio de Janeiro Earth Summit on Environment and Development (1922), DSF is defined as arid, semi-arid, and dry sub-humid induced LD and that is adopted at the UNEP's Nairobi ad hoc meeting in 1977. It has been seen that there is no variability in the trend of long-term rainfall, but the change has been found in the variability of temperature (avg. temp. 0-5 °C). There is no proof that the air pollution brought on by CO2 and other warming gases is the cause of this rise, which seems to be partially caused by urbanization. The two types of driving factors in DSF-CC (climate change) along with anthropogenic influences-must be compared in order to work and take action to stop DSF from spreading. The proportional contributions of human activity and CC to DSF have been extensively evaluated in this work from "qualitative, semi-quantitative, and quantitative" perspectives. In this study, we have tried to connect the drives of desertification to desertification-induced migration due to loss of biodiversity and agriculture failure. The authors discovered that several of the issues from the earlier studies persisted. The policy-makers should follow the proper SLM (soil and land management) through using the land. The afforestation with social forestry and consciousness among the people can reduce the spreading of the desertification (Badapalli et al. 2023). The green wall is also playing an important role to reduce the desertification. For instance, it was clear that assessments were subjective; they could not be readily replicated, and they always relied on administrative areas rather than being taken and displayed in a continuous space. This research is trying to fulfill the mentioned research gap with the help of the existing literatures related to this field.

Hydro-chemical based assessment of groundwater vulnerability in the Holocene multi-aquifers of Ganges delta.

Determining the degree of high groundwater arsenic (As) and fluoride (F-) risk is crucial for successful groundwater management and protection of public health, as elevated contamination in groundwater poses a risk to the environment and human health. It is a fact that several non-point sources of pollutants contaminate the groundwater of the multi-aquifers of the Ganges delta. This study used logistic regression (LR), random forest (RF) and artificial neural network (ANN) machine learning algorithm to evaluate groundwater vulnerability in the Holocene multi-layered aquifers of Ganges delta, which is part of the Indo-Bangladesh region. Fifteen hydro-chemical data were used for modelling purposes and sophisticated statistical tests were carried out to check the dataset regarding their dependent relationships. ANN performed best with an AUC of 0.902 in the validation dataset and prepared a groundwater vulnerability map accordingly. The spatial distribution of the vulnerability map indicates that eastern and some isolated south-eastern and central middle portions are very vulnerable in terms of As and F- concentration. The overall prediction demonstrates that 29% of the areal coverage of the Ganges delta is very vulnerable to As and F- contents. Finally, this study discusses major contamination categories, rising security issues, and problems related to groundwater quality globally. Henceforth, groundwater quality monitoring must be significantly improved to successfully detect and reduce hazards to groundwater from past, present, and future contamination.

Using unsupervised machine learning models to drive groundwater chemistry and associated health risks in Indo-Bangla Sundarban region.

Groundwater is an essential resource in the Sundarban regions of India and Bangladesh, but its quality is deteriorating due to anthropogenic impacts. However, the integrated factors affecting groundwater chemistry, source distribution, and health risk are poorly understood along the Indo-Bangla coastal border. The goal of this study is to assess groundwater chemistry, associated driving factors, source contributions, and potential non-carcinogenic health risks (PN-CHR) using unsupervised machine learning models such as a self-organizing map (SOM), positive matrix factorization (PMF), ion ratios, and Monte Carlo simulation. For the Sundarban part of Bangladesh, the SOM clustering approach yielded six clusters, while it yielded five for the Indian Sundarbans. The SOM results showed high correlations among Ca2+, Mg2+, and K+, indicating a common origin. In the Bangladesh Sundarbans, mixed water predominated in all clusters except for cluster 3, whereas in the Indian Sundarbans, Cl--Na+ and mixed water dominated in clusters 1 and 2, and both water types dominated the remaining clusters. Coupling of SOM, PMF, and ionic ratios identified rock weathering as a driving factor for groundwater chemistry. Clusters 1 and 3 were found to be influenced by mineral dissolution and geogenic inputs (overall contribution of 47.7%), while agricultural and industrial effluents dominated clusters 4 and 5 (contribution of 52.7%) in the Bangladesh Sundarbans. Industrial effluents and agricultural activities were associated with clusters 3, 4, and 5 (contributions of 29.5% and 25.4%, respectively) and geogenic sources (contributions of 23 and 22.1% in clusters 1 and 2) in Indian Sundarbans. The probabilistic health risk assessment showed that NO3- poses a higher PN-CHR risk to human health than F- and As, and that potential risk to children is more evident in the Bangladesh Sundarban area than in the Indian Sundarbans. Local authorities must take urgent action to control NO3- emissions in the Indo-Bangla Sundarbans region.

Hydrogeochemical properties of groundwater and associated human health hazards in coastal multiaquifers of India.

Due to the scarcity of water supplies, coastal groundwater quality most importantly influences sustainable development in the coastal region. Rising groundwater pollution through heavy metal contamination is an intense health hazard and environmental concern worldwide. This study shows that 27%, 32%, and 10% of the total area come under the categories very high, high, and very low human health hazard index (HHHI) accordingly. This area's water quality is also much polluted; the study shows approximately 1% has very good water quality. High concentrations of Fe, As, TDS, Mg2+, Na, and Cl- are relatively noticed in the portion of the western part of this district. The concentration of heavy metals in coastal aquifers influences the groundwater pollution of that region. The average heavy metal concentration in this region is 0.20 mg/l (As) and 1.160 mg/l (TDS). The groundwater quality and hydrogeochemical properties are determined through the Piper diagram. The study stated that TDS, Cl- (mg/l), and Na+ (mg/l) are the most regulatory issues of vulnerability. In the present study region, a huge number of alkaline substances are present resulting in the water being unfit for drinking purposes. Lastly, it is clear from the study's findings that multiple risks exist there like As, TDS, Cl-, and other hydrochemical parameters in the groundwater. The proposed approach applied in this research work may be a pivotal tool for predicting groundwater vulnerability in other regions.

A review of recent advances and future prospects in calculation of reference evapotranspiration in Bangladesh using soft computing models.

Evapotranspiration (ETo) is a complex and non-linear hydrological process with a significant impact on efficient water resource planning and long-term management. The Penman-Monteith (PM) equation method, developed by the Food and Agriculture Organization of the United Nations (FAO), represents an advancement over earlier approaches for estimating ETo. Eto though reliable, faces limitations due to the requirement for climatological data not always available at specific locations. To address this, researchers have explored soft computing (SC) models as alternatives to conventional methods, known for their exceptional accuracy across disciplines. This critical review aims to enhance understanding of cutting-edge SC frameworks for ETo estimation, highlighting advancements in evolutionary models, hybrid and ensemble approaches, and optimization strategies. Recent applications of SC in various climatic zones in Bangladesh are evaluated, with the order of preference being ANFIS > Bi-LSTM > RT > DENFIS > SVR-PSOGWO > PSO-HFS due to their consistently high accuracy (RMSE and R2). This review introduces a benchmark for incorporating evolutionary computation algorithms (EC) into ETo modeling. Each subsection addresses the strengths and weaknesses of known SC models, offering valuable insights. The review serves as a valuable resource for experienced water resource engineers and hydrologists, both domestically and internationally, providing comprehensive SC modeling studies for ETo forecasting. Furthermore, it provides an improved water resources monitoring and management plans.

A review of microplastic threat mitigation in Asian lentic environments.

Microplastic (MP) pollution has evolved into a significant worldwide environmental concern due to its widespread sources, enduring presence, and adverse effects on lentic ecosystems and human well-being. The growing awareness of the hidden threat posed by MPs in lentic ecosystems has emphasized the need for more in-depth research. Unlike marine environments, there remain unanswered questions about MP hotspots, ecotoxic effects, transport mechanisms, and fragmentation in lentic ecosystems. The introduction of MPs represents a novel threat to long-term environmental health, posing unresolved challenges for sustainable management. While MP pollution in lentic ecosystems has garnered global attention due to its ecotoxicity, our understanding of MP hotspots in lakes from an Asian perspective remains limited. Hence, the aim of this review is to provide a comprehensive analysis of MP hotspots, morphological attributes, ecotoxic impacts, sustainable solutions, and future challenges across Asia. The review summarizes the methods employed in previous studies and the techniques for sampling and analyzing microplastics in lake water and sediment. Notably, most studies concerning lake microplastics tend to follow the order of China > India > Pakistan > Nepal > Turkey > Bangladesh. Additionally, this review critically addresses the analysis of microplastics in lake water and sediment, shedding light on the prevalent net-based sampling methods. Ultimately, this study emphasizes the existing research gaps and suggests new research directions, taking into account recent advancements in the study of microplastics in lentic environments. In conclusion, the review advocates for sustainable interventions to mitigate MP pollution in the future, highlighting the presence of MPs in Asian lakes, water, and sediment, and their potential ecotoxicological repercussions on both the environment and human health.

Modelling groundwater vulnerability in a vulnerable deltaic coastal region of Sundarban Biosphere Reserve, India.

Groundwater is the most reliable source of freshwater for human well-being. Significant toxic contamination in groundwater, particularly in the aquifers of the Ganges delta, has been a substantial source of arsenic (As). The Sundarban Biosphere Reserve (SBR), located in the southwestern part of the world's largest Ganges delta, suffers from As contamination in groundwater. Therefore, assessment of groundwater vulnerability is essential to ensure the safety of groundwater quality in SBR. Three data-driven algorithms, i.e. "logistic regression (LR)", "random forest (RF)", and "boosted regression tree (BRT)", were used to assess groundwater vulnerability. Groundwater quality and hydrogeochemical characteristics were evaluated by Piper, United States Salinity Laboratory (USSL), and Wilcox's diagram. The result of this study indicates that among the applied models, BRT (AUC = 0.899) is the best-fit model, followed by RF (AUC = 0.882) and LR (AUC = 0.801) to assess groundwater vulnerability. In addition, the result also indicates that the general quality of the groundwater in this area is not very good for drinking purposes. The applied methods of this study can be used to evaluate the groundwater vulnerability of the other aquifer systems.

Spatio-temporal assessment of water quality of a tropical decaying river in India for drinking purposes and human health risk characterization.

River water pollution and water-related health problems are common issues across the world. The present study aims to examine the Jalangi River's water quality to assess its suitability for drinking purposes and associated human health risks. The 34 water samples were collected from the source to the mouth of Jalangi River in 2022 to depict the spatial dynamics while another 119 water samples (2012-2022) were collected from a secondary source to portray the seasonal dynamics. Results indicate better water quality in the lower reach of the river in the monsoon and post-monsoon seasons. Principal component analysis reveals that K+, NO3-, and total alkalinity (TA) play a dominant role in controlling the water quality of the study region, while, CaCO3, Ca2+, and EC in the pre-monsoon, EC, TDS, Na+, and TA in the monsoon, and EC, TDS and TA in the post-monsoon controlled the water quality. The results of ANOVA reveal that BOD, Ca2+, and CaCO3 concentrations in water have significant spatial dynamics, whereas pH, BOD, DO, Cl-, SO42-, Na+, Mg2+, Ca2+, CaCO3, TDS, TA, and EC have seasonal dynamics (p < 0.05). The water quality index depicts that the Jalangi River's water quality ranged from 6.23 to 140.83, i.e., excellent to unsuitable for drinking purposes. Human health risk analysis shows that 32.35% of water samples have non-carcinogenic health risks for all three groups of people, i.e., adults, children, and infants while only 5.88% of water samples have carcinogenic health risks for adults and children. The gradual decay of the Jalangi River coupled with the disposal of urban and agricultural effluents induces river pollution that calls for substantial attention from the various stakeholders to restore the water quality.

Receptor model-based source-specific health risks of toxic metal(loid)s in coal basin-induced agricultural soil in northwest Bangladesh.

Toxic metal(loid)s (TMLs) in agricultural soils cause detrimental effects on ecosystem and human health. Therefore, source-specific health risk apportionment is very crucial for the prevention and control of TMLs in agricultural soils. In this study, 149 surface soil samples were taken from a coal mining region in northwest Bangladesh and analyzed for 12 TMLs (Pb, Cd, Ni, Cr, Mn, Fe, Co, Zn, Cu, As, Se, and Hg). Positive matrix factorization (PMF) and absolute principal component score-multiple linear regression (APCS-MLR) receptor models were employed to quantify the pollution sources of soil TMLs. Both models identified five possible sources of pollution: agrochemical practice, industrial emissions, coal-power-plant, geogenic source, and atmospheric deposition, while the contribution rates of each source were calculated as 28.2%, 17.2%, 19.3%, 19% and 16.3% in APCS-MLR, 22.2%, 13.4%, 24.3%, 15.1% and 25.1% in PMF, respectively. Agrochemical practice was the major source of non-carcinogenic risk (NCR) (adults: 32.37%, children: 31.54%), while atmospheric deposition was the highest source of carcinogenic risk (CR) (adults: 48.83%, children: 50.11%). NCR and CR values for adults were slightly higher than for children. However, the trends in NCR and CR between children and adults were similar. As a result, among the sources of pollution, agrochemical practices and atmospheric deposition have been identified as the primary sources of soil TMLs, so prevention and control strategies should be applied primarily for these pollution sources in order to protect human health.

Assessment of soil heavy metal pollution and associated ecological risk of agriculture dominated mid-channel bars in a subtropical river basin.

The elevated concentrations of heavy metals in soil considerably threaten ecological and human health. To this end, the present study assesses metals pollution and its threat to ecology from the mid-channel bar's (char) agricultural soil in the Damodar River basin, India. For this, the contamination factor (CF), enrichment factor (EF), geoaccumulation index (Igeo), pollution index, and ecological risk index (RI) were measured on 60 soil samples at 30 stations (2 from each station, i.e., surface and sub-surface) in different parts of the mid-channel bar. The CF and EF indicate that both levels of char soil have low contamination and hence portray a higher potential for future enrichment by heavy metals. Moreover, Igeo portrays that soil samples are uncontaminated to moderately contaminated. Further, pollution indices indicate that all the samples (both levels) are unpolluted with a mean of 0.062 for surface soils and 0.048 for sub-surface soils. Both levels of the char have a low potentiality for ecological risk with an average RI of 0.20 for the surface soils and 0.19 for the sub-surface soils. Moreover, Technique for order preference by similarity to ideal solution (TOPSIS) indicates that the sub-surface soils have lower pollution than the surface soils. The geostatistical modeling reveals that the simple kriging technique was estimated as the most appropriate interpolation model. The present investigation exhibits that reduced heavy metal pollution is due to the sandy nature of soils and frequent flooding. However, the limited pollution is revealed due to the intensive agricultural practices on riverine chars. Therefore, this would be helpful to regional planners, agricultural engineers, and stakeholders in a basin area.

Land subsidence susceptibility mapping: comparative assessment of the efficacy of the five models.

Land subsidence (LS) as a major geological and hydrological hazard poses a major threat to safety and security. The various triggers of LS include intense extraction of aquifer bodies. In this study, we present an LS inventory map of the Daumeghan plain of Iran using 123 LS and 123 non-LS locations which were identified through field survey. Fourteen LS causative factors related to topography, geology, hydrology, and anthropogenic characteristics were selected based on multi-collinearity test. Based on the results, five susceptibility maps were generated employing models and input data. The LS susceptibility models were evaluated and validated using the receiver operating characteristic (ROC) curve and statistical indices. The results indicate that the LS susceptibility maps produced have good accuracy in predicting the spatial distribution of LS in the study area. The result showed that the optimization models BA and GWO were better than the other machine learning algorithm (MLA). In addition, The BA model has 96.6% area under of ROC (AUROC) followed by GWO (95.8%), BART (94.5%), BRT (93.1%), and SVR (92.7%). The LS susceptibility maps formulated in our study can serve as a useful tool for formulating mitigation strategies and for better land-use planning.

Estimating ground-level PM2.5 using subset regression model and machine learning algorithms in Asian megacity, Dhaka, Bangladesh.

Fine particulate matter (PM2.5) has become a prominent pollutant due to rapid economic development, urbanization, industrialization, and transport activities, which has serious adverse effects on human health and the environment. Many studies have employed traditional statistical models and remote-sensing technologies to estimate PM2.5 concentrations. However, statistical models have shown inconsistency in PM2.5 concentration predictions, while machine learning algorithms have excellent predictive capacity, but little research has been done on the complementary advantages of diverse approaches. The present study proposed the best subset regression model and machine learning approaches, including random tree, additive regression, reduced error pruning tree, and random subspace, to estimate the ground-level PM2.5 concentrations over Dhaka. This study used advanced machine learning algorithms to measure the effects of meteorological factors and air pollutants (NOX, SO2, CO, and O3) on the dynamics of PM2.5 in Dhaka from 2012 to 2020. Results showed that the best subset regression model was well-performed for forecasting PM2.5 concentrations for all sites based on the integration of precipitation, relative humidity, temperature, wind speed, SO2, NOX, and O3. Precipitation, relative humidity, and temperature have negative correlations with PM2.5. The concentration levels of pollutants are much higher at the beginning and end of the year. Random subspace is the optimal model for estimating PM2.5 because it has the least statistical error metrics compared to other models. This study suggests ensemble learning models to estimate PM2.5 concentrations. This study will help quantify ground-level PM2.5 concentration exposure and recommend regional government actions to prevent and regulate PM2.5 air pollution. Supplementary Information: The online version contains supplementary material available at 10.1007/s11869-023-01329-w.

Retraction Note: Weather indicators and improving air quality in association with COVID-19 pandemic in India.

[This retracts the article DOI: 10.1007/s00500-021-06012-9.].

Groundwater vulnerability assessment of elevated arsenic in Gangetic plain of West Bengal, India; Using primary information, lithological transport, state-of-the-art approaches.

Deterioration of groundwater quality is a long-term incident which leads unending vulnerability of groundwater. The present work was carried out in Murshidabad District, West Bengal, India to assess groundwater vulnerability due to elevated arsenic (As) and other heavy metal contamination in this area. The geographic distribution of arsenic and other heavy metals including physicochemical parameters of groundwater (in both pre-monsoon and post-monsoon season) and different physical factors were performed. GIS-machine learning model such as support vector machine (SVM), random forest (RF) and support vector regression (SVR) were used for this study. Results revealed that, the concentration of groundwater arsenic compasses from 0.093 to 0.448 mg/L in pre-monsoon and 0.078 to 0.539 mg/L in post-monsoon throughout the district; which indicate that all water samples of the Murshidabad District exceed the WHO's permissible limit (0.01 mg/L). The GIS-machine learning model outcomes states the values of area under the curve (AUC) of SVR, RF and SVM are 0.923, 0.901 and 0.897 (training datasets) and 0.910, 0.899 and 0.891 (validation datasets), respectively. Hence, "support vector regression" model is best fitted to predict the arsenic vulnerable zones of Murshidabad District. Then again, groundwater flow paths and arsenic transport was assessed by three dimensions underlying transport model (MODPATH). The particles discharging trends clearly revealed that the Holocene age aquifers are major contributor of As than Pleistocene age aquifers and this may be the main cause of As vulnerability of both northeast and southwest parts of Murshidabad District. Therefore, special attention should be paid on the predicted vulnerable areas for the safeguard of the public health. Moreover, this study can help to make a proper framework towards sustainable groundwater management.

Personal protective equipment-derived pollution during Covid-19 era: A critical review of ecotoxicology impacts, intervention strategies, and future challenges.

During the COVID-19 pandemic, people used personal protective equipment (PPE) to lessen the spread of the virus. The release of microplastics (MPs) from discarded PPE is a new threat to the long-term health of the environment and poses challenges that are not yet clear. PPE-derived MPs have been found in multi-environmental compartments, e.g., water, sediments, air, and soil across the Bay of Bengal (BoB). As COVID-19 spreads, healthcare facilities use more plastic PPE, polluting aquatic ecosystems. Excessive PPE use releases MPs into the ecosystem, which aquatic organisms ingest, distressing the food chain and possibly causing ongoing health problems in humans. Thus, post-COVID-19 sustainability depends on proper intervention strategies for PPE waste, which have received scholarly interest. Although many studies have investigated PPE-induced MPs pollution in the BoB countries (e.g., India, Bangladesh, Sri Lanka, and Myanmar), the ecotoxicity impacts, intervention strategies, and future challenges of PPE-derived waste have largely gone unnoticed. Our study presents a critical literature review covering the ecotoxicity impacts, intervention strategies, and future challenges across the BoB countries (e.g., India (162,034.45 tons), Bangladesh (67,996 tons), Sri Lanka (35,707.95 tons), and Myanmar (22,593.5 tons). The ecotoxicity impacts of PPE-derived MPs on human health and other environmental compartments are critically addressed. The review's findings infer a gap in the 5R (Reduce, Reuse, Recycle, Redesign, and Restructure) Strategy's implementation in the BoB coastal regions, hindering the achievement of UN SDG-12. Despite widespread research advancements in the BoB, many questions about PPE-derived MPs pollution from the perspective of the COVID-19 era still need to be answered. In response to the post-COVID-19 environmental remediation concerns, this study highlights the present research gaps and suggests new research directions considering the current MPs' research advancements on COVID-related PPE waste. Finally, the review suggests a framework for proper intervention strategies for reducing and monitoring PPE-derived MPs pollution in the BoB countries.

Pollution trends and ecological risks of heavy metal(loid)s in coastal zones of Bangladesh: A chemometric review.

Heavy metal(loid)s inputs contribute to human and environmental stresses in the coastal zones of Bangladesh. Several studies have been conducted on metal(loid)s pollution in sediment, soil, and water in the coastal zones. However, they are sporadic, and no attempt has been made in coastal zones from the standpoint of chemometric review. The current work aims to provide a chemometric assessment of the pollution trend of metal(loid)s, namely arsenic (As), chromium (Cr), cadmium (Cd), lead (Pb), copper (Cu), zinc (Zn), and nickel (Ni) in sediments, soils, and water across the coastal zones from 2015 to 2022. The findings showed that 45.7, 15.2, and 39.1 % of studies on heavy metal(loid)s were concentrated in the eastern, central, and western zones of coastal Bangladesh. The obtained data were further modeled using chemometric approaches, such as the contamination factor, pollution load index, geoaccumulation index, degree of contamination, Nemerow's pollution index, and ecological risk index. The results revealed that metal(loid)s, primarily Cd, have severely polluted the sediments (contamination factor, CF = 5.20) and soils (CF = 9.35) of coastal regions. Water was moderately polluted (Nemerow's pollution index, PN=5.22 ± 6.26) in the coastal area. The eastern zone was the most polluted compared to other zones, except for a few observations in the central zone. The overall ecological risks posed by metal(loid)s highlighted the significant ecological risk in sediments (ecological risk index, RI = 123.50) and soils (RI = 238.93) along the eastern coast. The coastal zone may have higher pollution levels due to the proximity of industrial effluent, residential sewage discharge, agricultural activities, sea transport, metallurgical industries, shipbreaking and recycling operations, and seaport activities, which are the major sources of metal(loid)s. This study will provide useful information to the relevant authorities and serve as the foundation for future management and policy decisions to reduce metal(loid) pollution in the coastal zones of southern Bangladesh.

A critical review and prospect of NO2 and SO2 pollution over Asia: Hotspots, trends, and sources.

Nitrogen dioxide (NO2) and sulfur dioxide (SO2) are two major atmospheric pollutants that significantly threaten human health, the environment, and ecosystems worldwide. Despite this, only some studies have investigated the spatiotemporal hotspots of NO2 and SO2, their trends, production, and sources in Asia. Our study presents a literature review covering the production, trends, and sources of NO2 and SO2 across Asian countries (e.g., Bangladesh, China, India, Iran, Japan, Pakistan, Malaysia, Kuwait, and Nepal). Based on the findings of the review, NO2 and SO2 pollution are increasing due to industrial activity, fossil fuel burning, biomass burning, heavy traffic movement, electricity generation, and power plants. There is significant concern about health risks associated with NO2 and SO2 emissions in Bangladesh, China, India, Malaysia, and Iran, as they pay less attention to managing and controlling pollution. Even though the lack of quality datasets and adequate research in most Asian countries further complicates the management and control of NO2 and SO2 pollution. This study has NO2 and SO2 pollution scenarios, including hotspots, trends, sources, and their influences on Asian countries. This study highlights the existing research gaps and recommends new research on identifying integrated sources, their variations, spatiotemporal trends, emission characteristics, and pollution level. Finally, the present study suggests a framework for controlling and monitoring these two pollutants' emissions.