Green synthesis of nonprecious metal-doped copper hydroxide nanoparticles for construction of a dopamine sensor.

Background: Copper oxide nanoparticles doped with nonprecious metal species (Ni and Mn) were synthesized. Method: A glassy carbon electrode (GCE) was modified by drop-casting of nanostructure suspensions, constructing Ni:Cu(OH)2/GCE, Mn:Cu(OH)2/GCE and Cu(OH)2/GCE. Results: The voltammetric oxidation of dopamine (DA) by the constructed electrodes confirmed that the electrocatalytic oxidation of DA is a reversible, pH-dependent, diffusion-controlled process; the best response was obtained by Mn:Cu(OH)2/GCE. A sensitive calibration graph (0.664 µA/µM) was produced for DA in the concentration range of 0.3-10.0 µM, with a detection limit of 79 nM using Mn:Cu(OH)2/GCE. Conclusion: The Mn:Cu(OH)2/GCE possessed an accurate response toward DA with an acceptable selectivity, stability and antifouling effect, revealing the applicability of the Mn:Cu(OH)2/GCE for DA analysis in biological samples.

Promoting Interfacial Interactions with the Addition of Lignin in Poly(Lactic Acid) Hybrid Nanocomposites.

In this paper, the calorimetric response of the amorphous phase was examined in hybrid nanocomposites which were prepared thanks to a facile synthetic route, by adding reduced graphene oxide (rGO), Cloisite 30B (C30B), or multiwalled carbon nanotubes (MWCNT) to lignin-filled poly(lactic acid) (PLA). The dispersion of both lignin and nanofillers was successful, according to a field-emission scanning-electron microscopy (FESEM) analysis. Lignin alone essentially acted as a crystallization retardant for PLA, and the nanocomposites shared this feature, except when MWCNT was used as nanofiller. All systems exhibiting a curtailed crystallization also showed better thermal stability than neat PLA, as assessed from thermogravimetric measurements. As a consequence of favorable interactions between the PLA matrix, lignin, and the nanofillers, homogeneous dispersion or exfoliation was assumed in amorphous samples from the increase of the cooperative rearranging region (CRR) size, being even more remarkable when increasing the lignin content. The amorphous nanocomposites showed a signature of successful filler inclusion, since no rigid amorphous fraction (RAF) was reported at the filler/matrix interface. Finally, the nanocomposites were crystallized up to their maximum extent from the glassy state in nonisothermal conditions. Despite similar degrees of crystallinity and RAF, significant variations in the CRR size were observed among samples, revealing different levels of mobility constraining in the amorphous phase, probably linked to a filler-dimension dependence of space filling.