Recent advances in heavy metal removal by chitosan based adsorbents.

Chitosan, a low cost polymer, has been used in many studies for adsorption of heavy metal ions. This review covers the performance of all those adsorbents which were derived from chitosan for the adsorption of heavy metal ions in recent past. Further, the common chitosan modifications methods have been discussed in this paper among which crosslinking and grafting were found to be the most popular methods. Adsorption equilibrium and kinetics were also studied and Pseudo-second order kinetic model and Langmuir isotherm were found to be successful for modeling of most of the chitosan derivatives-metal adsorption experiments. Moreover, with focus on chitosan derivatives, effect of adsorbent structure on metal removal, adsorption mechanism, effect of co-existing ions on adsorption, adsorbent synthesis protocols and regeneration methods have been also discussed in great detail. Finally, fixed bed column design for industrial wastewater treatment was elaborated along with efficiency of chitosan based adsorbents in columns.

Polyethersulfone based MMMs with 2D materials and ionic liquid for CO2, N2 and CH4 separation.

Increasing concerns on global warming and climate change have led to numerous attempts on developing new membrane materials to reduce excessive CO2 emission into the atmosphere. In the present work, we focused on the separation of CO2 from gas mixtures through two-dimensional (2D) materials based mixed matrix membranes (MMMs). The ionic liquid (IL) 1-Ethyl-3methylimidazolium bis (trifluoromethylsulfonyl) imide together with different weight fractions (0.5-1.5 wt %) 2D materials, such as molybdenum disulfide (MoS2) and hexagonal boron nitride (h-BN), were homogenously blended to prepare polyether sulfone (PES) MMMs. The main aim was to investigate the effect of the addition of 2D materials on the gas separation/permeation properties of the PES membranes. Pure gas permeation for N2, CO2, and CH4 and binary gas mixtures separation for CO2/N2 and CO2/CH4 were investigated through pure PES and modified PES membranes. The prepared membranes were characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA) and water contact angle tests. The gas permeabilities were found to be improved by average 15-20 times higher compared to pure PES. The [Formula: see text] and [Formula: see text] were improved up to 124% and 18% using PES/h-BN (1 wt %)/IL and PES/MoS2 (1.5 wt %)/IL combination, respectively. In overall, 2D materials and IL together as a filler into PES matrix revealed a significant improvement in the gas separation/permeation properties of PES and can be considered as a competent membrane for CO2/CH4 and CO2/N2 separation.