RESUMEN
Crude oil pipelines are considered as the lifelines of energy industry. However, accidents of the pipelines can lead to severe public health and environmental concerns, in which greenhouse gas (GHG) emissions, primarily methane, are frequently overlooked. While previous studies examined fugitive emissions in normal operation of crude oil pipelines, emissions resulting from accidents were typically managed separately and were therefore not included in the emission account of oil systems. To bridge this knowledge gap, we employed a bottom-up approach to conducted the first-ever inventory of GHG emissions resulting from crude oil pipeline accidents in the United States at the state level from 1968 to 2020, and leveraged Monte Carlo simulation to estimate the associated uncertainties. Our results reveal that GHG emissions from accidents in gathering pipelines (~720,000 tCO2e) exceed those from transmission pipelines (~290,000 tCO2e), although significantly more accidents have occurred in transmission pipelines (6883 cases) than gathering pipelines (773 cases). Texas accounted for over 40% of total accident-related GHG emissions nationwide. Our study contributes to enhanced accuracy of the GHG account associated with crude oil transport and implementing the data-driven climate mitigation strategies.
RESUMEN
Natural gas is believed to be a critical transitional energy source. However, natural gas pipelines, once failed, will contribute to a large amount of greenhouse gas (GHG) emissions, including methane from uncontrolled natural gas venting and carbon dioxide from flared natural gas. However, the GHG emissions caused by pipeline incidents are not included in the regular inventories, making the counted GHG amount deviate from the reality. This study, for the first time, establishes an inventory framework for GHG emissions including all natural gas pipeline incidents in the two of the largest gas producers and consumers in North America (United States and Canada) from 1980s to 2021. The inventory comprises GHG emissions resulting from gathering and transmission pipeline incidents in a total of 24 states or regions in the United States between 1970 and 2021, local distribution pipeline incidents in 22 states or regions between 1970 and 2021, as well as natural gas pipeline incidents in a total of 7 provinces or regions in Canada between 1979 and 2021. These datasets can improve the accuracy of regular emission inventories by covering more emission sources in the United States and Canada and provide essential information for climate-oriented pipeline integrity management.
RESUMEN
Environmentally persistent free radicals (EPFRs) have aroused widespread concern due to their potential adverse health effects. Research on EPFRs in road dust is still very limited. In this study, 86 road dust samples were collected using vacuum sampling in a rapidly developing city in central China. The pollution characterization and health risk of EPFRs in the urban road dust were then systematically analyzed. The results showed the average concentrations of EPFRs in urban road dust and fraction of particle with aerodynamic diameters lower than 10 µm (PM10) were 2.24 × 1017 to 3.72 × 1019 spins·g-1 and 6.02 × 1017 to 1.41 × 1020 spins g-1, respectively. The concentrations of EPFRs in dust from expressways, arterial roads, and secondary trunk roads were significantly higher than those found in the remaining road types. The g-factors of 2.0032-2.0039 indicated that the EPFRs have consisted of oxygen-centered and carbon-centered radicals or carbon-centered radicals with nearby oxygen or halogen atoms. Moreover, three decay patterns of EPFRs were observed: a fast decay followed by a slow decay, a single slow decay, and the slowest decay. In addition, a comparative evaluation was made for probabilistic risk assessments of exposure to the EPFRs in road dust and the PM10 fraction. Compared with road dust, the probability of the number of equivalent cigarettes to exceed the 100 and 200 cigarettes for inhaling EPFRs in the PM10 fraction increased by 27.0% and 25.0%, respectively. The simulation results showed the PM10 fraction were primarily deposited in the upper respiratory tract regions (57.1%) and pulmonary regions (28.8%). The findings of this study suggest a potential risk of EPFRs in inhalable particles and provide a new insight for further exploration of the EPFRs in fine particles of road dust.