1.
J Org Chem
; 71(11): 4305-7, 2006 May 26.
Artículo
en Inglés
| MEDLINE
| ID: mdl-16709076
RESUMEN
A simple and efficient procedure for the synthesis of chiral beta-seleno-amines derivatives from a one-pot indium(I) iodide-mediated aziridine ring opening with diorganoyl diselenides has been developed. As an application, the synthesis of selenocysteine and selenotreonine derivatives has been accomplished.
Asunto(s)
Aminas/síntesis química , Indio/química , Selenocisteína/análogos & derivados , Selenocisteína/síntesis química , Estructura Molecular
2.
Chem Commun (Camb)
; (11): 1258-9, 2003 Jun 07.
Artículo
en Inglés
| MEDLINE
| ID: mdl-12809219
RESUMEN
Metal tellurolates (M = B3+; BuTeTeBu/NaBH4/EtOH; Li3+, Te0/BuLi/THF; In3+, BuTeTeBu/InI/EtOH) react with aminoalkynes to produce vinylic tellurides containing amino groups; the regio-, and stereo-chemistry of the hydrotelluration reaction depend on the metallic counter ion and on the nature of the amino group substituent.
