Mangiferin: A comprehensive review on its extraction, purification and uses in food systems.

With the target of fabricating healthier products, food manufacturing companies look for natural-based nutraceuticals that can potentially improve the physicochemical properties of food systems while being nutritive to the consumer and providing additional health benefits (biological activities). In this regard, Mangiferin joins all these requirements as a potential nutraceutical, which is typically contained in Mangifera indica products and its by-products. Unfortunately, knowing the complex chemical composition of Mango and its by-products, the extraction and purification of Mangiferin remains a challenge. Therefore, this comprehensive review revises the main strategies proposed by scientists for the extraction and purification of Mangiferin. Importantly, this review identifies that there is no report reviewing and criticizing the literature in this field so far. Our attention has been targeted on the timely findings on the primary extraction techniques and the relevant insights into isolation and purification. Our discussion has emphasized the advantages and limitations of the proposed strategies, including solvents, extracting conditions and key interactions with the target xanthone. Additionally, we report the current research gaps in the field after analyzing the literature, as well as some examples of functional food products containing Mangiferin.

Merging Proline:Xylitol Eutectic Solvent in Crosslinked Chitosan Pervaporation Membranes for Enhanced Water Permeation in Dehydrating Ethanol.

The scope of this research aims at merging a new deep eutectic mixture (DES) into a biopolymer-based membrane for a pervaporation application in dehydrating ethanol. Herein, an L-proline:xylitol (at 5:1) eutectic mixture was successfully synthesized and blended with chitosan (CS). A complete characterization of the hybrid membranes, in terms of morphology, solvent uptake, and hydrophilicity, has been conducted. As part of their applicability, the blended membranes were assayed for their ability to separate water from ethanolic solutions by means of pervaporation. At the highest temperature (50 °C), a water permeation of ca. 0.46 kg m-2 h-1 was acquired, representing a higher permeation than the pristine CS membranes (ca. 0.37 kg m-2 h-1). Therefore, CS membranes demonstrated an enhanced water permeation thanks to their blending with the hydrophilic L-proline:xylitol agent, making these membranes a good candidate for other separations containing polar solvents.

A comprehensive review on Ginger (Zingiber officinale) as a potential source of nutraceuticals for food formulations: Towards the polishing of gingerol and other present biomolecules.

Currently, ginger is one the most consumed plants when dealing with the treatments of various illnesses. So far, it is known that various biologically active molecules, such as gingerols, shogaols and zingerone, among others, are the main responsible for specific biological activities, opening a new window for its utilization as a nutraceutical in foods. In pioneering extraction processes, solvent extraction has been initially used for these applications; however, the drawbacks of this typical extraction method compared with other emergent separation techniques make it possible for the exploration of new extraction pathways, including microwave, ultrasound, supercritical, subcritical and pressurized-assisted extraction, along with three phase partitioning, high-speed counter current chromatography and magnetic solid phase extraction. To the best of our knowledge, there is no report documenting the recent studies and cases of study in this field. Therefore, we comprehensively review the progress and the latest findings (over the last five years) on research developments, including patents and emerging extraction methods, aiming at the purification of biologically active molecules (gingerols, shogaols and zingerone) contained in ginger. Over the course of this review, particular emphasis is devoted to breakthrough strategies and meaningful outcomes in ginger components extraction. Finally, dosage and safety concerns related to ginger extracts are also documented.

Ultrasound-assisted heterogeneous activation of persulfate and peroxymonosulfate by asphaltenes for the degradation of BTEX in water.

This study investigated - for the first time - the simultaneous degradation of benzene, toluene, ethylbenzene and o-xylene (BTEX) by persulfate (PS) and peroxymonosulfate (PMS) activated by asphaltenes (Asph) under ultrasound (US) irradiation. Advantageous properties such as high thermal stability, low production cost and extensive availability make asphaltenes as an appealing carbonaceous material for heterogeneous catalysis. The application of asphaltenes in PS/US increased the degradation of BTEXs from 31%, 34%, 35%, 32%-78%, 94%, 98% and 98%, while the removal of these compounds in PMS/US system was improved from 26%, 27%, 24%, 20%-76%, 91%, 97%, 97%, respectively. PS and PMS activation followed a typical sulfate-radical based advanced oxidation processes. In terms of activation of PS and PMS, the particles of asphaltenes intensified formation of reactive radicals by creating additional centers of cavitational events. Moreover, owing to π-π stacking interaction between asphaltenes and sp2-hybridized systems of BTEX, the contaminants undergo adsorption on the surface of asphaltenes and subsequent oxidation by formed radicals. The radical route of BTEX degradation in both PS/US/Asph and PMS/US/Asph systems was mainly contributed by sulfate (SO4•-) and hydroxyl radicals (HO•) and coexisting superoxide radical anions (O2•-) played a minor role.