Production of Modified Composite Nanofiber Yarns with Functional Particles.

The study focused on the production of modified composite nanofiber yarns with fine functional particles. A device that incorporates fine functional particles into a nanofiber yarn wrapper was specially developed, which ensures the continuous production of modified yarn. It was demonstrated during the study that the specially designed equipment could be used effectively for incorporating fine functional particles into the nanofiber packaging, thus creating a unique yarn with high application potential. The use of particles with dimensions of just tens of micrometers results in the uneven flow of particles inside the chamber and the uneven supply of particles to the composite yarn. The study also determined that the number of particles incorporated into the composite yarn is affected by the particle concentration and the variation of the vortex velocity ratios in the chamber. During testing, it was also found that the nanofiber sheet of the composite yarn improves the mechanical properties of the produced yarn. In addition, the study included the semi-industrial production of a composite filter candle, which can be used for the treatment of fluids, especially air and water.

Residual stress determination by the layer removal and X-ray diffraction measurement - correction method.

Very often a manufacturing process is followed by some surface treatment. Such a process induces residual stress into the manufactured component. Compressive residual stress is desirable for enhancing the fatigue properties of the component. The residual stress is often measured only at the surface, if at all. However, residual stress is equilibrating in the whole component. Therefore, compressive residual stress at the surface induces undesirable tensile stress inside in the component. Knowledge of the residual stress distribution in a body can be very useful in engineering applications. The authors found this knowledge necessary for a proper description of fatigue crack propagation in railway axles described in the original paper [1]. With the onset of modern surface treating technologies, e.g. induction hardening, which can affect the entire cross-section of the component, the residual stress determination is even more critical. The presented paper aims to describe a procedure developed for proper residual stress determination. The procedure can be easily used e.g. in R&D centers, where X-ray diffraction residual stress measurement is already in use. The procedure is suitable for the residual stress determination in sizable cylindrical bodies or components, e.g. railway axles. It uses X-ray diffraction residual stress surface measurement and layer removal by machining. Results experimentally obtained are corrected by a general procedure developed in MATLAB software in order to obtain the original residual stress state in the cylindrical body.•More accurate procedure for a residual stress determination in cylindrical bodies.

Optimization of the Spinneret Rotation Speed and Airflow Parameters for the Nozzleless Forcespinning of a Polymer Solution.

This paper addresses the changing of the process parameters of nozzleless centrifugal spinning (forcespinning). The primary aim of this study was to determine the dependence of the final product on the dosing of the polymer, the rotation speed of the spinneret and the airflow in order to determine the extent of the technological applicability of aqueous polyvinyl alcohol (PVA) and its modifications. PVA was chosen because it is a widely used polymeric solution with environmentally friendly properties and good biodegradability. It is used in the health care and food packaging sectors. The nanofibrous layers were produced by means of a mobile handheld spinning device of our own construction. This mobile application of the spinning machine has several limitations compared to stationary laboratory equipment, mainly due to dimensional limitations. The uniqueness of our device lies in the possibility of its actual use outside the laboratory. In addition to improved mobility, another exciting feature is the combination of nozzleless forcespinning and fiber application using airflow. Dosing, the rotation speed of the spinnerets and the targeted and controlled use of air comprise the fundamental technological parameters for many devices that operate on a centrifugal force system. The rotation rate of the spinnerets primarily affects the production of fibers and their quality, while the airflow acts as a fiber transport and drying medium. The quality of the fibers was evaluated following the preparation of a testing set for the fiber layers. The most suitable combinations of rotation speed and airflow were then used in subsequent experiments to determine the ideal settings for the device. The solution was then modified by reducing the concentration to 16% and adding a surfactant, thus leading to a reduction in the diameters of the resulting fibers. The nanofiber layers so produced were examined using a scanning electron microscope (SEM) in order to analyze the number of defects and to statistically evaluate the fiber diameters.

The Optimization of Alternating Current Electrospun PA 6 Solutions Using a Visual Analysis System.

The electrospinning process that produces fine nanofibrous materials have a major disadvantage in the area of productivity. However, alternating current (AC) electrospinning might help to solve the problem via the modification of high voltage signal. The aforementioned productivity aspect can be observed via a camera system that focuses on the jet creation area and that measures the average lifespan. The paper describes the optimization of polyamide 6 (PA 6) solutions and demonstrates the change in the behavior of the process following the addition of a minor dose of oxoacid. This addition served to convert the previously unspinnable (using AC) solution to a high-quality electrospinning solution. The visual analysis of the AC electrospinning of polymeric solutions using a high-speed camera and a programmable power source was chosen as the method for the evaluation of the quality of the process. The solutions were exposed to high voltage applying two types of AC signal, i.e., the sine wave and the step change. All the recordings presented in the paper contained two sets of data: firstly, camera recordings that showed the visual expression of electrospinning and, secondly, signal recordings that provided information on the data position in the signal function.

Effect of Underload Cycles on Oxide-Induced Crack Closure Development in Cr-Mo Low-Alloy Steel.

Underload cycles with small load amplitudes below the fatigue crack growth threshold are dominantly considered as insignificant cycles without any influence on fatigue lifespan of engineering structural components. However, this paper shows that in some cases these underload cycles can retard the consequent crack propagation quite significantly. This phenomenon is a consequence of oxide-induced crack closure development during cyclic loading below the threshold. The experimentally described effect of fatigue crack growth retardation was supported by measurement of the width and the thickness of the oxide debris layer using the EDS technique and localized FIB cuts, respectively. Both the retardation effect and the amount of oxide debris were larger for higher number and larger amplitudes of the applied underload cycles. Crack closure measurement revealed a gradual increase of the closure level during underload cycling. Specimens tested in low air humidity, as well as specimens left with the crack open for the same time as that needed for application of the underload cycles, revealed no retardation effect. The results can improve our understanding of environmental effects on fatigue crack propagation and understanding the differences between the results of laboratory testing and the fatigue lives of components in service.

Effect of Solution Annealing on Fatigue Crack Propagation in the AISI 304L TRIP Steel.

Fatigue crack propagation in near-threshold regime was studied in the 304L austenitic stainless steel in two microstructural states: as-received (AR) with finer microstructure and low susceptibility to the transformation-induced plasticity (TRIP) effect, and solution-annealed (SA) with coarser microstructure and higher susceptibility to TRIP. At the load ratio R = 0.1 the threshold was higher in the SA state than in the AR state due to coarser grains and possibly the TRIP effect. In order to clarify the role of crack closure, experiments at R = 0.7 were done. The threshold in the SA state was still higher by 1 MPa·m0.5. This effect was identified as crack tip shielding induced by phase transformation, an example of a non-closure shielding effect. Higher resistance to crack growth in the SA state was attributed to promoted martensitic transformation in non-favorable oriented grain families rather than thicker martensite layers in the crack path area. The conclusions were verified by experiments at R = 0.7 and temperature 150 °C > Ms which did not reveal any notable difference in thresholds. However, the threshold values were affected by the load-shedding gradient C = -dΔK/da, which had to be equalized in both experimental setups inside and outside the furnace.

Desire for Parenthood and Associated Trends in Czech Lesbian Women.

INTRODUCTION: Worldwide, there are more lesbians who chose to have children in the context of a same-sex relationship than ever before. The Czech studies focusing on this issue, including the analysis of methods of conception, are limited. AIM: We aimed to examine the changes over time in the desire of Czech lesbian women for children and to analyze their chosen methods of conception. METHODS: We analyzed retrospectively the personal history of lesbian patients who visited our clinic in the period from 2009 to 2017. Our sample (n = 318) was divided into 2 groups: Group A - our patients between 2009 and 2013, whereas group B comprised our patients from 2013 to 2017. MAIN OUTCOME MEASURES: The outcome of this study is comparing groups A and B, regarding factors associated to parenthood, such as desire to have a child and preferences in methods of conception. RESULTS: We compared group A and group B and obtained the following results: The percentage of homosexual women who did not desire to have a child decreased (22.5% vs 15.6%). Regarding the changes in the preferences in methods of conception among group A and group B, the findings are as follows: a child from a previous relationship (31.2% vs 27.4%), clinically assisted reproduction with an anonymous donor (19.6% vs 30.1%), home intrauterine insemmination with a known donor (24.6% vs 19.2%), clinically assisted reproduction with a known donor (13.1% vs 9.6%), coitus outside the relationship for the purpose of a child conception (9.8% vs 5.5%), home intrauterine insemmination by sperm from an anonymous donor (1.6% vs 4.1%), assisted reproduction performed abroad was selected only in group B (2.7%). CONCLUSIONS: We confirm that the percentage of Czech lesbians who have a child or want to have a child has increased and that several variables regarding the desire for parenthood in the Czech lesbian community are changing over time (eg, methods of conception) mostly in concordance with other Western European countries. Turcan P, Prochazka M, Prochazka P, et al. Desire for Parenthood and Associated Trends in Czech Lesbian Women. Sex Med 2020;8:650-659.

Influence of coating technology and thermal annealing on the optical performance of AR coatings in iodine-filled absorption cells.

In this contribution, we investigate the properties of antireflective coatings on iodine-filled absorption cell windows. These coatings are subject to high temperatures during the cell production process and are in direct contact with the absorption medium, which influences their optical performance. We tested the thermal resistance of TiO2- and Ta2O5- based coatings produced using conventional electron beam evaporation (e-beam) and ion-assisted deposition (PIAD). We prepared a set of iodine-filled absorption cells that were used to test the coatings' resistance to iodine vapors. We show that the choice of coating materials, coating methods, and a well-chosen bakeout procedure can mitigate any unwanted effects, such as temperature-induced spectral shifts and optical losses inhomogeneities or settling of the absorption medium in the coating.

Fabrication of dual-functional composite yarns with a nanofibrous envelope using high throughput AC needleless and collectorless electrospinning.

Nanotechnologies allow the production of yarns containing nanofibres for use in composites, membranes and biomedical materials. Composite yarns with a conventional thread core for mechanical strength and a nanofibrous envelope for functionality, e.g. biological, catalytic, have many advantages. Until now, the production of such yarns has been technologically difficult. Here, we show an approach to composite yarn production whereby a plume of nanofibers generated by high throughput AC needleless and collectorless electrospinning is wound around a classic thread. In the resulting yarn, nanofibres can form up to 80% of its weight. Our yarn production speed was 10 m/min; testing showed this can be increased to 60 m/min. After the yarn was embedded into knitwear, scanning electron microscope images revealed an intact nanofibrous envelope of the composite yarn. Our results indicate that this production method could lead to the widespread production and use of composite nanofibrous yarns on an industrial scale.

Needleless coaxial electrospinning: A novel approach to mass production of coaxial nanofibers.

Herein, we describe a simple spinneret setup for needleless coaxial electrospinning that exceeds the limited production capacity of current approaches. The proposed weir spinneret enables coaxial electrospinning from free liquid surface. This approach leads to the formation of coaxial nanofibers with higher and uniform shell/core ratio, which results in the possibility of better tuning of the degradation rate. The throughput and quality increase favor the broader application of coaxial nanofibers from weir spinnerets as systems for controlled drug delivery in regenerative medicine and tissue engineering.