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2.
J Hazard Mater ; 136(3): 922-9, 2006 Aug 25.
Artículo en Inglés | MEDLINE | ID: mdl-16510239

RESUMEN

Activated carbon was produced from a biowaste product, rubberwood sawdust (RWSD) using steam in a high temperature fluidized bed reactor. Experiments were carried out to investigate the influence of various process parameters such as activation time, activation temperature, particle size and fluidising velocity on the quality of the activated carbon. The activated carbon was characterized based on its iodine number, methylene blue number, Brauner Emmet Teller (BET) surface area and surface area obtained using the ethylene glycol mono ethyl ether (EGME) retention method. The best quality activated carbon was obtained at an activation time and temperature of 1h and 750 degrees C for an average particle size of 0.46 mm. The adsorption kinetics shows that pseudo-second-order rate fitted the adsorption kinetics better than pseudo-first-order rate equation. The adsorption capacity of carbon produced from RWSD was found to be 1250 mg g(-1) for the Bismark Brown dye. The rate constant and diffusion coefficient for intraparticle transport were determined for steam activated carbon. The characteristic of the prepared activated carbon was found comparable to the commercial activated carbon.


Asunto(s)
Carbono/química , Hevea/química , Adsorción , Algoritmos , Compuestos Azo/química , Colorantes/química , Difusión , Polvo , Indicadores y Reactivos , Residuos Industriales , Cinética , Microscopía Electrónica de Rastreo , Tamaño de la Partícula , Vapor , Temperatura
3.
J Hazard Mater ; 126(1-3): 63-70, 2005 Nov 11.
Artículo en Inglés | MEDLINE | ID: mdl-16040190

RESUMEN

Hevea brasiliensis or rubberwood tree, as it is commonly known finds limited use once the latex has been tapped. The sawdust of this tree is chosen to ascertain it viability as a precursor for activation. The carbons thus obtained were characterized in terms of iodine, methylene blue number and surface area. The best carbon in each method was utilized to study the adsorption of Bismark Brown, a dye used in the leather industry. Adsorption equilibrium studies were carried out with the synthetic solutions of the dye, at room temperature (298 K). Equilibrium data are fitted with the Langmuir and the Freundlich isotherms models for the system. The effects of contact time, adsorbent dosage and initial dye concentrations on sorption capacity were carried out. Excellent adsorption capacities of 2000 and 1111 mg g(-1) were obtained for steam and chemical followed by steam-activated carbons, respectively. Pilot-plant experimental studies have been performed using packed-bed column with different feed concentrations, flow rates and bed heights, to evaluate sorption of Bismark Brown on steam-activated carbon. Bed depth service time (BDST) design model have been used to analyze the data.


Asunto(s)
Compuestos Azo/aislamiento & purificación , Carbón Orgánico/química , Colorantes/aislamiento & purificación , Hevea/química , Residuos Industriales/prevención & control , Contaminantes Químicos del Agua/aislamiento & purificación , Contaminación Química del Agua/prevención & control , Adsorción , Cinética , Modelos Químicos , Concentración Osmolar
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