1.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 9): o1734, 2008 Aug 09.
Artículo
en Inglés
| MEDLINE
| ID: mdl-21201717
RESUMEN
The title mol-ecule, C(14)H(11)BrClNO, adopts a trans configuration with respect to the C=N double bond. The dihedral angle between the two aromatic rings is 70.4â (5)°. An intra-molecular O-Hâ¯N hydrogen bond is observed between the hydroxyl and imine groups.
2.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 1): m202, 2007 Dec 18.
Artículo
en Inglés
| MEDLINE
| ID: mdl-21200550
RESUMEN
In the mononuclear centrosymmetric title compound, [Ni(C(14)H(11)ClNO)(2)], the Ni(II) atom, lying on a center of symmetry, is four-coordinated by two O atoms and two N atoms from two Schiff base ligands, forming a slightly distorted square-planar environment. The dihedral angle between the two aromatic rings of the ligand is 72.0â (2)°. No significant hydrogen bonding or π-π stacking inter-actions are observed.