Quantitative source apportionment of heavy metals in sediments from the Bohai Sea, China.

In this study, the sources of nine heavy metals (Cd, As, Hg, Cu, Pb, Ni, Cr, Zn, and Co) in the sediments of the Bohai Sea were quantitatively identified through a positive factor matrix to provide better advice for marine and coastal management. In Bohai Sea sediments, most metals fell below detectable contamination levels, including As, Cu, Pb, Ni, Cr, Zn, and Co. Unfortunately, Bohai Sea sediments were moderately to significantly enrich with Cd and Hg, posing potentially adverse ecological risks to aquatic ecosystems. Our modeled results showed three factors representing natural, anthropogenic, and atmospheric deposition sources. Enriched Cd and Hg were likely derived from anthropogenic activities through river runoff and atmospheric deposition due to adjacent Zn smelting and chlor-alkali production, respectively. The other metals were mainly derived from natural sources.

Regional background determination and pollution assessment of heavy metals in the semi-closed Bohai Sea sediments.

Background metal concentrations are important in assessing pollution level of marine sediments; however, they can be significantly altered by local depositional environments, resulting in significant errors in regional pollution assessment. This study was based on the investigation of the background levels of heavy metals in the Bohai Sea sediments using sediment core, 2-sigma outlier, and regression methods. We also estimate the ecological risks of heavy metals for surface sediments collected from the Bohai Sea using the three methods mentioned above. Ecological risks of heavy metals calculated using the regression method show wide disparities and significant differences from those calculated using the sediment core and 2-sigma methods, indicating that the regression method is not suitable for the Bohai Sea, likely as a result of its complex sources. Conversely, the estimated ecological risks using the sediment core method are moderate, and most heavy metals, except for Hg and Cd, have negligible contamination.

Enhanced Arctic sea ice melting controlled by larger heat discharge of mid-Holocene rivers.

Arctic sea ice retreat is linked to extrapolar thermal energy import, while the potential impact of pan-Arctic river heat discharge on sea-ice loss has been unresolved. We reconstructed the Holocene history of Arctic sea ice and Russian pan-Arctic river heat discharge, combining ice-rafted debris records and sedimentation rates from the East Siberian Arctic Shelf with a compilation of published paleoclimate and observational data. In the mid-Holocene, the early summer (June-July) solar insolation was higher than that during the late Holocene, which led to a larger heat discharge of the Russian pan-Arctic rivers and contributed to more Arctic sea ice retreat. This intensified decline of early-summer sea ice accelerated the melting of sea ice throughout the summertime by lowering regional albedos. Our findings highlight the important impact of the larger heat discharge of pan-Arctic rivers, which can reinforce Arctic sea-ice loss in the summer in the context of global warming.

Combining GRACE and satellite altimetry data to detect change in sediment load to the Bohai Sea.

The Gravity Recovery and Climate Experiment (GRACE) satellites provide a powerful tool for monitoring sediment mass change. However, signal leakage from nearby groundwater storage depletion in the North China Plain limits the potential capacity of GRACE to estimate sediment input from the Yellow River flows into the Bohai Sea. In the present work, we developed an improved approach based on forward modeling to reduce signal leakage from GRACE data and combined it with satellite altimetry to recover sediment load changes from 2003 to 2013 to the Bohai Sea. The total sediment input averaged 1.7 ± 0.8 Gt/yr, which agrees well with the estimate based on in-situ sediment data measured from the sediment cores (1.1 Gt/yr). Our method is also capable to describe sediment seasonal variations, with higher inputs in winter and spring, which confirm the output simulated by the sediment transportation model. We make presently tentative connections of seasonal variations to sediment resuspension driven by climatic monsoons contributed rough seas: although sediment load in rivers peaks in summer, low water discharge of the Yellow River leads to most of the sediment being deposited in a narrow area near the river mouth and not transported into the Bohai Sea; in winter and spring, huge waves provide favorable conditions for resuspension resulting in large amounts of sediment near the estuary being transported to the ocean along with northward waves. Moreover, our results indicate coastal erosion is also a nonnegligible resource of the sediment in the Bohai Sea. Comparing to the traditional approach, our study provides a new technological way to derive sediment in the Bohai Sea, which is capable of providing continuous measurements with improved timeliness at a lower cost.

Lead isotopes in the Central Yellow Sea Mud: Evidence of atmospheric deposition and its implication for regional energy consumption shift.

Anthropogenic activities have increased lead (Pb) emissions and impacted their spatiotemporal distributions in coastal seas. To quantify the increasing variability of Pb and identify the specific origins and their corresponding magnitudes, Pb and Pb isotopes are investigated in a well-placed sediment core covering the period of 1928-2008 in the Central Yellow Sea Mud (CYSM). The concentration of Pb varied from 27.17 µg/g to 37.30 µg/g upwardly along the core, with pronounced anthropogenic disturbance since the late 1960s. The Pb input history of the CYSM experienced five stages according to industrialization levels and Pb contamination, with relative pristine stages from 1928 to 1969 and human activity-impacted stages from 1969 to 2008. The 206Pb/207Pb ratio demonstrated an overall decreasing profile while the 208Pb/206Pb ratio displayed the reverse trend upwardly along the core, possibly due to the atmospheric delivery of anthropogenic Pb emissions from northern China. Furthermore, 208Pb/206Pb vs. 206Pb/207Pb shows certain linearity between natural sediment sources and anthropogenic emissions of Pb (atmospheric deposition); thus, atmospheric inputs account for 34-43% of the Pb in the sediment since Pb enrichment using the two-endmember mixing model. Moreover, the steep decrease in 206Pb/207Pb and rapid increase in 208Pb/206Pb since the 1970s suggest the introduction of leaded gasoline and the increasing proportionate consumption of gasoline relative to total energy consumption. The continuously decreasing 206Pb/207Pb ratio and increasing 208Pb/206Pb ratio since 2000 are the combined results of coal consumption, nonferrous smelting, and residual Pb contamination from leaded gasoline, which is quite distinctive from cases in North America and Europe. The relatively high 206Pb/207Pb and low 208Pb/206Pb ratios before 1969 represent the natural Pb isotopic signatures. Hence, Pb input is significantly affected by regional energy consumption and restructuring, and the Pb isotopic ratios may be a potential proxy for the shift in energy consumption.

Occurrence and distribution of microplastics in surface sediments from the Gulf of Thailand.

This study investigated the distribution and characteristics of microplastics in surface sediments of the Gulf of Thailand (GoT), and discussed the correlation between sediment grain size and microplastic content. The results indicate the abundance of microplastics is 150.4 ± 86.2 pieces/kg dry weight, representing a medium microplastic pollution level compared to other sea areas. Small microplastics (0.5-1 mm) take up >70% of total microplastic numbers. Fibrous microplastics are the dominant component of microplastics. According to micro-Fourier transform infrared spectroscopy, rayon (37%) and polyester (PES: 16%) are the most typical polymer types found in sediments. The results imply that secondary microplastics are the dominant pollutant, while fibrous microplastics are mainly from municipal sewage discharge. We also find that inconspicuous correlation between grain size and microplastics, which is caused by the multi-sources and different flow field. This study deepens our understanding of the environmental risks posed by microplastics to marine ecosystems in the GoT.

Distribution and assessment of heavy metals in surface sediments from the Bohai Sea of China.

In this study, we analyzed heavy metals in 404 surface sediment samples from the Bohai Sea to measure contamination status and distribution. We found Zn levels to be the highest, whereas Hg concentrations were the lowest of measured heavy metals. We found that the samples containing the most heavy metals were those collected from Fuzhou Bay, Jinzhou Bay, central Bohai Sea mud area, and the Yellow River Delta. Further analyses suggest that these heavy metals in surface sediments in the Jinzhou Bay and Fuzhou Bay pose a serious ecological risk, with substantial Cd and Hg accumulation in the Jinzhou Bay and Yellow River Delta regions being indicative of intense human activities.

Persistent effects of the Yellow River on the Chinese marginal seas began at least ~880 ka ago.

The Yellow River (or Huanghe and also known as China's Sorrow in ancient times), with the highest sediment load in the world, provides a key link between continental erosion and sediment accumulation in the western Pacific Ocean. However, the exact age of its influence on the marginal sea is highly controversial and uncertain. Here we present high-resolution records of clay minerals and lanthanum to samarium (La/Sm) ratio spanning the past ~1 million years (Myr) from the Bohai and Yellow Seas, the potential sedimentary sinks of the Yellow River. Our results show a climate-driven provenance shift from small, proximal mountain rivers-dominance to the Yellow River-dominance at ~880 ka, a time period consistent with the Mid-Pleistocene orbital shift from 41-kyr to 100-kyr cyclicity. We compare the age of this provenance shift with the available age data for Yellow River headwater integration into the marginal seas and suggest that the persistent influence of the Yellow River on the Chinese marginal seas must have occurred at least ~880 ka ago. To our knowledge, this study provides the first offshore evidence on the drainage history of the Yellow River within an accurate chronology framework.

Sources and mass inventory of sedimentary polycyclic aromatic hydrocarbons in the Gulf of Thailand: Implications for pathways and energy structure in SE Asia.

Surface sediments obtained from a matrix of 92 sample sites in the Gulf of Thailand (GOT) were analyzed for a comprehensive study of the distribution, sources, and mass inventory of polycyclic aromatic hydrocarbons (PAHs) to assess their input pathways and impacts of the regional land-based energy structure on the deposition of PAHs on the adjacent continental margins. The concentration of 16 PAHs in the GOT ranged from 2.6 to 78.1ng/g (dry weight), and the mean concentration was 19.4±15.1ng/g. The spatial distribution pattern of 16 PAH was generally consistent with that of sediment grain size, suggesting the influence of regional hydrodynamic conditions. Correlation and principal component analysis of the PAHs indicated that direct land-based inputs were dominantly responsible for the occurrence of PAHs in the upper GOT and the low molecular weight (LMW) PAHs in the coastal region could be from petrogenic sources. A positive matrix factorization (PMF) model apportioned five contributors: petroleum residues (~44%), biomass burning (~13%), vehicular emissions (~11%), coal combustion (~6%), and air-water exchange (~25%). Gas absorption may be a significant external input pathway for the volatile PAHs in the open GOT, which further implies that atmospheric loading could be important for the sink of PAHs in the open sea of the Southeast Asia (SE Asia). The different PAH source patterns obtained and a significant disparity of PAH mass inventory in the sediments along the East and Southeast Asia continental margins can be ascribed mainly to different land-based PAH emission features under the varied regional energy structure in addition to the depositional environment and climatic conditions.