Research on mix design and mechanical performances of MK-GGBFS based geopolymer pastes using central composite design method.

In order to alleviate environmental problems and reduce CO2 emissions, geopolymers had drew attention as a kind of alkali-activated materials. Geopolymers are easier access to raw materials, green and environment friendly than traditional cement industry. Its special reaction mechanism and gel structure show excellent characteristics such as quick hardening, high strength, acid and alkali resistance. In this paper, geopolymer pastes were made with metakaolin (MK) and ground granulated blast furnace slag (GGBFS) as precursors. The effects of liquid-solid ratio (L/S) and modulus of sodium silicate (Ms) on the performances of MK-GGBFS based geopolymer paste (MSGP) were characterized by workability, strength and microstructural tests. The regression equations were obtained by central composite design method to optimize the mix design of MSGP. The goodness of fit of all the equations were more than 98%. Based on the results of experiments, the optimum mix design was found to have L/S of 0.75 and Ms of 1.55. The workability of MSGP was significantly improved while maintaining the strength under the optimum mix design. The initial setting time of MSGP decreased by 71.8%, while both of the fluidity and 28-d compressive strength increased by 15.3%, compared with ordinary Portland cement pastes. Therefore, geopolymers are promising alternative cementitious material, which can consume a large amount of MK and GGBFS and promote green and clean production.

One-Part Alkali-Activated Materials: State of the Art and Perspectives.

Alkali-activated materials (AAM) are recognized as potential alternatives to ordinary Portland cement (OPC) to limit CO2 emissions and beneficiate several wastes into useful products. Compared with its counterparts involving the concentrated aqueous alkali solutions, the development of "just add water" one-part alkali-activated materials (OP-AAM) has drawn much attention, mainly attributed to their benefits in overcoming the hazardous, irritating, and corrosive nature of activator solutions. This study starts with a comprehensive overview of the OP-AAM; 89 published studies reported on mortar or concrete with OP-AAM were collected and concluded in this paper. Comprehensive comparisons and discussions were conducted on raw materials, preparation, working performance, mechanical properties, and durability, and so on. Moreover, an in-depth comparison of different material pretreatment methods, fiber types, and curing methods was presented, and their potential mechanisms were discussed. It is found that ground granulated blast-furnace slag (GGBS) provides the best mechanical properties, and the reuse of most aluminosilicate materials can improve the utilization efficiency of solid waste. The curing temperature can be improved significantly for precursor materials with low calcium contents. In order to overcome the brittleness of the AAM, fiber reinforcement might be an efficient way, and steel fiber has the best chemical stability. It is not recommended to use synthetic fiber with poor chemical stability. Based on the analysis of current limitations, both the recommendations and perspectives are laid down to be the lighthouse for further research.

Mechanical properties and acoustic emission analysis of desert sand concrete reinforced with steel fiber.

In this study, to reduce the consumption of natural sand and improve the utilization rate of desert sand in western China, while preparing 14 groups of samples, desert sand is used to replace natural sand by the ratio of 20%, 40%, and 60%, and steel fiber is mixed with volume fraction 0.5%, 1.0%, 1.5%, and 2.0%. The mechanical properties of the specimens, including compressive strength, splitting tensile strength, and axial compressive strength were tested. Besides, the microstructures of the samples were analyzed by SEM, XRD, and acoustic emission detection technologies to identify the damage process. The results show that the desert sand can refine the microstructure and fill the pores, and it has good comprehensive properties at a 40% substitution rate. The compression properties of specimens are not apparently improved, but the tensile strength and deformation properties are significantly improved. The steel fiber with 1.5 vol% content behaves better, and the 28d compressive strength of the optimized group reaches 58.7 MPa. As a result, the polynomial fitting degree of total AE hits and stress level receives a more incredible goodness (R2) value than 0.96. The strength characteristics of steel fiber-desert sand concrete (SFDSC) can meet the demands of C40 concrete, and this research can provide a reference for engineers using desert sand in their designs.