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1.
Opt Express ; 24(5): 5039-5044, 2016 Mar 07.
Artículo en Inglés | MEDLINE | ID: mdl-29092332

RESUMEN

We report few-cycle THz pulses emission from a novel organic crystal 2,6-diaminopyridinium-4-nitrophenolate-4-nitrophenol (DAP+NP-NP). The observed amplitude of the THz electric field from a DAP+NP-NP crystal is comparable with that from a ZnTe single crystal under the same optical pumping conditions. Both the waveform and spectra of the THz radiation from DAP+NP-NP are similar to those from ZnTe. We conclude that a high quality DAP+NP-NP crystal would be a high potential candidate in THz generation and applications.

2.
Spectrochim Acta A Mol Biomol Spectrosc ; 71(2): 480-5, 2008 Nov 15.
Artículo en Inglés | MEDLINE | ID: mdl-18339577

RESUMEN

Good quality single crystals of thiourea-doped triglycinesulphate (TuTGS) a new semiorganic nonlinear optical (NLO) crystal has been successfully grown from aqueous solution by slow evaporation method. The solubilities under various solvents in different proportions have been studied. The structural characterization of the grown crystals was carried out by X-ray diffraction. The grown crystals were subjected to FTIR and Raman analyses for vibrational assignments. The optical absorption coefficient alpha was analysed and interpreted to be allowed in the direct transition. The values of allowed direct energy gap (Eg) for undoped and doped crystals were calculated. It was found that Eg values were decreased with organic molecule doping. The powder technique of Kurtz and Perry confirm the NLO property of the grown crystal.


Asunto(s)
Glicina/química , Cristalización , Ligandos , Solubilidad , Espectroscopía Infrarroja por Transformada de Fourier , Espectrometría Raman , Difracción de Rayos X
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