Weakened AMOC related to cooling and atmospheric circulation shifts in the last interglacial Eastern Mediterranean.

There is limited understanding of temperature and atmospheric circulation changes that accompany an Atlantic Meridional Overturning Circulation (AMOC) slowdown beyond the North Atlantic realm. A Peqi'in Cave (Israel) speleothem dated to the last interglacial period (LIG), 129-116 thousand years ago (ka), together with a large modern rainfall monitoring dataset, serve as the base for investigating past AMOC slowdown effects on the Eastern Mediterranean. Here, we reconstruct LIG temperatures and rainfall source using organic proxies (TEX86) and fluid inclusion water d-excess. The TEX86 data show a stepwise cooling from 19.8 ± 0.2° (ca. 128-126 ka) to 16.5 ± 0.6 °C (ca. 124-123 ka), while d-excess values decrease abruptly (ca. 126 ka). The d-excess shift suggests that rainfall was derived from more zonal Mediterranean air flow during the weakened AMOC interval. Decreasing rainfall d-excess trends over the last 25 years raise the question whether similar atmospheric circulation changes are also occurring today.

Long-range transported North American wildfire aerosols observed in marine boundary layer of eastern North Atlantic.

Wildfire is a major source of biomass burning aerosols, which greatly impact Earth climate. Tree species in North America (NA) boreal forests can support high-intensity crown fires, resulting in elevated injection height and longer lifetime (on the order of months) of the wildfire aerosols. Given the long lifetime, the properties of aged NA wildfire aerosols are required to understand and quantify their effects on radiation and climate. Here we present comprehensive characterization of climatically relevant properties, including optical properties and cloud condensation nuclei (CCN) activities of aged NA wildfire aerosols, emitted from the record-breaking Canadian wildfires in August 2017. Despite the extreme injection height of ~12 km, some of the wildfire plumes descended into the marine boundary layer in the eastern North Atlantic over a period of ~2 weeks, owing to the dry intrusions behind mid-latitude cyclones. The aged wildfire aerosols have high single scattering albedos at 529 nm (ω529; 0.92-0.95) while low absorption Ångström exponents (Åabs) at 464 nm/648 nm (0.7-0.9). In comparison, Åabs of fresh/slightly aged ones are typically 1.4-3.5. This low Åabs indicates a nearly complete loss of brown carbon, likely due to bleaching and/or evaporation, during the long-range transport. The nearly complete loss suggests that on global average, direct radiative forcing of BrC may be minor. Combining Mie calculations and the measured aerosol hygroscopicity, volatility and size distributions, we show that the high ω529 and low Åabs values are best explained by an external mixture of non-absorbing organic particles and absorbing particles of large BC cores (>~110 nm diameter) with thick non-absorbing coatings. The accelerated descent of the wildfire plume also led to strong increase of CCN concentration at the supersaturation levels representative of marine low clouds. The hygroscopicity parameter, κCCN, of the aged wildfire aerosols varies from 0.2 to 0.4, substantially lower than that of background marine boundary layer aerosols. However, the high fraction of particles with large diameter (i.e., within accumulation size ranges, ~100-250 nm) compensates for the low values of κ, and as a result, the aged NA wildfire aerosols contribute more efficiently to CCN population. These results provide direct evidence that the long-range transported NA wildfires can strongly influence CCN concentration in remote marine boundary layer, therefore the radiative properties of marine low clouds. Given the expected increases of NA wildfire intensity and frequency and regular occurrence of dry intrusion following mid-latitude cyclones, the influence of NA wildfire aerosols on CCN and clouds in remote marine environment need to be further examined.

Climatology and dynamics of the link between dry intrusions and cold fronts during winter. Part I: global climatology.

Cold fronts are a primary feature of the day-to-day variability of weather in the midlatitudes, and feature in conceptual extratropical cyclone models alongside the dry intrusion airstream. Here the climatological frequency and spatial distribution of the co-occurrence of these two features are quantified, and the differences in cold front characteristics (intensity, size, and precipitation) when a dry intrusion is present or not are calculated. Fronts are objectively identified in the ECMWF ERA-Interim dataset for the winter seasons in each hemisphere and split into three sub-types: central fronts (within a cyclone area); trailing fronts (outwith the cyclone area but connected to a central front); and isolated fronts (not connected to a cyclone). These are then associated with dry intrusions identified using Lagrangian trajectory analysis. Trailing fronts are most likely to be associated with a DI in both hemispheres, and this occurs more frequently in the western parts of the major storm track regions. Isolated fronts are linked to DIs more frequently on the eastern ends of the storm tracks, and in the subtropics. All front types, when co-occurring with a DI, are stronger in terms of their temperature gradient, are much larger in area, and typically have higher average precipitation. Therefore, climatologically the link with DIs increases the impact of cold fronts. There are some differences in the statistics of the precipitation for trailing and isolated fronts that are further investigated in Part II of this study from the front-centred perspective.

Climatology and dynamics of the link between dry intrusions and cold fronts during winter, Part II: Front-centred perspective.

The conceptual picture of an extratropical cyclone typically includes a cold front and a dry intrusion (DI) behind it. By objectively identifying fronts and DIs in ECMWF ERA-Interim data for 1979-2014, Part I quantified the climatological relationship between cold fronts and DIs. Driven by the finding that front intensity and frontal precipitation are enhanced in the presence of DIs, here we employ a front-centred perspective to focus on the dynamical and thermodynamical environment of cold fronts with and without DIs in the Northern Hemisphere winter. Distinguishing between trailing fronts (that connect to a parent cyclone) and isolated fronts, examples of DIs behind each type illustrate the baroclinic environment of the trailing front, and the lack of strong temperature gradients across the isolated front. Composite analyses of North Atlantic and North Pacific fronts outline the major differences in the presence of DIs, compared to similar fronts but without DIs in their vicinity. The magnitude and spatial structure of the modification by DIs depends on the front intensity. Yet, generally with DIs, trailing fronts occur with stronger SLP dipole, deeper upper-tropospheric trough, stronger 10-m wind gusts, enhanced ocean sensible and latent heat fluxes in the cyclone cold sector and heavier precipitation. Isolated weak fronts exhibit similar behaviour, with different spatial structure. This study highlights the central role of DIs for shaping the variability of fronts and their associated environment and impact.

Investigation of ozone deposition to vegetation under warm and dry conditions near the Eastern Mediterranean coast.

Dry deposition of ozone (O3) to vegetation is an important removal pathway for tropospheric O3, while O3 uptake through plant stomata negatively affects vegetation and leads to climate change. Both processes are controlled by vegetation characteristics and ambient conditions via complex mechanisms. Recent studies have revealed that these processes can be fundamentally impacted by coastal effects, and by dry and warm conditions in ways that have not been fully characterized, largely due to lack of measurements under such conditions. Hence, we hypothesized that measuring dry deposition of O3 to vegetation along a sharp spatial climate gradient, and at different distances from the coast, can offer new insights into the characterization of these effects on O3 deposition to vegetation and stomatal uptake, providing important information for afforestation management and for climate and air-quality model improvement. To address these hypotheses, several measurement campaigns were performed at different sites, including pine, oak, and mixed Mediterranean forests, at distances of 20-59 km from the Eastern Mediterranean coast, under semiarid, Mediterranean and humid Mediterranean climate conditions. The eddy covariance technique was used to quantify vertical O3 flux (Ftot) and its partitioning to stomatal flux (Fst) and non-stomatal flux (Fns). Whereas Fst tended to peak around noon under humid Mediterranean and Mediterranean conditions in summer, it was strongly limited by drought under semiarid conditions from spring to early winter, with minimum average Fst/Ftot of 8-11% during the summer. Fns in the area was predominantly controlled by relative humidity (RH), whereas increasing Fns with RH for RH < 70% indicated enhancement of Fns by aerosols, via surface wetness stimulation. At night, efficient turbulence due to sea and land breezes, together with increased RH, resulted in strong enhancement of Ftot. Extreme dry surface events, some induced by dry intrusion from the upper troposphere, resulted in positive Fns events.