Magneto-optical Kerr Effect in Ferroelectric Antiferromagnetic Two-Dimensional Heterostructures.

We studied the magneto-optical Kerr effect (MOKE) of two-dimensional (2D) heterostructure CrI3/In2Se3/CrI3 using density functional theory calculations and symmetry analysis. The spontaneous polarization in the In2Se3 ferroelectric layer and the antiferromagnetic ordering in CrI3 layers break the mirror and the time-reversal symmetry, thus activating MOKE. We show that the Kerr angle can be reversed by either the polarization or the antiferromagnetic order parameter. Our results suggest that ferroelectric and antiferromagnetic 2D heterostructures could be exploited for ultracompact information storage devices, where the information is encoded by the two ferroelectric or the two time-reversed antiferromagnetic states and the read-out is performed optically by MOKE.

NiSe and CoSe Topological Nodal-Line Semimetals: A Sustainable Platform for Efficient Thermoplasmonics and Solar-Driven Photothermal Membrane Distillation.

The control of heat at the nanoscale via the excitation of localized surface plasmons in nanoparticles (NPs) irradiated with light holds great potential in several fields (cancer therapy, catalysis, desalination). To date, most thermoplasmonic applications are based on Ag and Au NPs, whose cost of raw materials inevitably limits the scalability for industrial applications requiring large amounts of photothermal NPs, as in the case of desalination plants. On the other hand, alternative nanomaterials proposed so far exhibit severe restrictions associated with the insufficient photothermal efficacy in the visible, the poor chemical stability, and the challenging scalability. Here, it is demonstrated the outstanding potential of NiSe and CoSe topological nodal-line semimetals for thermoplasmonics. The anisotropic dielectric properties of NiSe and CoSe activate additional plasmonic resonances. Specifically, NiSe and CoSe NPs support multiple localized surface plasmons in the optical range, resulting in a broadband matching with sunlight radiation spectrum. Finally, it is validated the proposed NiSe and CoSe-based thermoplasmonic platform by implementing solar-driven membrane distillation by adopting NiSe and CoSe nanofillers embedded in a polymeric membrane for seawater desalination. Remarkably, replacing Ag with NiSe and CoSe for solar membrane distillation increases the transmembrane flux by 330% and 690%, respectively. Correspondingly, costs of raw materials are also reduced by 24 and 11 times, respectively. The results pave the way for the advent of NiSe and CoSe for efficient and sustainable thermoplasmonics and related applications exploiting sunlight within the paradigm of the circular blue economy.

Short-Pulsed Metamaterials.

We study a class of temporal metamaterials characterized by time-varying dielectric permittivity waveforms of duration much smaller than the characteristic wave-dynamical timescale. In the analogy between spatial and temporal metamaterials, such a short-pulsed regime can be viewed as the temporal counterpart of metasurfaces. We introduce a general and compact analytical formalism for modeling the interaction of a short-pulsed metamaterial with an electromagnetic wave packet. Specifically, we elucidate the role of local and nonlocal effects, as well as the time-reversal symmetry breaking, and we show how they can be harnessed to perform elementary analog computing, such as first and second derivatives. Our theory validated against full-wave numerical simulations suggests a novel route for manipulating electromagnetic waves without relying on long, periodic temporal modulations. Just as metasurfaces have played a pivotal role in the technological viability and practical applicability of conventional (spatial) metamaterials, short-pulsed metamaterials may catalyze the development of temporal and space-time metamaterials.

Closing the THz gap with Dirac semimetals.

High-performance THz photodetection is unprecedentedly accessed by integrating a topological Dirac (Weyl) semimetal in a carefully designed antenna at deep-subwavelength scales.

Phase-matching-free parametric oscillators based on two-dimensional semiconductors.

Optical parametric oscillators are widely used as pulsed and continuous-wave tunable sources for innumerable applications, such as quantum technologies, imaging, and biophysics. A key drawback is material dispersion, which imposes a phase-matching condition that generally entails a complex design and setup, thus hindering tunability and miniaturization. Here we show that the burden of phase-matching is surprisingly absent in parametric micro-resonators utilizing mono-layer transition-metal dichalcogenides as quadratic nonlinear materials. By the exact solution of nonlinear Maxwell equations and first-principle calculations of the semiconductor nonlinear response, we devise a novel kind of phase-matching-free miniaturized parametric oscillator operating at conventional pump intensities. We find that different two-dimensional semiconductors yield degenerate and non-degenerate emission at various spectral regions due to doubly resonant mode excitation, which can be tuned by varying the incidence angle of the external pump laser. In addition, we show that high-frequency electrical modulation can be achieved by doping via electrical gating, which can be used to efficiently shift the threshold for parametric oscillation. Our results pave the way for the realization of novel ultra-fast tunable micron-sized sources of entangled photons-a key device underpinning any quantum protocol. Highly miniaturized optical parametric oscillators may also be employed in lab-on-chip technologies for biophysics, detection of environmental pollution and security.

Efficient Vortex Generation in Subwavelength Epsilon-Near-Zero Slabs.

We show that a homogeneous and isotropic slab, illuminated by a circularly polarized beam with no topological charge, produces vortices of order 2 in the opposite circularly polarized components of the reflected and transmitted fields, as a consequence of the transverse magnetic and transverse electric asymmetric response of the rotationally invariant system. In addition, in the epsilon-near-zero regime, we find that vortex generation is remarkably efficient in subwavelength thick slabs up to the paraxial regime. This physically stems from the fact that a vacuum paraxial field can excite a nonparaxial field inside an epsilon-near-zero slab since it hosts slowly varying fields over physically large portions of the bulk. Our theoretical predictions indicate that epsilon-near-zero media hold great potential as nanophotonic elements for manipulating the angular momentum of the radiation, since they are available without resorting to complicated micro- or nanofabrication processes and can operate even at very small (ultraviolet) wavelengths.

All-optical modulation in wavelength-sized epsilon-near-zero media.

We investigate the interaction of two pulses (pump and probe) scattered by a nonlinear epsilon-near-zero (ENZ) slab whose thickness is comparable with the ENZ wavelength. We show that when the probe has a narrow spectrum localized around the ENZ wavelength, its transmission is dramatically affected by the intensity of the pump. Conversely, if the probe is not in the ENZ regime, its propagation is not noticeably affected by the pump. Such all-optical modulation is due to the oversensitive character of the ENZ regime, and it is so efficient that it even occurs in a wavelength thick slab.

Photo-generated metamaterials induce modulation of CW terahertz quantum cascade lasers.

Periodic patterns of photo-excited carriers on a semiconductor surface profoundly modifies its effective permittivity, creating a stationary all-optical quasi-metallic metamaterial. Intriguingly, one can tailor its artificial birefringence to modulate with unprecedented degrees of freedom both the amplitude and phase of a quantum cascade laser (QCL) subject to optical feedback from such an anisotropic reflector. Here, we conceive and devise a reconfigurable photo-designed Terahertz (THz) modulator and exploit it in a proof-of-concept experiment to control the emission properties of THz QCLs. Photo-exciting sub-wavelength metastructures on silicon, we induce polarization-dependent changes in the intra-cavity THz field, that can be probed by monitoring the voltage across the QCL terminals. This inherently flexible approach promises groundbreaking impact on THz photonics applications, including THz phase modulators, fast switches, and active hyperbolic media.

One-Dimensional Chirality: Strong Optical Activity in Epsilon-Near-Zero Metamaterials.

We suggest that electromagnetic chirality, generally displayed by 3D or 2D complex chiral structures, can occur in 1D patterned composites whose components are achiral. This feature is highly unexpected in a 1D system which is geometrically achiral since its mirror image can always be superposed onto it by a 180 deg rotation. We analytically evaluate from first principles the bianisotropic response of multilayered metamaterials and we show that the chiral tensor is not vanishing if the system is geometrically one-dimensional chiral; i.e., its mirror image cannot be superposed onto it by using translations without resorting to rotations. As a signature of 1D chirality, we show that 1D chiral metamaterials support optical activity and we prove that this phenomenon undergoes a dramatic nonresonant enhancement in the epsilon-near-zero regime where the magnetoelectric coupling can become dominant in the constitutive relations.

Kapitza homogenization of deep gratings for designing dielectric metamaterials.

We theoretically investigate the homogenization of the dielectric response to transverse electric waves of a transverse grating characterized by the Kapitza condition; i.e., the permittivity is rapidly modulated with a modulation depth scaling as the large wavelength-to-modulation-period ratio. We show that the resulting effective dielectric permittivity, in addition to the standard average of the underlying dielectric profile, has a further contribution arising from the fast and deep dielectric modulation. Such a contribution turns out to be comparable with the other one and hence can provide an additional method for designing dielectric metamaterials. As an example, we discuss an effective metal-to-dielectric transition produced by the Kapitza contribution obtained by changing the grating depth, a remarkable result for applications involving epsilon-near-zero metamaterial design.

Terahertz optically tunable dielectric metamaterials without microfabrication.

We theoretically investigate the terahertz (THz) dielectric response of a semiconductor slab hosting a tunable grating photogenerated by the interference of two tilted infrared (IR) plane waves. In the case where the grating period is much smaller than the THz wavelength, we numerically evaluate the ordinary and extraordinary component of the effective permittivity tensor by resorting to electromagnetic full-wave simulation coupled to the dynamics of charge carriers excited by IR radiation. We show that the photo-induced metamaterial optical response can be tailored by varying the grating and it ranges from birefringent to hyperbolic to anisotropic negative dielectric without resorting to microfabrication.

Effective medium theory for Kapitza stratified media: diffractionless propagation.

We show that in the presence of a rapidly modulated dielectric permittivity with a large modulation depth (Kapitza medium) a novel and robust regime of diffractionless electromagnetic propagation occurs. This happens when the mean value to depth ratio of the dielectric profile is comparable to the small ratio between the modulation period and the wavelength. We show that the standard effective medium theory is inadequate to describe the proposed regime and that its occurrence is not substantially hampered by medium losses. We check the feasibility of the proposed regime by means of a large modulation depth metal-dielectric layered medium whose electromagnetic behavior is analytically investigated.

Controlling cavity solitons by means of photorefractive soliton electro-activation.

We consider a hybrid system consisting of a centrosymmetric photorefractive crystal in contact with a vertical-cavity surface-emitting laser. We numerically investigate the generation and control of cavity solitons (CSs) by propagating a plane wave through electro-activated solitonic waveguides in the crystal. In such a compound scheme, which couples a propagative/conservative field dynamics to a bistable/dissipative one, we show that by changing the electro-activation voltage of the crystal, the CSs can be turned on and shifted with controlled velocity across the device section, on the scale of tens of nanoseconds. The configuration can be exploited for applications to optical information encoding and processing.

Terahertz active spatial filtering through optically tunable hyperbolic metamaterials.

We theoretically consider infrared-driven hyperbolic metamaterials able to spatially filter terahertz (THz) radiation. The metamaterial is a slab made of alternating semiconductor and dielectric layers whose homogenized uniaxial response, at THz frequencies, shows principal permittivities of different signs. The gap provided by metamaterial hyperbolic dispersion allows the slab to stop spatial frequencies within a bandwidth tunable by changing the infrared radiation intensity. We numerically prove the device functionality by resorting to full wave simulation coupled to the dynamics of charge carries photoexcited by infrared radiation in semiconductor layers.

Miniaturized bending-free solitons by restoring symmetry in periodically biased photorefractives.

We consider optical propagation through a centrosymmetric photorefractive crystal with the externally applied bias voltage modulated along the optical propagation direction. We analytically prove that, if the modulation scale is smaller than the optical diffraction length, the resulting effective nonlinearity has an even parity in the transverse plane for an even-symmetric intensity profile and supports bending-free solitons down to few-micrometer beam widths. Numerical integration of the full photorefractive model for light-matter interaction allows us to confirm the feasibility of these miniaturized solitons and, for longer modulation periods, to investigate the excitation of self-trapped wiggling optical beams.

Transverse and soliton instabilities due to counterpropagation through a reflection grating in Kerr media.

Transverse instabilities are shown to accompany counterpropagation of optical beams through reflection gratings in Kerr media. The instability threshold of continuous waves is analytically derived, and it is shown that the presence of the grating broadens and narrows the stability region of plane waves in focusing and defocusing media, respectively. Furthermore, counterpropagating soliton stability is numerically investigated and compared with the transverse modulation instability analysis, revealing an underlying physical link.

Photorefractive solitons embedded in gratings in centrosymmetric crystals.

We investigate (1+1D) spatial optical solitons embedded in a fixed-volume grating in centrosymmetric photorefractive crystals. We numerically identify a two-parameter soliton family and deduce both its existence surface and soliton profiles. For shallow gratings, the soliton Fourier spectrum exhibits three lobes located at the reciprocal lattice points -K, 0, and K. Soliton trapping is a consequence of both the self-induced nonlinear waveguide and the grating reflectivity, which prevents the breakaway of the lateral components. To provide a preliminary evaluation of soliton stability, we also investigate the propagation of slightly perturbed soliton profiles.

Counterpropagating spatial Kerr soliton in reflection gratings.

We analytically predict the existence of both spatial bright and dark counterpropagating solitons in a reflection grating in the presence of the Kerr nonlinearity. The basic trapping mechanism consists of a twofold balance where diffraction is compensated by self-focusing and reflection is altered by the nonlinear-induced interferometric grating. We find that, whenever the spectral soliton profile lies within the grating stop band, bright and dark solitons exist only if the mutual phase of the counterpropagating solitons is pi or 0, respectively.