Biofilm reactors for the treatment of used water in space:potential, challenges, and future perspectives.

Water is not only essential to sustain life on Earth, but also is a crucial resource for long-duration deep space exploration and habitation. Current systems in space rely on the resupply of water from Earth, however, as missions get longer and move farther away from Earth, resupply will no longer be a sustainable option. Thus, the development of regenerative reclamation water systems through which useable water can be recovered from "waste streams" (i.e., used waters) is sorely needed to further close the loop in space life support systems. This review presents the origin and characteristics of different used waters generated in space and discusses the intrinsic challenges of developing suitable technologies to treat such streams given the unique constrains of space exploration and habitation (e.g., different gravity conditions, size and weight limitations, compatibility with other systems, etc.). In this review, we discuss the potential use of biological systems, particularly biofilms, as possible alternatives or additions to current technologies for water reclamation and waste treatment in space. The fundamentals of biofilm reactors, their advantages and disadvantages, as well as different reactor configurations and their potential for use and challenges to be incorporated in self-sustaining and regenerative life support systems in long-duration space missions are also discussed. Furthermore, we discuss the possibility to recover value-added products (e.g., biomass, nutrients, water) from used waters and the opportunity to recycle and reuse such products as resources in other life support subsystems (e.g., habitation, waste, air, etc.).

Slippery lubricant-infused silica nanoparticulate film processing for anti-biofouling applications.

Microbial biofilm build-up in water distribution systems can pose a risk to human health and pipe material integrity. The impact is more devastating in space stations and to astronauts due to the isolation from necessary replacement parts and medical resources. As a result, there is a need for coatings to be implemented onto the inner region of the pipe to minimize the adherence and growth of biofilms. Lubricant-infused surfaces has been one such interesting material for anti-biofouling applications in which their slippery property promotes repellence to many liquids and thus prevents bacterial adherence. Textured and porous films are suitable substrate candidates to infuse and contain the lubricant. However, there is little investigation in utilizing a nanoparticulate thin film as the substrate material for lubricant infusion. A nanoparticulate film has high porosity within the structure which can promote greater lubricant infusion and retention. The implementation as a thin film structure aids to reduce material consumption and cost. In our study, we utilized a well-studied nanoporous thin film fabricated via layer-by-layer assembly of polycations and colloid silica and then calcination for greater stability. The film was further functionalized to promote fluorinated groups and improve affinity with a fluorinated lubricant. The pristine nanoporous film was characterized to determine its morphology, thickness, wettability, and porosity. The lubricant-infused film was then tested for its lubricant layer stability upon various washing conditions and its performance against bacterial biofilm adherence as a result of its slippery property. Overall, the modified silica nanoparticulate thin film demonstrated potential as a base substrate for lubricant-infused surface fabrication that repelled against ambient aqueous solvents and as an anti-biofouling coating that demonstrated low biofilm coverage and colony forming unit values. Further optimization to improve lubricant retention or incorporation of a secondary function can aid in developing better coatings for biofilm mitigation.

Energized Composites for Electric Vehicles: A Dual Function Energy-Storing Supercapacitor-Based Carbon Fiber Composite for the Body Panels.

The current electric vehicles (EVs) face many challenges like limited charge capacity, low miles/charge, and long charging times. Herein, these issues are addressed by developing a dual-function supercapacitor-based energy-storing carbon fiber reinforced polymer (e-CFRP) that can store electrical energy and function as the structural component for the EV's body shell. This is achieved by developing a unique design, vertically aligned graphene sheets attached to carbon fiber electrodes on which different metal oxides are deposited to obtain high-energy density electrodes. A high-strength multilayer e-CFRP assembly is fabricated using an alternate layer patterning configuration of epoxy and polyacrylamide gel electrolyte. The e-CFRP so developed delivers a high areal energy density of 0.31 mWh cm-2 at 0.3 mm thickness and a high tensile strength of 518 MPa, bending strength of 477 MPa, and impact strength of 2666 J m-1 . To show its application in EVs, a toy car's body panel is fabricated with e-CFRP and the toy car is able to operate using the energy stored in its frame. Moreover, when integrated with a solar cell, this composite powers an Internet of Things device, showing its feasibility in communication satellites.

Aquatic invertebrate protein sources for long-duration space travel.

During the summer of 2020, NASA returned to launching astronauts to the International Space Station (ISS) from American soil. By 2024, NASA's mission is to return to the Moon, and by 2028 create a sustainable presence. Long duration missions come with obstacles, especially when trying to create a sustainable environment in a location where "living off the land" is impossible. Some resources on the Moon can be recovered or resupplied; however, many resources such as those needed for sustaining life must be recycled or grown to support humans. To achieve sustainability, food and water must be grown and recycled using elements found within the habitat. NASA's current work focuses on food resupply and growing plants as supplemental nutrient content. This paper examines the possibility for using aquaculture systems to purify water while growing nutrient-rich species as food sources, which aquatic food sources would be ideal for a habitat environment, and which species might provide an ideal test case for future studies aboard ISS. The aquatic species should be rapidly grown with high protein content and low launch mass requirements. Although there are numerous challenges and unknown technology gaps for maintaining aquaculture systems in reduced gravity environments, the benefit of employing such systems would be of great advantage towards creating a sustainable presence beyond Earth's orbit for sustainable aquaculture.

Regenerative water purification for space applications: Needs, challenges, and technologies towards 'closing the loop'.

Human missions to establish surface habitats on the Moon and Mars are planned in the coming decades. Extraplanetary surface habitat life support systems (LSS) will require new capabilities to withstand anticipated unique, harsh conditions. In order to provide safe, habitable environments for the crew, water purification systems that are robust and reliable must be in place. These water purification systems will be required to treat all sources of water in order to achieve the necessary levels of recovery needed to sustain life over the long-duration missions. Current water recovery and purification systems aboard the International Space Station (ISS) are only partially closed, requiring external inputs and resupply. Furthermore, organic wastes, such as fecal and food wastes, are currently discarded and not recycled. For long-duration missions and habitats, this is not a viable approach. The inability to recycle organic wastes represents a lost opportunity to recover critical elements (e.g., C, H, O, N, P) for subsequent food production, water purification, and atmospheric regeneration. On Earth, a variety of technologies are available to meet terrestrial wastewater treatment needs; however, these systems are rarely completely closed-loop, due to lack of economic drivers, legacy infrastructure, and the (perceived) abundance of resources on Earth. Extraplanetary LSS provides a game-changing opportunity to incentivize the development of completely closed-loop systems. Candidate technologies may be biological, physical, or chemical, with associated advantages and disadvantages. This paper presents a survey of potential technologies, along with their inputs, outputs and requirements, which may be suitable for next-generation regenerative water purification in space. With this information, particular technologies can be down-selected for subsystem integration testing and optimization. In order for future space colonies to have closed-loop systems which minimize consumable inputs and maximize recovery, strategic implementation of a variety of complementary subsystems is needed.

Pentacene disproportionation during sublimation for field-effect transistors.

At moderate temperatures in flowing gas, pentacene undergoes a disproportionation reaction to produce 6,13-dihydropentacene (DHP) and a series of polycondensed aromatic hydrocarbons, including the previously unknown peripentacene (PP). The process requires activation by heating to 320 degrees C and is possibly catalyzed by impurities such as DHP, 6,13-pentacenequinone (PQ), Al, or Fe found in the starting materials. These impurities also result in a decrease in the intrinsic field-effect mobility (FEM) of pentacene crystals. Subsequent purifications remove such impurities, thus inhibiting the formation of the disproportionation products and increasing the FEM of pentacene (2.2 cm(2)/Vs). These results clarify the importance of purification of semiconductive materials for measurements of intrinsic mobility and optimal device performance.