1.
Chem Commun (Camb)
; 50(5): 524-6, 2014 Jan 18.
Artículo
en Inglés
| MEDLINE
| ID: mdl-24282827
RESUMEN
We report the crystal structure and dielectric properties of a pure H2O@C60 crystal at low temperature. The caged water molecules free from the hydrogen bonds rotate even at 8 K. The antifreeze rotating water molecules respond to an external electric field due to their permanent dipole moment.
2.
Angew Chem Int Ed Engl
; 51(14): 3377-81, 2012 Apr 02.
Artículo
en Inglés
| MEDLINE
| ID: mdl-22374838
RESUMEN
Rock solid: fullerene-encapsulated Li(+) (Li(+)@C(60)) is an alkaline cation owing to the spherical shape and positive charge. Li(+)@C(60) crystallizes as a rock-salt-type crystal in the presence of PF(6)(-). The orientations of C(60) and PF(6)(-) (orange) are perfectly ordered below 370 K, and Li(+) (purple) hops within the cage. At temperatures below 100 K two Li(+) units are localized at two polar positions within each C(60) .