Reutilization of carbon of waste filter cartridge after its surface modification for the fluoride removal from water by continuous flow process.

In the present study, the waste carbon cartridge of the water filter was modified and reutilized for defluoridation of water. The modified carbon was characterized by particle size analysis (PSA), Fourier transformed infrared spectroscopy (FTIR), zeta potential, pHzpc, energy-dispersive X-ray (EDS), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and X-ray crystallography (XRD). The adsorptive nature of modified carbon was investigated with pH (4-10), dose (1-5 g/L), contact time (0-180 min), temperature (25-55 °C), fluoride concentration (5-20 mg/L), and the effect of the competitive ions. Adsorption isotherm, kinetics, thermodynamics, and breakthrough studies were evaluated for fluoride uptake on surface-modified carbon (SM*C). Fluoride adsorption on the carbon accepted Langmuir model (R2 = 0.983) and pseudo-second-order kinetic (R2 = 0.956). The presence of HCO3- in the solution reduced the elimination of fluoride. The carbon was regenerated and reused four times; the removal percentage was decreased from 92 to 31.7%. This adsorption phenomenon showed exothermic behavior. The maximum fluoride uptake capacity of SM*C achieved 2.97 mg/g at 20 mg/L of initial concentration. The modified carbon cartridge of the water filter was successfully employed for fluoride removal from water.

Adsorption of As(III) and As(V) from aqueous solution by magnetic biosorbents derived from chemical carbonization of pea peel waste biomass: Isotherm, kinetic, thermodynamic and breakthrough curve modeling studies.

The purpose of this research was to investigate the adsorption of arsenic (As) from aqueous solutions using MPAC-500 and MPAC-600 (magnetic-activated carbons synthesized from the peel of Pisum sativum (pea) pyrolyzed at 500 °C and 600 °C temperatures, respectively). The potential of both biosorbents for As adsorption was determined in batch and column mode. The characterization of both biosorbents was performed by energy dispersive spectroscopy, scanning electron microscope, pHZPC, particle size distribution, X-ray diffraction, zeta potential and Fourier-transform infrared spectroscopy. It was found that the efficiency of MPAC-600 was better than MPAC-500 for the adsorption of As(III) and As(V) ions. The adsorption capacities of MPAC-500 and MPAC-600 in removing As(III) were 0.7297 mg/g and 1.3335 mg/g, respectively, while the values of Qmax for As(V) on MPAC-500 and MPAC-600 were 0.4930 mg/g and 0.9451 mg/g, respectively. The Langmuir isotherm model was found to be the best fit for adsorption of As(III) by MPAC-500 and MPAC-600, as well as adsorption of As(V) by MPAC-500. The Freundlich isotherm model, on the other hand, was optimal for As(V) removal with MPAC-600. With R2 values close to unity, the pseudo-second-order kinetics were best fitted to the adsorption process of both As species. The Thomas model was used to estimate the breakthrough curves. The effects of coexisting oxyanions and regeneration studies were also carried out to examine the influence of oxyanions on As adsorption and reusability of biosorbents.

Removal of arsenic from aqueous solution by novel iron and iron-zirconium modified activated carbon derived from chemical carbonization of Tectona grandis sawdust: Isotherm, kinetic, thermodynamic and breakthrough curve modelling.

The aim of the present study was: development of activated carbon modified with iron (Fe@AC) and modified with iron and zirconium (Fe-Zr@AC) from the Tectona grandis sawdust (TGS) waste biomass and its potential applicability for the removal of As (III) from contaminated water by batch and column mode. The biomass waste was pre-treated with ferric chloride (FeCl3) and the mixture of FeCl3 and zirconium oxide (ZrO2) and then pyrolyzed at 500 °C for 2 h. The properties of both bioadsorbents were comprehensively characterized by using Scanning electron microscopy (SEM), Energy dispersive X-ray (EDX), Fourier transform infra-red spectroscopy (FTIR), X-ray diffraction (XRD), Particle Size analysis (PSA), point of zero charge (pHZPC), Brunauer-Emmett-Teller (BET) to prove successful impregnation of the Fe and Zr on the surface of AC of TGS. FTIR analysis clearly indicates the Fe and Fe-Zr complexation on biosorbents surface and biosorption of As (III). The results revealed that maximum As (III) removal was achieved 86.35% by Fe-Zr@AC (3 g/L dose, pH-7.0, temperature-25 °C and concentration 0.5 mg/L). However, maximum removal of As (III) was attained ~75% by Fe@AC (with dose-4g/L, pH-7.0, temperature-25 °C and concentration 0.5 mg/L) at the initial concentration of 0.5 mg/L of As (III). Fe-Zr@AC exhibits higher efficiency with qmax value 1.206 mg/g than Fe@AC with the qmax value 0.679 mg/g for the removal of As(III). While in the column study, Fe-Zr@AC exhibited 98.8% removal at flow rate of 5 mL/min and bed height of 5 cm. Biosorption Isotherm and Kinetics were fitted good with Langmuir isotherm (R2 ≥ 0.99) and followed pseudo-second-order (R2 ≥ 0.99). The regeneration study indicates that the prepared biosorbents efficiently recycled up to five cycles. Therefore, Fe@AC and Fe-Zr@AC derived from TGS has been showed to be novel, effective, and economical biosorbent. The collective benefits of easy development, good affinity towards As (III), good separability, reusability, and inexpensive of magnetized Fe@AC and Fe-Zr@AC make it a novel biosorbent. The application of Fe-Zr@AC for the removal of As (III) from the water was very efficient its concentration in the solution after treatment was found below the 10 µg/L as per the guideline WHO.