Short-term residual characteristics of ambient-cured green geopolymer mortar exposed to elevated temperatures.

Every structure might be exposed to fire at some point in its lifecycle. The ability of geopolymer composites to withstand the effects of fire damage early before it is put out is of great importance. This study examined the effects of fire on geopolymer composite samples made with high-calcium fly ash and alkaline solution synthesised from waste banana peduncle and silica fume. A ratio of 0.30, 0.35, and 0.4 was used in the study for the alkaline solution to fly ash. Also used were ratios of 0.5, 0.75, and 1 for silica oxide (silica fume) to potassium hydroxide ratio. The strength loss, residual compressive strength, percentage strength loss, relative residual compressive strength, ultrasonic pulse velocity, and microstructural properties of the thirteen mortar mixes were measured after exposure to temperatures of 200, 400, 600, and 800 °C for 1 h, respectively. The results reveal that geopolymer samples exposed to elevated temperatures showed great dimensional stability with no visible surface cracks. There was a colour transition from dark grey to whitish brown for the green geopolymer mortar and brown to whitish brown for the control sample. As the temperature rose, weight loss became more pronounced, with 800 °C producing the most significant weight reduction. The optimum mixes had a residual compressive strength of 25.02 MPa after being exposed to 200 °C, 18.72 MPa after being exposed to 400 °C, 14.04 MPa after being exposed to 600 °C, and 7.41 MPa after being exposed to 800 °C. The control had a residual compressive strength of 8.45 MPa after being exposed to 200 °C, 6.67 MPa after being exposed to 400 °C, 3.16 MPa after being exposed to 600 °C, and 2.23 MPa after being exposed to 800 °C. The relative residual compressive strength decreases for green geopolymer mortar are most significant at 600 and 800 °C, with an average decrease of 0.47 and 0.30, respectively. The microstructure of the samples revealed various phase changes and new product formations as the temperature increased.

Effective Microorganisms and Glass Nanopowders from Waste Bottle Inclusion on Early Strength and Microstructure Properties of High-Volume Fly-Ash-Based Concrete.

In concrete production, the use of high-volume fly ash (FA) as the cement substitute became interesting to achieve more sustainable and eco-friendly construction materials. However, concrete produced using high volumes of FA as cement substitute suffers from various limitations such as low strength at early ages. Considering the engineering solutions and economy of FA-included concrete, it has become vital to address such issues. In this perception, some concrete mixes were designed using more abundant and low-cost local waste materials such as waste glass bottle nanopowders (WGBNPs) and effective microorganisms (EMs) to determine the feasibility of compensating for the strength loss at early ages due to FA inclusion. The proposed mixes contained 10% of EMs as water replacement, 50% of FA, and various percentages of WGBNPs as cement replacement. The effects of EMs and WGBNPs inclusion on the early strength and microstructure properties of the produced FA-based concrete mixes were determined. The results show that the strength indexes of the concrete at all test ages were improved due to WGBNP and EM incorporation. At almost all curing ages, the mechanical performance of the concrete made with 10% EMs and 4% WGBNPs was comparable to that of normal concrete (control mix), wherein the mix containing 6% WGBNPs outperformed the control mix. The microstructure analysis of the studied mixes revealed an increase in the hydration products, structural compactness, and homogeneity due to the synergy of WGBNPs and EMs, especially the specimen made using 10% EMs and 6% WGBNPs. It is established that the proper utilization of EMs and WGBNPs in FA-based concrete can be beneficial for waste recycling and landfill problems, thus lowering environment pollution.

Influence of Glass Silica Waste Nano Powder on the Mechanical and Microstructure Properties of Alkali-Activated Mortars.

The recycling of millions of tons of glass bottle waste produced each year is far from optimal. In the present work, ground blast furnace slag (GBFS) was substituted in fly ash-based alkali-activated mortars (AAMs) for the purpose of preparing glass bottle waste nano-powder (BGWNP). The AAMs mixed with BGWNP were subsequently subjected to assessment in terms of their energy consumption, economic viability, and mechanical and chemical qualities. Besides affording AAMs better mechanical qualities and making them more durable, waste recycling was also observed to diminish the emissions of carbon dioxide. A more than 6% decrease in carbon dioxide emissions, an over 16% increase in compressive strength, better durability and lower water absorption were demonstrated by AAM consisting of 5% BGWNP as a GBFS substitute. By contrast, lower strength was exhibited by AAM comprising 10% BGWNP. The conclusion reached was that the AAMs produced with BGWNP attenuated the effects of global warming and thus were environmentally advantageous. This could mean that glass waste, inadequate for reuse in glass manufacturing, could be given a second life rather than being disposed of in landfills, which is significant as concrete remains the most commonplace synthetic material throughout the world.

Binary effect of fly ash and palm oil fuel ash on heat of hydration aerated concrete.

The binary effect of pulverized fuel ash (PFA) and palm oil fuel ash (POFA) on heat of hydration of aerated concrete was studied. Three aerated concrete mixes were prepared, namely, concrete containing 100% ordinary Portland cement (control sample or Type I), binary concrete made from 50% POFA (Type II), and ternary concrete containing 30% POFA and 20% PFA (Type III). It is found that the temperature increases due to heat of hydration through all the concrete specimens especially in the control sample. However, the total temperature rises caused by the heat of hydration through both of the new binary and ternary concrete were significantly lower than the control sample. The obtained results reveal that the replacement of Portland cement with binary and ternary materials is beneficial, particularly for mass concrete where thermal cracking due to extreme heat rise is of great concern.