Upscaling Point Velocity Measurements to Characterize a Glacial Outwash Aquifer.

Small-scale point velocity probe (PVP)-derived velocities were compared to conventional large-scale velocity estimates from Darcy calculations and tracer tests, and the possibility of upscaling PVP data to match the other velocity estimates was evaluated. Hydraulic conductivity was estimated from grain-size data derived from cores, and single-well response testing or slug tests of onsite wells. Horizontal hydraulic gradients were calculated using 3-point estimators from all of the wells within an extensive monitoring network, as well as by representing the water table as a single best fit plane through the entire network. Velocities determined from PVP testing were generally consistent in magnitude with those from depth specific data collected from multilevel monitoring locations in the tracer test, and similar in horizontal flow direction to the average hydraulic gradient. However, scaling up velocity estimates based on PVP measurements for comparison with site-wide Darcy-based velocities revealed issues that challenge the use of Darcy calculations as a generally applicable standard for comparison. The Darcy calculations were shown to underestimate the groundwater velocities determined both by the PVPs and large-scale tracer testing, in a depth-specific sense and as a site-wide average. Some of this discrepancy is attributable to the selective placement of the PVPs in the aquifer. Nevertheless, this result has important implications for the design of in situ treatment systems. It is concluded that Darcy estimations of velocity should be supplemented with independent assessments for these kinds of applications.

Stimulating in situ denitrification in an aerobic, highly permeable municipal drinking water aquifer.

A preliminary trial of a cross-injection system (CIS) was designed to stimulate in situ denitrification in an aquifer servicing an urban community in southern Ontario. It was hypothesized that this remedial strategy could be used to reduce groundwater nitrate in the aquifer such that it could remain in use as a municipal supply until the beneficial effects of local reduced nutrient loadings lead to long-term water quality improvement at the wellfield. The CIS application involved injecting a carbon source (acetate) into the subsurface using an injection-extraction well pair positioned perpendicular to the regional flow direction, up-gradient of the water supply wells, with the objective of stimulating native denitrifying bacteria. The pilot remedial strategy was targeted in a high nitrate flux zone within an aerobic and heterogeneous section of the glacial sand and gravel aquifer. Acetate injections were performed at intervals ranging from daily to bi-daily. The carbon additions led to general declines in dissolved oxygen concentrations; decreases in nitrate concentration were localized in aquifer layers where velocities were estimated to be less than 0.5m/day. NO3-(15)N and NO3-(18)O isotope data indicated the nitrate losses were due to denitrification. Relatively little nitrate was removed from groundwater in the more permeable strata, where velocities were estimated to be on the order of 18 m/day or greater. Overall, about 11 percent of the nitrate mass passing through the treatment zone was removed. This work demonstrates that stimulating in situ denitrification in an aerobic, highly conductive aquifer is challenging but achievable. Further work is needed to increase rates of denitrification in the most permeable units of the aquifer.

Applications and implications of direct groundwater velocity measurement at the centimetre scale.

Three projects involving point velocity probes (PVPs) illustrate the advantages of direct groundwater velocity measurements. In the first, a glacial till and outwash aquifer was characterized using conventional methods and multilevel PVPs for designing a bioremediation program. The PVPs revealed a highly conductive zone that dominated the transport of injected substances. These findings were later confirmed with a natural gradient tracer test. In the second, PVPs were used to map a groundwater velocity field around a dipole recirculation well. The PVPs showed higher than expected velocities near the well, assuming homogeneity in the aquifer, leading to improved representations of the aquifer heterogeneity in a 3D flow model, and an improved match between the modelled and experimental tracer breakthrough curves. In the third study, PVPs detected subtle changes in aquifer permeability downgradient of a biostimulation experiment. The changes were apparently reversible once the oxygen source was depleted, but in locations where the oxygen source lingered, velocities remained low. PVPs can be a useful addition to the hydrogeologist's toolbox, because they can be constructed inexpensively, they provide data in support of models, and they can provide information on flow in unprecedented detail.

Transient heterogeneity in an aquifer undergoing bioremediation of hydrocarbons.

Localized, transient heterogeneity was studied in a sand aquifer undergoing benzene, toluene, ethylbenzene, and xylene bioremediation using a novel array of multilevel, in situ point velocity probes (PVPs). The experiment was conducted within a sheet-pile alleyway to maintain a constant average flow direction through time. The PVPs measured changes in groundwater velocity direction and magnitude at the centimeter scale, making them ideal to monitor small-scale changes in hydraulic conductivity (K). Velocities were shown to vary nonuniformly by up to a factor of 3 when a source of oxygen was established down-gradient of the petroleum spill. In spite of these local variations, the average groundwater velocity within the 7 m × 20 m sheet-piled test area only varied within ± 25%. The nonuniform nature of the velocity variations across the gate indicated that the changes were not due solely to seasonal hydraulic gradient fluctuations. At the conclusion of the experiment, microbial biomass levels in the aquifer sediments was approximately 1 order of magnitude higher in the oxygen-amended portion of the aquifer than at the edge of the plume or in locations up-gradient of the source. These data suggest that the transient velocities resulted, at least in part, from enhanced biological activity that caused transient heterogeneities in the porous medium.