Surface Modification of Feldspathic Ceramic Used for Minimally Invasive Restorations: Effect of Airborne Particle Type on the Surface Properties and Biaxial Flexural Strength.

This study aimed to evaluate the effect of airborne particle abrasion with different particles on the surface free energy, roughness, and biaxial flexural strength of a feldspathic ceramic by comparing it with hydrofluoric acid etching, the standard surface treatment, and polishing. Square-shaped feldspathic ceramic specimens (12 mm × 12 mm × 1.2 mm) were divided into subgroups as airborne particles abraded with alumina (AO3a, AO3b, AO25, AO50a, AO50b, AO90, AO110a, AO110b, AO120a, and AO120b), silica (SO50a, SO50b, SO100, and SO100/200), or nutshell granule (NS100/200), hydrofluoric acid etched, and polished (n = 12). Surface free energy (n = 5), roughness (n = 5), biaxial flexural strength (n = 12), and Weibull moduli (n = 12) were investigated. Data were evaluated with 1-way ANOVA and Tukey HSD tests, and possible correlations were investigated with Pearson's correlation (α = 0.05). SO100/200 mostly had lower surface free energy (p ≤ 0.011), and polishing and etching led to higher surface free energy than AO3a, AO3b, and AO120a (p ≤ 0.031). Polished, SO100, and SO50b specimens mostly had lower roughness and AO125 had the highest roughness (p ≤ 0.029). SO100/200 mostly had lower biaxial flexural strength (p ≤ 0.041), and etched specimens had higher biaxial flexural strength than AO120a, AO120b, and SO50b (p ≤ 0.043). AO3b had the highest (33.56) and AO120b had the lowest (11.8) Weibull modulus. There was a weak positive correlation between the surface free energy and the biaxial flexural strength (r = 0.267, p = 0.011). A larger particle size mostly resulted in higher roughness, which was also affected by the particle shape. Most of the test groups had similar biaxial flexural strength to that of the hydrofluoric acid-etched group. Therefore, for tested feldspathic ceramic, airborne particle abrasion with tested parameters may be a suitable alternative without causing any further damage.

Revealing dynamic processes in laser powder bed fusion with in situ X-ray diffraction at PETRA III.

The high flux combined with the high energy of the monochromatic synchrotron radiation available at modern synchrotron facilities offers vast possibilities for fundamental research on metal processing technologies. Especially in the case of laser powder bed fusion (LPBF), an additive manufacturing technology for the manufacturing of complex-shaped metallic parts, in situ methods are necessary to understand the highly dynamic thermal, mechanical, and metallurgical processes involved in the creation of the parts. At PETRA III, Deutsches Elektronen-Synchrotron, a customized LPBF system featuring all essential functions of an industrial LPBF system, is used for in situ x-ray diffraction research. Three use cases with different experimental setups and research questions are presented to demonstrate research opportunities. First, the influence of substrate pre-heating and a complex scan pattern on the strain and internal stress progression during the manufacturing of Inconel 625 parts is investigated. Second, a study on the nickel-base superalloy CMSX-4 reveals the formation and dissolution of γ' precipitates depending on the scan pattern in different part locations. Third, phase transitions during melting and solidification of an intermetallic γ-TiAl based alloy are examined, and the advantages of using thin platelet-shaped specimens to resolve the phase components are discussed. The presented cases give an overview of in situ x-ray diffraction experiments at PETRA III for research on the LPBF technology and provide information on specific experimental procedures.

Two-body wear of occlusal splint materials from subtractive computer-aided manufacturing and three-dimensional printing.

OBJECTIVES: To investigate the two-body wear of occlusal splint materials fabricated from subtractive computer-aided manufacturing (CAM) compared to three-dimensional printing (3DP). MATERIAL AND METHODS: Forty-eight substrates (n = 12/material) in the design of a mandibular first molar were fabricated using CAM (CAM-TD, Thermeo, pro3dure medical GmbH, Iserlohn, Germany; CAM-CL, CLEARsplint, Astron Dental Corporation, Lake Zurich, USA) and 3DP (3DP-GI, GR22 flex, pro3dure medical GmbH; 3DP-KY, KeySplint soft, Keystone Industries, Gibbstown, USA). The substrates were subjected to mastication simulation (120,000 cycles, 37 °C, 50 N, 1.3 Hz) opposed to enamel antagonists. The two-body wear was measured through matching of the scanned substrates before and after aging using Gaussian best-fit method. The damage patterns were categorized and evaluated based on microscopic examinations. Data was analyzed using Kolmogorov-Smirnov test followed by 1-way analysis of variance (ANOVA). Pearson correlation was calculated between vertical and volumetric material loss. The failure types were analyzed with Chi2-test and Ciba Geigy table. RESULTS: No difference in two-body wear results between all materials was found (p = 0.102). Fatigue substrates showed a perforation for CAM and a fracture for 3DP. No abrasion losses on the antagonists were detected. CONCLUSIONS: 3DP substrates showed no differences in two-body wear compared to CAM ones but are more likely to show a fracture. None of the tested materials caused an abrasion on human teeth structure. CLINICAL RELEVANCE: While therapies with occlusal splint materials are rising, 3DP offers a promising alternative to CAM in terms of production accuracy and therapeutic success at reduced costs.

Methodology investigation: Impact of crown geometry, crown, abutment and antagonist material and thermal loading on the two-body wear of dental materials.

OBJECTIVES: To investigate the impact of crown geometry, crown/abutment/antagonist material and thermal loading on the two-body wear of dental materials caused by chewing simulation. MATERIALS AND METHODS: For the crown geometry, crowns (polymethylmethacrylate (PMMA), polyetheretherketone (PEEK) and silicate ceramic (SiO2)) were milled with a flat, steep, or medium cusp inclination (CINC). For the crown/abutment material, crowns (PMMA, PEEK and SiO2) were combined with PMMA, polymer-infiltrated-ceramic-network (PICN), cobalt-chrome alloy (CoCr) and natural teeth (ENAM) abutments. For the antagonist material, antagonists were fabricated from PICN, CAD/CAM resin composite (RECO), steatite (STEA), steel (STL) and ENAM and tested against flat specimens (substrates) made of veneering ceramic (VC). For thermal loading, the duration (30 s, 60 s, 120 s) and presence of temperature changes (37 °C versus 5 °C/55 °C) was varied. Material losses were determined by matching scanned specimens before and after aging (400,000 chewing cycles, 50 N, 1.3 Hz). Martens parameters were determined for the antagonists/substrates. Data were analyzed using Kolmogorov-Smirnov-test, Kruskal-Wallis H, Scheffé-Post-Hoc-tests, pairwise comparisons, Bonferroni correction, one-way ANOVA, Mann-Whitney-U and Spearman rho. RESULTS: PMMA crowns presented the highest and PEEK the lowest material losses. Flat CINC showed the lowest material losses for PEEK and SiO2 crowns. CoCr and ENAM abutments presented material losses in the same range. Antagonist and cumulative material losses for RECO and ENAM were similar. Thermal loading did not influence material losses. SIGNIFICANCE: Crown geometry influences the crown and antagonists wear, with an increased cusp inclination entailing increased wear. For in vitro set-ups, CoCr abutments and RECO antagonists present valid alternatives to natural teeth. For polymers, in vitro chewing simulations may be performed at a constant temperature (37 °C).

A laser powder bed fusion system for in situ x-ray diffraction with high-energy synchrotron radiation.

In Laser Powder Bed Fusion (LPBF), the highly localized energy input by the laser leads to high-temperature gradients. Combined with the inherent cycles of re-melting and solidification of the material, they can result in high mechanical stresses. These stresses can cause distortion and cracking within the component. In situ diffraction experiments with high-energy synchrotron radiation allow an analysis of the lattice spacing during the LPBF process and provide insight into the dynamics of stress generation and texture evolution. In this work, an LPBF system for the purpose of synchrotron x-ray diffraction experiments during the manufacturing process of multi-layer components with simple geometries is described. Moreover, results from diffraction experiments at the HEMS beamline P07 at PETRA III, DESY, Hamburg, Germany, are presented. Components with a length of ls = 20 mm and a width of ws = 2.5 mm consisting of 100 layers with a layer thickness of Δz = 50 µm were produced using the nickel-base alloy Inconel 625 as the powder material. Diffraction experiments were carried out in situ at sampling rates of f = 10 Hz with a synchrotron radiation beam size of 750 × 70 µm2. The presented experimental setup allows for the observation of arbitrary measuring positions in the sample in the transmission mode while gathering full diffraction rings. Thus, new possibilities for the observation of the dynamic evolution of strains, stresses, and textures during the LPBF process are provided.