1.
Chem Commun (Camb)
; 58(22): 3681-3684, 2022 Mar 15.
Artículo
en Inglés
| MEDLINE
| ID: mdl-35226000
RESUMEN
A straightforward synthesis of aryl aziridines is reported from readily available azides and alkenes and using technical solvents in the presence of air. This methodology does not require any additives and the obtained compounds can be employed in ring-opening and ring-expansion reactions.
Asunto(s)
Aziridinas , Alquenos , Azidas , Reacción de Cicloadición , Estructura Molecular , Estereoisomerismo
2.
ChemCatChem
; 10(9): 2041-2045, 2018 May 09.
Artículo
en Inglés
| MEDLINE
| ID: mdl-29861792
RESUMEN
A series of well-defined copper(I) complexes bearing ring-expanded N-heterocyclic carbene (NHC) ligands has been applied to the azide-alkyne cycloaddition reaction. The obtained results notably showed that the six-membered NHC ligands outperform well-established five-membered ones. [CuI(Mes-6)] displayed a remarkable catalytic activity while respecting the strict criteria for click reactions.