RESUMEN
A smart window is an optical dimming device with intelligent functions that can control its relevant performances through external stimuli, achieving functions such as privacy protection and temperature regulation. Light is an ideal stimulus for regulating smart windows, which is noninvasive and allows self-adaptable manipulation of materials. This review highlights recent significant achievements in smart windows constructed by photo-responsive liquid crystals (LCs) systems that can undergo the transition between different phases. The smart windows based on photo-responsive LCs are used in a plethora of areas, including privacy protection, absorption glass, building decoration, energy saving, and climate modulation applications. The review concludes with a brief perspective on some significant challenges and opportunities for the future development of photo-responsive smart windows, which is crucial for expanding the applications of smart windows and improving their performances.