In situ MIL-101 growth on cotton cloth to fabricate multifunctional phase change composites driven by solar and magneto-thermal for all-day desalination.

It is certainly one of the most feasible ways to extract fresh water from seawater in the face of the current depletion of fresh water resources. Although solar energy as a heat source for desalination is the cleanest and most abundant way, its intermittent and seasonal also poses an obstacle to its practical application. In order to solve the above-mentioned issues, we prepared a series of phase change composites (PCCs) with excellent light-absorbing and magnetic properties by growing MIL-101(Fe) in situ on cotton fabric. All-day desalination through the synergistic action of phase change material (PCM) and magnetic particles. The evaporation rate of PCC can reach 2.76 kg m-2h-1 with an evaporation efficiency of 90.19 % under one sunlight condition. The evaporation rate of sea water under the synergistic effect of magnetic particles and PCM reached 4.53 kg m-2h-1 in the absence of sunlight. This paper provides a new approach to all-day desalination without contact heating.

Upgrading Electricity Generation and Electromagnetic Interference Shielding Efficiency via Phase-Change Feedback and Simple Origami Strategy.

Developing ultimate electromagnetic interference (EMI) shielding materials that can simultaneously upgrade the quality of generated electricity and the light-thermal-electric conversion efficiency based on traditional thermoelectric devices is crucially desired. Herein, a series of flexible multilayered phase change films (PCFs) is developed by a simple and novel origami strategy. The PCFs are first reported to improve the light-thermal-electric conversion efficiency by as high as 11.3%. Simultaneously, the PCFs could significantly upgrade the generated electricity on average voltage (27.3%), average current (23.8%), and lasting power outputs by 2010 times from microwatts to milliwatts. Besides, the EMI shielding efficiency of PCFs could be tuned from 39.2 to 71.9 dB by the origami process, the wide-range EMI shielding performance could be suitable for varying occasions. Overall, this work provides a promising solution for both the preparation of multifunctional materials, high-efficiency solar energy harvesting and upgrading electricity generation, which shows broad application prospects in EMI shielding, energy storage, and conversion.

Bioinspired Micro/Nanostructured Polyethylene/Poly(Ethylene Oxide)/Graphene Films with Robust Superhydrophobicity and Excellent Antireflectivity for Solar-Thermal Power Generation, Thermal Management, and Afterheat Utilization.

The rational utilization and circulation of multiple energy sources is an effective way to address the crises of energy shortages and environmental pollution. Herein, microextrusion compression molding, an industrialized polymer molding technology that combines melt blending and compression molding, is proposed for the mass production of a bioinspired micro/nanostructured polyethylene/poly(ethylene oxide)/graphene (MN-PPG) film. The MN-PPG film exhibits robust shape stability, high storage energy density, and excellent thermal management capability owing to the cocontinuous network formed by poly(ethylene oxide) and the polyethylene matrix. The MN-PPG film has sufficient photothermal property due to the uniformly dispersed graphene nanosheets and the bioinspired surface micro/nanostructures. Interestingly, the MN-PPG film surface exhibits durable superhydrophobicity, acid/alkali resistance, and active deicing performance. Further, a multifunctional energy harvesting and circulation system was established by integrating the MN-PPG film, an LED chip, and a thermoelectric module. The hybrid system produced an open-circuit voltage of 315.4 mV and power output of 2.5 W m-2 under 3 sun irradiation. Furthermore, the afterheat generated by the LED chips at night can be converted into electricity through thermoelectric conversion. The proposed method enables the large-scale fabrication of multifunctional phase change composites for energy harvesting in harsh environments.

High Thermal Conductivity and Mechanical Strength Phase Change Composite with Double Supporting Skeletons for Industrial Waste Heat Recovery.

The "solid-liquid" leakage and low thermal conductivity of organic phase change materials limit their wide range of applications. In this paper, a novel carbon fiber/boron nitride (CF/BN)-based nested structure was constructed, and then, a series of poly(ethylene glycol) (PEG)-based phase change composites (PCCs) with high thermal conductivity and mechanical strength were prepared via the simple vacuum adsorption technology by employing the CF/BN nested structure as the heat conduction path and supporting material and the in situ obtained cross-linking epoxy resin as another supporting material. The thermal conductivity of the obtained PCC is as high as 0.81 W/m K, which is 7.4 times higher than that sample without the CF/BN nested structure. The support of the double skeletons confers the obtained PCCs with excellent mechanical strength. Surprisingly, there is not any deformation for PCCs under the pressure of 128.5 times its own weight during the phase change process. In addition, the phase change enthalpy of the obtained PCC is as high as 107.9 J/g. All the results indicate that the obtained PEG-based PCCs possess huge application potential in the field of industrial waste heat recovery.